Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1
Last Answer : (C) Azeotropes obey Raoult's law at all temperature
Description : Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of ... law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Last Answer : (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law
Description : What are non-ideal solutions? Explain as to why non-ideal solutions deviate from Raoult’s Law.
Last Answer : Ans:- Non ideal solution are those which do not obey Raoult’s law. When the molecular interaction between solute molecules solvent. Solvent molecules is not same as the molecular interaction between solute & solvent molecules then deviotion occurs.
Description : Pick out the wrong statement. (A) An ideal liquid or solid solution is defined as one in which each component obeys Raoult's law (B) If Raoult's law is applied to one component of a binary mixture; ... also (C) Henry's law is rigorously correct in the limit of infinite dilution (D) None of these
Last Answer : (D) None of these
Description : Raoult's law is applicable to the (A) Ideal solutions (B) Real solutions (C) Mixture of water and alcohol
Last Answer : (A) Ideal solutions
Description : In a liquid-liquid extraction, 10 kg of a solution containing 2 kg of solute C and 8 kg of solvent A is brought into contact with 10 kg of solvent B. Solvent A and B are completely immiscible in each other whereas ... (C) Less than 1 kg of C is transferred to B (D) No amount of C is transferred to B
Last Answer : (A) The entire amount of C is transferred to solvent B
Description : State Raoult’s Law for a binary solution containing volatile components.
Last Answer : Ans:- At a particular temperature the partial vapour pressure of each component of a solution containing volatile liquid is directly propositional to its mole fraction.
Description : Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)
Last Answer : (A) A solution of benzene, toluene and o-xylene
Description : A solute distributes itself between two non-miscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of ... B) Followed from Margules equation (C) A corollary of Henry's law (D) None of these
Last Answer : (A) The distribution law
Description : Freundlich equation applies to the adsorption of solute from (A) Dilute solutions, over a small concentration range (B) Gaseous solutions at high pressure (C) Concentrated solutions (D) None of these
Last Answer : (A) Dilute solutions, over a small concentration range
Description : Pick out the wrong statement. Raoult's law does not apply, when the (A) Size of component molecules are not equal (B) Attractive forces between like and unlike molecules ... D) Chemical combination or molecular association between unlike molecules takes place in the formation of solution
Last Answer : (C) Component molecules are non-polar
Description : A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further 18 g of water is added to this solution. The new vapour pressure ... K. Calculate (i) the molecular mass of solute and (ii) vapour pressure of water at 298 K -Chemistry
Last Answer : For a very dilute solution ∴ Molecular mass, MB = 34 g/mol.
Description : What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation
Last Answer : ANSWER: X -- IDEAL GAS EQUATION
Description : When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of ... to the partial pressure of A (D) Partial pressure of component A to the total pressure
Last Answer : (A) Vapour pressure of component A to that of component B
Description : Pick out the wrong statement. (A) 'Solvates' are chemical compounds formed by solute with their solvents. When water is the solvent, then it is called a 'hydrate' (B) In heat exchanger ... vertical evaporators, area of central downtake is about 50 to 100% of the total tube cross-sectional area
Last Answer : (C) Heat transfer co-efficient during nucleate boiling is not influenced by the agitation imparted
Description : Pick out the wrong statement. (A) At constant pressure, solubility of a gas in a liquid diminishes with rise in temperature (B) Normally, the gases which are easily liquefied are more soluble ... (D) At constant pressure, solubility of a gas in a liquid increases with rise in temperature
Last Answer : (A) At constant pressure, solubility of a gas in a liquid diminishes with rise in temperature
Description : The Stoke's stream function applies to the (A) Irrotational flow only (B) Ideal/non i viscous fluids only (C) Cases of axial symmetry (D) None of these
Last Answer : (C) Cases of axial symmetry
Description : Positive deviation from Raoult's law means a mixture whose total pressure is (A) Greater than that computed for ideality (B) Less than that computed for ideality
Last Answer : (A) Greater than that computed for ideality
Description : One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect (A) ... The fraction vaporised but not the product composition (D) Neither the product composition nor the fraction vaporised
Last Answer : (C) The fraction vaporised but not the product composition
Description : Stage efficiency in a leaching process depends on the (A) Time of contact between the solid and the solution (B) Rate of diffusion of the solute through the solid and into the liquid (C) Both (A) and (B) (D) Vapour pressure of the solution
Last Answer : (C) Both (A) and (B)
Description : The rate of solid-liquid extraction is limited by the (A) Phase change of the solute as it dissolves in the solvent (B) Diffusion of the solute through the solvent in the pores to the outside of the particle (C) ... contact with the particle to the main bulk of the solution (D) All 'a', 'b' & 'c'
Last Answer : (D) All 'a', 'b' & 'c'
Description : Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these
Last Answer : (A) Departure from ideal solution behaviour
Description : Those solutions in which there is no volume change upon mixing the components in the liquid state and which, when diluted do not undergo any heat change (i.e. heat of dilution is zero), are called __________ solutions. (A) Ideal (B) Real (C) Isotonic (D) None of these
Last Answer : (A) Ideal
Description : In an interphase mass transfer process, the lesser the solubility of a given solute in a liquid, the higher are the chances that the transfer process will be (A) Liquid phase resistance-controlled (B) Gas phase resistance controlled (C) Impossible (D) Driven by a non-linear driving forc
Last Answer : (B) Gas phase resistance controlled
Description : What is a solution A. a solid dissolved in a gas B. a solute and a solvent C. a liquid dissolved in a gas D. an amalgam of solids, liquids, and gases?
Last Answer : B. A solute and a solvent
Description : Pick out the wrong statement regarding the solubility characteristics of high polymers. (A) Greater the degree of cross-linking in the polymer, lesser is its solubility (B) Polymers having more ... of the solvent (D) High molecular weight polymers on dissolving gives solution of very low viscosity
Last Answer : (D) High molecular weight polymers on dissolving gives solution of very low viscosity
Description : Tin vessels are corroded by (A) Anhydrous ammonia (B) Aromatic solvents (C) Synthetic detergent solution (D) None of these
Description : Which of the following solvents is used for the extraction of H3PO4 from CaCl2 solution during manufacture of ortho-phosphoric acid by wet process employing hydrochloric acid leaching? (A) Isopropyl alcohol (B) Butyl alcohol (C) Toluene (D) Hexane
Last Answer : (B) Butyl alcohol
Description : Which among the following is correct about ROM: a) ROM is non volatile memory because any data stored in ROM remains there, even if the power is turned off b) ROM is an ideal place to put the PC's startup instructions - that is, the software that boosts the system. c) Both of Above d) None of These
Last Answer : c) Both of Above
Description : Fourier's law of heat conduction applies to __________ surfaces. (A) Isothermal (B) Non-isothermal (C) Both (A) and (B) (D) Neither (A) and (B)
Description : If G = insoluble gas in gas stream and L = non-volatile solvent in liquid stream, then the slope of the operating line for the absorber is (A) L/G (B) G/L (C) Always < 1 (D) None of these
Last Answer : (A) L/G
Description : Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these
Last Answer : (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Description : When a solute is dissolved in water the solution's boiling temperature and the freezing temperature change in what way?
Last Answer : The boiling temperature increase and the freezing point decrease.
Description : What solute particles are present in water solutions of electrolytes and nonelectrolytes?
Last Answer : What is the answer ?
Description : What kinds of solute particles are present in h20 solutions of electrolytes and nonelectrolytes?
Description : Relative lowering of vapour pressure is a colligative property because_____________. (a)It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature of ... of an electrolyte or nonelectrolyte solutein solution as well as on the nature of solute molecules.
Last Answer : (a)It depends on the concentration of a non electrolyte solute in solution and does not depend on the nature of the solute molecules.
Description : Three pipes P, Q and R can fill a tank from empty to full in 40 minutes, 15 minutes, and 30 minutes respectively. When the tank is empty, all the three pipes are opened. P, Q and R discharge chemical solutions X, Y and Z respectively. ... 5 minutes? a) 8 / 15 b) 7 / 15 c) 8 / 17 d) 6 / 13 e) 8 / 13
Last Answer : a Part of the tank filled by pipe P in 1 minute = 1 / 40 Part of the tank filled by pipe Q in 1 minute = 1 / 15 Part of the tank filled by pipe R in 1 minute = 1/ 30 Here we have to find the proportion of ... together in 5 minute = 5 1/8 = 5/ 8 Required proportion = (1/3) / ( 5/8) = 8 / 15
Description : 3 faucet A,B,C can fill a cistern from empty to full in 45mins, 35mins, and 25 mins respectively. When the cistern is empty all the 3 faucets are opened. A,B,c discharge chemical solutions A,B,C respectively. What is ... the liquid in the tank after 5 mins? A) 63/143 B) 72/151 c) 67/173 D) 81/167
Last Answer : A Part filled by (A+B+C) in 5 mins = 5(1/45 +1/35 + 1/25) = 5 (35+45+63/1575) = 143/315 Part filled by c in 5 mins = 5/25 = 1/5 Required ratio = 1/5 * 315/143 =63/143.
Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Last Answer : (B) Solubility increases as temperature decreases
Description : For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient
Last Answer : (C) Activity co-efficient
Description : If two pure liquid constituents are mixed in any proportion to give an ideal solution, there is no change in (A) Volume (B) Enthalpy (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) & (B)
Description : Assertion(A): Ethyl alcohol is soluble in organic solvents Reason (R): Ethyl alcohol is having non polar ethyl group
Last Answer : Assertion(A): Ethyl alcohol is soluble in organic solvents Reason (R): Ethyl alcohol is having non polar ... is false D. A is false but R is true
Description : Most covalent compounds (a) Behave like electrolytes in the molten state (b) Have high melting and boiling points (c) Are hard substances because of strong covalent bonds (d) Are more soluble in non-polar solvents than in polar solvents
Last Answer : Ans:(d)
Description : Absorption (liquid-gas system) with evolution of heat as compared to isothermal absorption results in (A) Decreased solute solubility (B) Large minimum liquid to gas (L/G) ratio (C) Large number of trays (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : The individual mass transfer co-efficients (moles/m2s) for absorption of a solute from a gas mixture into a liquid solvent are, KL = 4.5 and KG = 1.5. The slope of the equilibrium line is 3. Which of ... A) Liquid side (B) Gas side (C) Interfacial (D) Both liquid and gas side
Last Answer : (B) Gas side
Description : The mass transfer co-efficient for a solid sphere of radius 'a' dissolving in a large volume of quiescent liquid, in which ‘D’ is the diffusivity of solute, is (A) D/a (B) D/2a (C) Proportional to √D (D) Dependent on the Reynolds number
Last Answer : (D) Dependent on the Reynolds number
Description : Thermosetting resins/polymers as compared to thermoplastic ones are (A) Soluble in all organic solvents (B) More brittle (C) Formed by addition polymerisation only (D) Easily reshaped & reused
Last Answer : (B) More brittle
Description : Fractional solvent extraction (A) Employs only one solvent (B) Employs two solvents (C) Results in low interfacial tension (D) None of these
Last Answer : (B) Employs two solvents
Description : On addition of solute in the solvent, the __________ of the solution decreases. (A) Boiling point (B) Freezing point (C) Vapour pressure (D) Both (B) and (C)
Last Answer : (D) Both (B) and (C)
Description : . In a solution containing 0.30 Kg mole of solute and 600 kg of solvent, the molality is (A) 0.50 (B) 0.60 (C) 1 (D) 2
Last Answer : (A) 0.50