State Raoult’s Law for a binary solution containing volatile components.

State Raoult’s Law for a binary solution containing volatile components.
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Ans:- At a particular temperature the partial vapour pressure of each component of a solution containing volatile liquid is directly propositional to its mole fraction.
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Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Last Answer : (C) Azeotropes obey Raoult's law at all temperature

Raoult's law applies to the (A) All liquid solutions (B) Non-ideal solution only (C) Non-volatile solute (D) Solvents

Description : Raoult's law applies to the (A) All liquid solutions (B) Non-ideal solution only (C) Non-volatile solute (D) Solvents

Last Answer : (D) Solvents

Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when (A) Only vapor phase follows Raoult's law (B) Only liquid phase obeys Dalton's law (C) Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Description : Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of ... law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Last Answer : (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Pick out the wrong statement. (A) An ideal liquid or solid solution is defined as one in which each component obeys Raoult's law (B) If Raoult's law is applied to one component of a binary mixture; Henry's law or Raoult's law is applied to the other component also (C) Henry's law is rigorously correct in the limit of infinite dilution (D) None of these

Description : Pick out the wrong statement. (A) An ideal liquid or solid solution is defined as one in which each component obeys Raoult's law (B) If Raoult's law is applied to one component of a binary mixture; ... also (C) Henry's law is rigorously correct in the limit of infinite dilution (D) None of these

Last Answer : (D) None of these

One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect (A) The product composition but not the fraction vaporised (B) The product composition as well as the fraction vaporised (C) The fraction vaporised but not the product composition (D) Neither the product composition nor the fraction vaporised

Description : One mole feed of a binary mixture of a given composition is flash vaporised at a fixed P and T. If Raoult's law is obeyed, then changing the feed composition would effect (A) ... The fraction vaporised but not the product composition (D) Neither the product composition nor the fraction vaporised

Last Answer : (C) The fraction vaporised but not the product composition

When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of component B (B) Vapour pressure of component A to the total pressure (C) Vapour pressure of component A to the partial pressure of A (D) Partial pressure of component A to the total pressure

Description : When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of ... to the partial pressure of A (D) Partial pressure of component A to the total pressure

Last Answer : (A) Vapour pressure of component A to that of component B

Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Description : Which of the following solutions will follow Raoult's law most closely? (A) A solution of benzene, toluene and o-xylene (B) 35% solution of camphor in water (C) 35% solution of NH3 in water (D) A solution of polar organic compounds (not of homologue of a series)

Last Answer : (A) A solution of benzene, toluene and o-xylene

Pick out the wrong statement. Raoult's law does not apply, when the (A) Size of component molecules are not equal (B) Attractive forces between like and unlike molecules in the solution are approximately equal (C) Component molecules are non-polar (D) Chemical combination or molecular association between unlike molecules takes place in the formation of solution

Description : Pick out the wrong statement. Raoult's law does not apply, when the (A) Size of component molecules are not equal (B) Attractive forces between like and unlike molecules ... D) Chemical combination or molecular association between unlike molecules takes place in the formation of solution

Last Answer : (C) Component molecules are non-polar

A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further 18 g of water is added to this solution. The new vapour pressure becomes 2.9 kPa at 298 K. Calculate (i) the molecular mass of solute and (ii) vapour pressure of water at 298 K -Chemistry

Description : A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further 18 g of water is added to this solution. The new vapour pressure ... K. Calculate (i) the molecular mass of solute and (ii) vapour pressure of water at 298 K -Chemistry

Last Answer : For a very dilute solution ∴ Molecular mass, MB = 34 g/mol.

What are non-ideal solutions? Explain as to why non-ideal solutions deviate from Raoult’s Law.

Description : What are non-ideal solutions? Explain as to why non-ideal solutions deviate from Raoult’s Law.

Last Answer : Ans:- Non ideal solution are those which do not obey Raoult’s law. When the molecular interaction between solute molecules solvent. Solvent molecules is not same as the molecular interaction between solute & solvent molecules then deviotion occurs.

What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation

Description : What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation

Last Answer : ANSWER: X -- IDEAL GAS EQUATION

According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a bottom fraction containing 98 mol% B ? Assume that relative volatility (αAB = 2) does not change appreciably in the column. (A) 5 (B) 9 (C) 12 (D) 28

Description : According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a ... in the column. (A) 5 (B) 9 (C) 12 (D) 28

Last Answer : (C) 12

Positive deviation from Raoult's law means a mixture whose total pressure is (A) Greater than that computed for ideality (B) Less than that computed for ideality

Description : Positive deviation from Raoult's law means a mixture whose total pressure is (A) Greater than that computed for ideality (B) Less than that computed for ideality

Last Answer : (A) Greater than that computed for ideality

Raoult's law is applicable to the (A) Ideal solutions (B) Real solutions (C) Mixture of water and alcohol

Description : Raoult's law is applicable to the (A) Ideal solutions (B) Real solutions (C) Mixture of water and alcohol

Last Answer : (A) Ideal solutions

(1) the action of ultraviolet rays on oxygen Explanation: The majority of tropospheric ozone formation occurs when nitrogen oxides (NOx), carbon monoxide (CO ) and volatile organic compounds (VOCs), such as xylene, react in the atmosphere in the presence of sunlight containing ultra violet rays. NOx, CO, and VOCs are called ozone precursors. CO + 2O2 + CO2 + O3

Description : (1) the action of ultraviolet rays on oxygen Explanation: The majority of tropospheric ozone formation occurs when nitrogen oxides (NOx), carbon monoxide (CO ) and volatile organic compounds (VOCs), such as xylene, ... violet rays. NOx, CO, and VOCs are called ozone precursors. CO + 2O2 + CO2 + O3

Last Answer : Water is not effective in extinguishing a fire caused by petrol because - (1) the flame is too hot for water to cool it down (2) water and petrol react chemically (3) water and petrol are ... (4) water and petrol are immiscible with each other and petrol which forms the upper layer continues to burn

Consider an ideal solution of components A and B. The entropy of mixing per mole of an alloy containing 50% B is (A) R ln 2 (B) -R ln 2 (C) 3 R ln 2 (D) -3R ln 2

Description : Consider an ideal solution of components A and B. The entropy of mixing per mole of an alloy containing 50% B is (A) R ln 2 (B) -R ln 2 (C) 3 R ln 2 (D) -3R ln 2

Last Answer : (A) R ln 2

Give reason: Magnesium ribbon should not be kept near bottles containing volatile chemicals.

Description : Give reason: Magnesium ribbon should not be kept near bottles containing volatile chemicals.

Last Answer : Magnesium is a reactive metal therefore it should not be kept near bottles containing volatile chemicals.

Coal containing large quantity of __________ are difficult to wash. (A) Ash (B) Inherent mineral matter (C) Free impurities (D) Volatile matter

Description : Coal containing large quantity of __________ are difficult to wash. (A) Ash (B) Inherent mineral matter (C) Free impurities (D) Volatile matter

Last Answer : (B) Inherent mineral matter

A coal containing high amount of volatile matter will have (A) Low ignition temperature (B) Very little ash content (C) High fusion point of its ash (D) Low adiabatic flame temperature

Description : A coal containing high amount of volatile matter will have (A) Low ignition temperature (B) Very little ash content (C) High fusion point of its ash (D) Low adiabatic flame temperature

Last Answer : (A) Low ignition temperature

Which of the following would require least amount of secondary air for combustion? (A) Coke breeze containing 25% ash and 2% volatile matter (B) Anthracite containing 10% volatile matter and 8% ash(C) Bituminous coal containing 20% ash and 25% volatile matter(D) Semi-bituminous coal containing 25% ash and 20% volatile matter

Description : Which of the following would require least amount of secondary air for combustion? (A) Coke breeze containing 25% ash and 2% volatile matter (B) Anthracite containing 10% volatile matter and 8% ash ... ash and 25% volatile matter (D) Semi-bituminous coal containing 25% ash and 20% volatile matter

Last Answer : (A) Coke breeze containing 25% ash and 2% volatile matter

A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor. (A) Isolated (B) Closed (C) Open (D) None of these

Description : A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor. (A) Isolated (B) Closed (C) Open (D) None of these

Last Answer : (C) Open

n(log n) is referred to A. A measure of the desired maximal complexity of data mining algorithms B. A database containing volatile data used for the daily operation of an organization C. Relational database management system D. None of these

Description : n(log n) is referred to A. A measure of the desired maximal complexity of data mining algorithms B. A database containing volatile data used for the daily operation of an organization C. Relational database management system D. None of these

Last Answer : A. A measure of the desired maximal complexity of data mining algorithms

In distillation column design, the McCabe-Thiele procedure is inadequate and a Ponchan-Savarit procedure is needed, when (A) Saturated feed is not used (B) An azeotrope forms (C) The latent heat of vaporisation of the more and less volatile components are greatly different (D) A total condenser is used

Description : In distillation column design, the McCabe-Thiele procedure is inadequate and a Ponchan-Savarit procedure is needed, when (A) Saturated feed is not used (B) An azeotrope forms (C) The latent ... vaporisation of the more and less volatile components are greatly different (D) A total condenser is used

Last Answer : (D) A total condenser is used

Fussain (A) Is friable, charcoal like substance(B) Has highest fixed carbon and lowest volatile matter content of all the four banded components of coal (C) Is non-coking, but when blended with highly coking coal, controls its swelling and produces high strength coke on carbonisation (D) All (A), (B) and (C)

Description : Fussain (A) Is friable, charcoal like substance (B) Has highest fixed carbon and lowest volatile matter content of all the four banded components of coal (C) Is non-coking, but when blended with highly coking ... its swelling and produces high strength coke on carbonisation (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is important in problems involving gas absorption without chemical reaction (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion (D) Total reflux in case of distillation operation requires infinite number of plates for a binary system separation

Description : Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is ... reflux in case of distillation operation requires infinite number of plates for a binary system separation

Last Answer : (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion

Simplest binary organic compounds containing carbon and hydrogen only are called

Description : Simplest binary organic compounds containing carbon and hydrogen only are called

Last Answer : hydrocarbons.

For a solution of volatile liquids, the partial vapour pressure of each component in solution is directly proportional to its (a) Molarity (b) Mole fraction (c) Molality (d) Normality

Description : For a solution of volatile liquids, the partial vapour pressure of each component in solution is directly proportional to its (a) Molarity (b) Mole fraction (c) Molality (d) Normality

Last Answer : Ans:(b)

In case of dry spinning of polymers, the polymer solution in a volatile solvent is forced through the spinnerates into a warm air chamber, where the solvent evaporates leaving behind the polymer in the filament form. Dry spinning is used for __________ fibres. (A) Polythene (B) PVC (C) Rayon (D) Polyvinyl acetate

Description : In case of dry spinning of polymers, the polymer solution in a volatile solvent is forced through the spinnerates into a warm air chamber, where the solvent evaporates leaving behind the polymer in the filament ... is used for __________ fibres. (A) Polythene (B) PVC (C) Rayon (D) Polyvinyl acetate

Last Answer : (B) PVC

Sirius `A` and Sirius `B` are two components of Sirius binary. The distance between the two components is `20.3AU` and the period of revolution about

Description : Sirius `A` and Sirius `B` are two components of Sirius binary. The distance between the two components is `20.3AU` and the period of revolution about

Last Answer : Sirius `A` and Sirius `B` are two components of Sirius binary. The distance between the two components ... 2.356, find the mass of the two components.

The orderly increase in the quantity of all the cellular components is known as a. Reproduction b. Growth c. Binary fission d. None of these

Description : The orderly increase in the quantity of all the cellular components is known as a. Reproduction b. Growth c. Binary fission d. None of these

Last Answer : Ans: B

Binary communications systems are better because A. they can interface directly with the analog telephone network B. the components are simpler, less costly, and more reliable C. people think better in binary D. interstate calls are less costly

Description : Binary communications systems are better because A. they can interface directly with the analog telephone network B. the components are simpler, less costly, and more reliable C. people think better in binary D. interstate calls are less costly

Last Answer : B. the components are simpler, less costly, and more reliable

The binary diffusivity in gases does not depend upon the (A) Pressure (B) Temperature (C) Nature of the components (D) None of these

Description : The binary diffusivity in gases does not depend upon the (A) Pressure (B) Temperature (C) Nature of the components (D) None of these

Last Answer : (D) None of these

McCabe-Thiele method of binary distillation does not assume that the (A) Sensible heat changes are negligible compared with latent heat changes (B) Molar latent heats of all components are equal (C) Heat of mixing is negligible (D) None of these

Description : McCabe-Thiele method of binary distillation does not assume that the (A) Sensible heat changes are negligible compared with latent heat changes (B) Molar latent heats of all components are equal (C) Heat of mixing is negligible (D) None of these

Last Answer : (D) None of these

Components, having widely different boiling point in a binary mixture, can be separated using __________ distillation. (A) Molecular (B) Extractive (C) Steam (D) Simple

Description : Components, having widely different boiling point in a binary mixture, can be separated using __________ distillation. (A) Molecular (B) Extractive (C) Steam (D) Simple

Last Answer : (D) Simple

Pick out the correct statement. (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non￾ideal binary system by distillation (B) A sharp decrease in pressure drop is an indication of flooding in a distillation coloumn (C) Solvent used in extractive distillation should be of high volatility (D) Flash distillation is suitable for separating components which have very close boiling temperature

Description : Pick out the correct statement. (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of ... Flash distillation is suitable for separating components which have very close boiling temperature

Last Answer : (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non￾ideal binary system by distillation

The boiling points of pure components of a binary system __________ with increase in total pressure of the system. (A) Decreases (B) Increases (C) Remains unchanged (D) May increase or decrease, depends on the system

Description : The boiling points of pure components of a binary system __________ with increase in total pressure of the system. (A) Decreases (B) Increases (C) Remains unchanged (D) May increase or decrease, depends on the system

Last Answer : (B) Increases

Which of the following statements is false? (A) Optimal binary search tree construction can be performed efficiently using dynamic programming. (B) Breadth-first search cannot be used to find connected components of a graph. (C) Given the prefix and postfix walks of a binary tree, the tree cannot be reconstructed uniquely. (D) Depth-first-search can be used to find the components of a graph. (1) A (2) B (3) C (4) D

Description : Which of the following statements is false? (A) Optimal binary search tree construction can be performed efficiently using dynamic programming. (B) Breadth-first search cannot be used to find connected components of a graph. (C) ... used to find the components of a graph. (1) A (2) B (3) C (4) D 

Last Answer : Answer: 2

Which will have greater molar conductivity ? Solution containing 1 mol KCl in 200 cc or 1 mol of KCl in 500 cc.

Description : Which will have greater molar conductivity ? Solution containing 1 mol KCl in 200 cc or 1 mol of KCl in 500 cc.

Last Answer : Ans. 1 mol of KCl in 500 cc. 

What laboratory procedure you would use to separate and recover the components of a mixture containing BaSO4 Na2CO3 and C10H8?

Description : What laboratory procedure you would use to separate and recover the components of a mixture containing BaSO4 Na2CO3 and C10H8?

Last Answer : Na2CO3 is soluble in water and separated by filtration from a water mixture.Naphtalene is separated by heating when sublimation occur.

Which of the following statements about the preparation and storage of blood components is/are true? A. Solutions containing citrate prevent coagulation by binding calcium. B. The shelf life of packed red blood cells preserved with CPDA-1 is approximately 35 days at 1؛ to 6؛ C. C. There are normal numbers of platelets in packed red blood cells stored at 1؛ to 6؛ C for more than 2 days. D. The storage lesion affecting refrigerated packed red blood cells includes development of acidosis, hyperkalemia, and decreased intracellular 2,3DPG (diphosphoglycerate).

Description : Which of the following statements about the preparation and storage of blood components is/are true? A. Solutions containing citrate prevent coagulation by binding calcium. B. The ... cells includes development of acidosis, hyperkalemia, and decreased intracellular 2,3DPG (diphosphoglycerate).

Last Answer : Answer: ABD DISCUSSION: After blood has been collected from a donor, it is anticoagulated with a solution containing citrate, which acts by binding calcium. Blood is then separated into its ... transfusion or produce effects other than those predicted based on the content of the unit of blood

The nurse teaches the patient with gastroesophageal reflux disease (GERD) which of the following measures to manage his disease? a) Avoid eating or drinking 2 hours before bedtime. The patient should not recline with a full stomach. b) Minimize intake of caffeine, ****, milk, and foods containing peppermint and spearmint. The patient should be instructed to avoid the listed foods and food components. c) Elevate the foot of the bed on 6- to 8-inch blocks The patient should be instructed to elevate the head of the bed on 6- to 8-inch blocks. d) Eat a low carbohydrate diet The patient is instructed to eat a low-fat diet

Description : The nurse teaches the patient with gastroesophageal reflux disease (GERD) which of the following measures to manage his disease? a) Avoid eating or drinking 2 hours before bedtime. The patient should not ... blocks. d) Eat a low carbohydrate diet The patient is instructed to eat a low-fat diet

Last Answer : a) Avoid eating or drinking 2 hours before bedtime. The patient should not recline with a full stomach.

What is volatile matter ?

Description : What is volatile matter ?

Last Answer : Substances which , when heat is applied, give a gaseous state directly from the solid state, and as a result of cooling, a hard state is obtained by re-gassing , are called volatile substances . Such as: naphthalene , iodine etc.

Spirit in contact with body gives cool sensation because it is – (1) liquid (2) transparent (3) highly volatile (4) a good conductor

Description : Spirit in contact with body gives cool sensation because it is – (1) liquid (2) transparent (3) highly volatile (4) a good conductor

Last Answer : (3) highly volatile Explanation: Spirit is very volatile. So when it is exposed, it evaporates rapidly to the air if released into the environment, producing a cool effect.

Which of the following type of coal has the lowest proportion of volatile matter? (1) Lignite (2) Peat (3) Bituminous (4) Anthracite

Description : Which of the following type of coal has the lowest proportion of volatile matter? (1) Lignite (2) Peat (3) Bituminous (4) Anthracite

Last Answer : (4) Anthracite Explanation: Anthracite has the lowest proportion of volatile matter. Volatile matter in coal refers to the components of coal, except for moisture, which are liberated at ... hydrocarbons and some sulfur. The volatile matter of coal is determined under rigidly controlled standards.

While separating a mixture of ortho and para-nitro phenols by steam distillation, name the isomer which will be steam volatile. Give reasons.

Description : While separating a mixture of ortho and para-nitro phenols by steam distillation, name the isomer which will be steam volatile. Give reasons.

Last Answer : In o-nitrophenol, there is intramolecular hydrogen bonding as follows : In p-nitrophenol, there is intramolecular hydrogen bonding as follows :   Due to intermolecular H ... -nitrophenol. Hence o-nitraphenol due to its lower b. p. is steam volatile while pnitrophenol is not.

Volatile hydrocarbons are not used in the brakes of automobile as lubricants, but non-volatile hydrocarbons are used as lubricants.

Description : Volatile hydrocarbons are not used in the brakes of automobile as lubricants, but non-volatile hydrocarbons are used as lubricants.

Last Answer : Ans.: The vapour pressure of volatile hydrocarbons is very high and they get evaporated leaving behind the system. Due to this they are not used as lubricants in automobiles. Nonvolatile hydrocarbons having low vapour pressure are used as lubricants.

Which of the following phrases is NOT appropriate for a description of benzene? w) characteristic reactivity of an alkene x) volatile liquid y) aromatic hydrocarbon z) resonance hybridization

Description : Which of the following phrases is NOT appropriate for a description of benzene? w) characteristic reactivity of an alkene x) volatile liquid y) aromatic hydrocarbon z) resonance hybridization

Last Answer : ANSWER: W -- CHARACTERISTIC REACTIVITY OF AN ALKENE

Spirit in contact with body gives cool sensation because it is : (1) liquid (2) transparent (3) highly volatile (4) a good conductor

Description : Spirit in contact with body gives cool sensation because it is : (1) liquid (2) transparent (3) highly volatile (4) a good conductor

Last Answer : highly volatile

Which of the following type of coal has the lowest proportion of volatile matter ? (1) Lignite (2) Peat (3) Bituminous (4) Anthracite

Description : Which of the following type of coal has the lowest proportion of volatile matter ? (1) Lignite (2) Peat (3) Bituminous (4) Anthracite

Last Answer : Anthracite