Why does H2O have a boiling point higher than H2S?

1 Answer

Answer :

Water (H20) has hydrogen bonding and London forces. Hydrogen sulfide (H2S) has only London forces. The reason why water has hydrogen bonding and hydrogen sulfide does not is because the oxygen in water is more electronegative than the sulfur in hydrogen sulfide. Hydrogen bonding only occurs between molecules that have hydrogen bonded to a very electronegative atom, which is either oxygen, fluorine, or nitrogen.Think about it: a hydrogen bond is a intermolecular attraction between the hydrogen of one atom and the lone pair of electrons of another atom. In order for the bond to exist the lone pair of electrons must belong to a electronegative atom, so there will be a great tendency for attraction.H2O is very strongly hydrogen bonded. These bonds require energy to break resulting in a higher

Related questions

Description : Why does H2O have a boiling point higher than H2S?

Last Answer : Water (H20) has hydrogen bonding and London forces. Hydrogen sulfide (H2S) has only London forces. The reason why water has hydrogen bonding and hydrogen sulfide does not is because the oxygen in ... .H2O is very strongly hydrogen bonded. These bonds require energy to break resulting in a higher

Description : Explain the following (a) The density of ice is less than that of liquid water? (b) The boiling point of water is less than that of H2S. (c) NaH has higher reducing character than H2O.

Last Answer : Ans-a) In structure of ice , Oxygen atom is tetrahedrally surrouneded by four hydrogen (with two hydrogen by hydrogen bond and with two hydrogen by covalent bond ) and have vacant spaces in ... Due to extensive hydrogen bonding in water c)NaH is ionic compound while water is a covalent compound

Description : Give reasons i) H2O is a liquid but H2S a gas. ii) Ammonia has higher boiling point than phosphine ii) Krypton & xenon make compounds.

Last Answer : Ans: i) Hydrogen bond is found in H2O but not in H2S.  ii) Hydrogen bond is found in NH3 but not in PH3.  iii) Because they have low ionization energy.

Description : Which type of intermolecular forces exists among the following molecules? (a) H2S molecules (b) H2O (c) Cl2 and CCl4 (d) SiH4 (e) Helium (f) He atoms and HCl molecules

Last Answer : Ans. (a) Dipole-Dipole interactions. (b)H-Bond. (c)Dispersion forces. (d)Dispersion forces. (e)Dispersion forces. (f)Induced dipole-dipole interactions.

Description : Which of the following compounds is the strongest base? w) NH3 x) PH3 y) H2O z) H2S

Last Answer : ANSWER: W -- NH3

Description : Which of the following compounds is the strongest acid? w) NH3 x) PH3 y) H2O z) H2S

Last Answer : ANSWER: Z -- H2S

Description : Consider three compounds : H2S, H2Se and H2O. Identify which has the highest boiling point. Justify.

Last Answer : Consider three compounds : H2S, H2Se and H2O. Identify which has the highest boiling point. Justify.

Description : The compound with the lowest boiling point is (a) H2O (b) CH3CH2OH (c) CH3OCH3 (d) CH3CH2CH3

Last Answer : CH3CH2CH3

Description : Out of (a) HNO3 + H2O and (b) C6H6 + C6H5CH3 which will form max. boiling azeotrope ?

Last Answer : (a) HNO3 + H2O.

Description : Compound (A) when reacted with PCl5 and then with ammonia gave (B). Compound (B) when treated with bromine and NaOH, produced (C). Compound (C) on treatment with NaNO2/HCl at 0°C and then boiling with H2O ... Compound (A) is (a) o-Toluic acid (b) o-Chlorotoluene (c) m-Toluic acid (d) o-Bromotoluene

Last Answer : o-Toluic acid

Description : Why is ethanol boiling at a higher boiling point than methyl ether boils at a lower boiling point despite the fact that they have the same molecular weight?

Last Answer : Need answer

Description : Why NH3 has a higher boiling point than CH4 and HCl?

Last Answer : Both NH3 and HCl exhibit hydrogen bonding as intermolecularforces, whereas CH4 does not. This makes CH4 have a lower boilingpoint. Since there are 3 hydrogen atoms in NH3 and only 1 inHCl(g), the intermolecular forces would be expected to be greaterin NH3 than in HCl.

Description : Which of the following is not a property of heavy water? (1) Boiling point of heavy water is lower than that or ordinary water (2) Density of heavy water is higher than that of ordinary water (3) Freezing point of heavy water is higher than that of ordinary water (4) It produces corrosion

Last Answer : (1) Boiling point of heavy water is lower than that or ordinary water Explanation: Heavy water, formally called deuterium oxide or 2H90 or D20, is a form of water that contains the hydrogen ... well: for instance heavy water used in CANDLE reactors is 99.75% enriched by hydrogen atom-fraction.

Description : steam distillation, the (A) Temperature is 100°C(B) Temperature is more than 100° C (C) Product must be immiscible with water (D) Temperature is higher than the boiling point of either component

Last Answer : (C) Product must be immiscible with water

Description : . A dilute aqueous solution is to be concentrated in an evaporator system. High pressure steam is available. Multiple effect evaporator system is employed, because (A) Total heat transfer area of ... in a single effect is much lower than that in any effect in a multi-effect system

Last Answer : (B) Total amount of vapor produced per Kg of feed steam in a multiple effect system is much higher than in a single effect

Description : Give reason for the higher melting point and boiling point of alkali earth metals than alkali metals. 

Last Answer : The melting and boiling points of these metals are higher than the corresponding alkali metals due to smaller sizes. 

Description : Which of the following is not a property of heavy water ? (1) Boiling point of heavy water is lower than that or ordinary water (2) Density of heavy water is higher than that of ordinary water (3) Freezing point of heavy water is higher than that of ordinary water (4) It produces corrosion

Last Answer : Boiling point of heavy water is lower than that or ordinary water

Description : Pick the wrong statement: hydrogen bonding results in (a) Increased solubility in water (b) Higher Van der Waal's forces (c) Molecular association (d) Abnormal boiling point

Last Answer : Ans:(b)

Description : Pressure Cooker cooks faster because (1) boiling point decreases with rise of pressure (2) it cooks the food at low pressure (3) higher temperature is attained for cooking (4) the material of the cooker is a good conductor

Last Answer : (3) higher temperature is attained for cooking Explanation: In pressure cooker boiling point of water increases due to high pressure.

Description : The boiling point of water decreases at higher altitudes is due to – (1) low temperature (2) low atmospheric pressure (3) high temperature (4) high atmospheric pressure

Last Answer : (2) low atmospheric pressure Explanation: At higher altitudes, the air pressure is decreased, which forces water's boiling point to lower. The air pressure decreases with altitude because of the ... of air. The lowered boiling point of water requires an increase in cooking times or temperature.

Description : In catalytic alkylation, higher iso-butane to olefin ratio gives (A) Low final boiling point product (B) Higher yield (C) Both (A) and (B) (D) Neither (A) nor (B

Last Answer : (A) Low final boiling point product

Description : Among Cis and Trans structure of Hex-2-ene which has higher boiling point and why?

Last Answer : Ans: The dipole moment of a molecule depends upon dipole-dipole interactions. Since cis-isomer has higher dipole moment, therefore it has higher boiling point.

Description : Name two isomers of butanol? Which has higher boiling point?

Last Answer : Ans. n-butanol and 2-methyl propan-2-ol.Butanol has the higher boiling point as the branching increases the surface area of the molecule decreases so the boiling point decreases.

Description : Use the information and data given below to answer the questions Stronger intermolecular forces result in higher boiling point Strength of London forces increases with the number of electrons in the molecule ... here? (c) Why is the boiling point of HF highest while that of HCl lowest?

Last Answer : Ans :( a) In the molecules HCl, HBr and HI, dipole-dipole interaction and London forces are present. (b) Dipole moment of HCl > HBr > HI but boiling point of HCl < HBr

Description : Glycerine is used as a coolant in cooling of some engines instead of water, because (A) Its higher boiling point (290°C) increases its heat carrying capacity (B) Comparatively less weight of coolant is required (C) Smaller radiator can be used (D) All a, b & c

Last Answer : (D) All a, b & c

Description : The distillation carried out in such a way that the liquid with the lowest boiling point is first evaporated and recondensed, then the liquid with the next higher boiling point is then evaporated and ... is called  A. cracking  B. carbonisation  C. fractional distillation  D. full distillation

Last Answer : Answer: C

Description : Safety aside, for which of the following reasons is alcohol used in preference to mercury in a minimum thermometer? w) Alcohol has a higher boiling point x) Alcohol has a lower freezing point y) Alcohol contracts more uniformly z) Alcohol can be dyed for visibility

Last Answer : ANSWER: X -- ALCOHOL HAS A LOWER FREEZING POINT

Description : Relative to the pure solvent, the boiling point of a solution is: w) higher x) lower y) at the same temperature

Last Answer : ANSWER: W -- HIGHER

Description : Compared to Chlorine, Bromine has: w) smaller atomic size x) higher density y) lower boiling point z) greater number of outer electrons

Last Answer : ANSWER: X -- HIGHER DENSITY

Description : The boiling point of water decreases at higher altitudes is due to (1) low temperature (2) low atmospheric pressure (3) high temprature (4) high atmospheric pressure

Last Answer : low atmospheric pressure

Description : Pressure Cooker cooks faster because (1) boiling point decreases with rise of pressure (2) it cooks the food at low pressure (3) higher temperature is attained for cooking (4) the material of the cooker is a good conductor

Last Answer : higher temperature is attained for cooking 

Description : Why H2S is a polar molecule?

Last Answer : S is more electronegative than H and also the molecule isasymmetric (not linear), so it will be polar.

Description : What is the compound polarity for H2S?

Last Answer : What is the answer ?

Description : Which reaction shows that the enthalpy of formation of H2S is Hf -20.6 kJmol?

Last Answer : H2(g) + S(s) —> H2S + 20.6 kJ

Description : The term ‘Cynogenesis’ describes the release of (a) hydrogen cyanide (HCN) (b) hydrochloric acid (HCl) (c) hydrogen peroxide (H202) (d) hydrogen sulphide (H2S)

Last Answer : Ans:(a)

Description : The major use of sulphur is in the manufacture of – (1) H2SO4 (2) H2S (3) SO2 (4) Fungicide

Last Answer : (1) H2SO4 Explanation: The major use of sulphur is in the manufacture of sulphuric acid (H2SO4) which is one of the most important compounds made by the chemical industry. It is used to make, literally, hundreds of compounds needed by almost every industry.

Description : Major gaseous pollutant of the thermal power station is – (1) H2S (2) NH3 (3) NO2 (4) SO2

Last Answer : (4) SO2 Explanation: A flue-gas stack is a type of chimney, a vertical pipe, channel or similar structure through which combustion product gases called flue gases are exhausted to the outside air ... CO2) and water vapor as well as nitrogen and excess oxygen remaining from the intake combustion air.

Description : In sewers the gas generally found, is A. Hydrogen sulphide (H2S) B. Carbon dioxide (CO2) C. Methane (CH4) D. All the above

Last Answer : ANS: D

Description : Which is obtained, when H2S is passed through the solution of sodium zincate?

Last Answer : ZnS

Description : What does mixture of CS2 and H2S on passing over heated copper give?

Last Answer : Methane

Description : Bog iron used for the adsorption of H2S from coke oven gas is (A) An intimate mixture of saw dust and iron dust (i.e. moist ferric hydroxide) (B) Iron impregnated with resin (usually Bakelite) (C) Carbon free iron (D) None of these

Last Answer : (A) An intimate mixture of saw dust and iron dust (i.e. moist ferric hydroxide)

Description : Which of the following is a suitable absorbent for removal of H2S from natural gas? (A) Vetrocoke solution (B) Monoethanolamine (MEA) (C) Dilute (D) Hot water

Last Answer : (B) Monoethanolamine (MEA)

Description : H2S present in naphtha reformed gas is removed by absorbing with (A) Ethanolamine (B) K2CO3 (C) HCl (D) Vacuum gas oi

Last Answer : (A) Ethanolamine

Description : H2S is being absorbed in a gas absorber unit. The height of the transfer unit based on the overall mass transfer coefficient on the gas side is 0.4 m. The equilibrium data is given by, y = 1.5 x. The bulk concentration of H2S ... by, y = 5x + 0.001 is (A) 2.0 (B) 1.56 (C) 1.0

Last Answer : (A) 2.0

Description : Which harmful gas is emitted by masonry building materials, even ground water? (a) H2S (b) Radon (c) Ammonia (d) CO2

Last Answer : (b) Radon

Description : The main constituent of biogas is (a) H2 (b) H2S (c) N2 (d) CH4

Last Answer : (d) CH4

Description : Which gas is released from paddy fields? a) CO2 b) H2S c) CH4 d) NH3

Last Answer : c) CH4

Description : Which adsorbent is used for removing sulphur compounds (S Q, H2S, RSH etc.) removal from coke oven gas in by-products recovery plant? (A) Silica gel (B) Diatomaceous earth (C) Basalt (D) Bog iron (i.e., moist ferric hydroxide)

Last Answer : (D) Bog iron (i.e., moist ferric hydroxide)

Description : Coke oven gas is stripped of its H2S and mercaptans content by (A) Absorption in wash oil (B) Adsorption on bog iron bed (C) Bubbling it through dilute sulphuric acid (D) Adsorption on silica gel

Last Answer : (B) Adsorption on bog iron bed

Description : Akiochi disease of rice is caused due to toxicity of — a. CH4 b. H2S c. CO2 d. NH4

Last Answer : b. H2S