Why NH3 has a higher boiling point than CH4 and HCl?

1 Answer

Answer :

Both NH3 and HCl exhibit hydrogen bonding as intermolecularforces, whereas CH4 does not. This makes CH4 have a lower boilingpoint. Since there are 3 hydrogen atoms in NH3 and only 1 inHCl(g), the intermolecular forces would be expected to be greaterin NH3 than in HCl.

Related questions

Description : Which of NH3 and HCl has higher prevalence rate and why ?

Last Answer : By the rate of diffusion of an object, we mean how much the object has spread through any medium at any given time. The lower the density of an object, the lower the molecular mass, the higher the rate of diffusion ... ( 36.5) is high. Thus the rate of diffusion of NH 3 is higher than that of HCl .

Description : Use the information and data given below to answer the questions Stronger intermolecular forces result in higher boiling point Strength of London forces increases with the number of electrons in the molecule ... here? (c) Why is the boiling point of HF highest while that of HCl lowest?

Last Answer : Ans :( a) In the molecules HCl, HBr and HI, dipole-dipole interaction and London forces are present. (b) Dipole moment of HCl > HBr > HI but boiling point of HCl < HBr

Description : Which was absent in the atmosphere at the time of origin of life? (a) NH3 (b) H2 (c) O2 (d) CH4

Last Answer : O2

Description : From his experiments, S.L. Miller produced amino acids by mixing the following in a closed flask. (a) CH4, H2, NH3 and water vapor at 800°C (b) CH3, H2, NH4 and water vapor at 800°C (c) CH4, H2, NH3 and water vapor at 600°C (d) CH3, H2, NH3 and water vapor at 600°C

Last Answer : a) CH4, H2, NH3 and water vapor at 800°C

Description : Which gas is released from paddy fields? a) CO2 b) H2S c) CH4 d) NH3

Last Answer : c) CH4

Description : Coke oven gas burns with a yellowish flame, because of the presence of (A) CO2 (B) CH4 (C) H2 (D) NH3

Last Answer : (B) CH4

Description : The worst enemy of ozone is a) Liquid NH3 b) SO2 c) CH4 d) CO.

Last Answer : c) CH4

Description : Which of the following molecules has a dipole moment? w) BF3 x) NH3 y) CCL4 z) CH4

Last Answer : ANSWER: B -- NH3

Description : Which of the following will have the lowest boiling point? (a) CH3Cl (b) CH4 (c) CH2Cl2 (d) CHCl3

Last Answer : CH4

Description : Which of the following compounds has the highest boiling point? w) CH4 x) CCL4 y) HI z) IF5

Last Answer : ANSWER: Z -- IF5

Description : Which of the following is a nonpolar molecule? (a) HCl (b) CH3Cl (c) H2 (d) NH3

Last Answer : H2

Description : In the Bayer's process, bauxite is digested under pressure using (A) H2SO4 (B) NaOH (C) NH3 (D) HCl

Last Answer : (B) NaOH

Description : Which of the following pairs of compounds could NOT be used to create a buffer solution? Would it be: w) HCL and NaCl (read: H - C - L and N - A - C - L) x) HCN and NaCN (read: H - C - N and N - A - C - N) y) NH3 ... - H - 4 - C - L) z) HNO2 and NaNO2 (read: H - N - O -2 and N - A - N - O - 2)

Last Answer : ANSWER: W -- HCL AND NaCl (read: H - C - L and N - A - C - L) 

Description : Who has the highest boiling point in HBr & HCl and why ?

Last Answer : answer:

Description : Which of the following compounds has the lowest boiling points? w) CH4 x) CCl4 y) PH3 z) PCl3

Last Answer : ANSWER: W -- CH4

Description : Compound (A) when reacted with PCl5 and then with ammonia gave (B). Compound (B) when treated with bromine and NaOH, produced (C). Compound (C) on treatment with NaNO2/HCl at 0°C and then boiling with H2O ... Compound (A) is (a) o-Toluic acid (b) o-Chlorotoluene (c) m-Toluic acid (d) o-Bromotoluene

Last Answer : o-Toluic acid

Description : Solvay process as compared to dual process (i.e. modified Solvay process). (A) Can use low grade brine (B) Has less corrosion problems (C) Involves higher investment in NH3 recovery units than that for crystallisation units for NH4Cl (D) Both (B) and (C)

Last Answer : (D) Both (B) and (C)

Description : Multistage operation (as in the case of catalytic oxidation of SO2 ) is not carried out for NH3 synthesis, because of (A) Comparatively higher pressure drop (B) High cost of the high pressure ... for the reactor (C) Higher pumping cost (D) Chances of entrainment and disturbance of catalyst bed

Last Answer : (B) High cost of the high pressure vessel used for the reactor

Description : For the reversible exothermic reaction, N2 + 3H2 ⇌ 2NH3, increase of pressure would (A) Shift the equilibrium towards right (B) Give higher yield of NH3 (C) Both (B) and (C) (D) Neither (A) nor (B)

Last Answer : (C) Both (B) and (C)

Description : Why is ethanol boiling at a higher boiling point than methyl ether boils at a lower boiling point despite the fact that they have the same molecular weight?

Last Answer : Need answer

Description : Why does H2O have a boiling point higher than H2S?

Last Answer : Water (H20) has hydrogen bonding and London forces. Hydrogen sulfide (H2S) has only London forces. The reason why water has hydrogen bonding and hydrogen sulfide does not is because the oxygen in ... .H2O is very strongly hydrogen bonded. These bonds require energy to break resulting in a higher

Description : Why does H2O have a boiling point higher than H2S?

Last Answer : Water (H20) has hydrogen bonding and London forces. Hydrogen sulfide (H2S) has only London forces. The reason why water has hydrogen bonding and hydrogen sulfide does not is because the oxygen in ... .H2O is very strongly hydrogen bonded. These bonds require energy to break resulting in a higher

Description : Which of the following is not a property of heavy water? (1) Boiling point of heavy water is lower than that or ordinary water (2) Density of heavy water is higher than that of ordinary water (3) Freezing point of heavy water is higher than that of ordinary water (4) It produces corrosion

Last Answer : (1) Boiling point of heavy water is lower than that or ordinary water Explanation: Heavy water, formally called deuterium oxide or 2H90 or D20, is a form of water that contains the hydrogen ... well: for instance heavy water used in CANDLE reactors is 99.75% enriched by hydrogen atom-fraction.

Description : Explain the following (a) The density of ice is less than that of liquid water? (b) The boiling point of water is less than that of H2S. (c) NaH has higher reducing character than H2O.

Last Answer : Ans-a) In structure of ice , Oxygen atom is tetrahedrally surrouneded by four hydrogen (with two hydrogen by hydrogen bond and with two hydrogen by covalent bond ) and have vacant spaces in ... Due to extensive hydrogen bonding in water c)NaH is ionic compound while water is a covalent compound

Description : Give reasons i) H2O is a liquid but H2S a gas. ii) Ammonia has higher boiling point than phosphine ii) Krypton & xenon make compounds.

Last Answer : Ans: i) Hydrogen bond is found in H2O but not in H2S.  ii) Hydrogen bond is found in NH3 but not in PH3.  iii) Because they have low ionization energy.

Description : steam distillation, the (A) Temperature is 100°C(B) Temperature is more than 100° C (C) Product must be immiscible with water (D) Temperature is higher than the boiling point of either component

Last Answer : (C) Product must be immiscible with water

Description : . A dilute aqueous solution is to be concentrated in an evaporator system. High pressure steam is available. Multiple effect evaporator system is employed, because (A) Total heat transfer area of ... in a single effect is much lower than that in any effect in a multi-effect system

Last Answer : (B) Total amount of vapor produced per Kg of feed steam in a multiple effect system is much higher than in a single effect

Description : Give reason for the higher melting point and boiling point of alkali earth metals than alkali metals. 

Last Answer : The melting and boiling points of these metals are higher than the corresponding alkali metals due to smaller sizes. 

Description : Which of the following is not a property of heavy water ? (1) Boiling point of heavy water is lower than that or ordinary water (2) Density of heavy water is higher than that of ordinary water (3) Freezing point of heavy water is higher than that of ordinary water (4) It produces corrosion

Last Answer : Boiling point of heavy water is lower than that or ordinary water

Description : Pick the wrong statement: hydrogen bonding results in (a) Increased solubility in water (b) Higher Van der Waal's forces (c) Molecular association (d) Abnormal boiling point

Last Answer : Ans:(b)

Description : Pressure Cooker cooks faster because (1) boiling point decreases with rise of pressure (2) it cooks the food at low pressure (3) higher temperature is attained for cooking (4) the material of the cooker is a good conductor

Last Answer : (3) higher temperature is attained for cooking Explanation: In pressure cooker boiling point of water increases due to high pressure.

Description : The boiling point of water decreases at higher altitudes is due to – (1) low temperature (2) low atmospheric pressure (3) high temperature (4) high atmospheric pressure

Last Answer : (2) low atmospheric pressure Explanation: At higher altitudes, the air pressure is decreased, which forces water's boiling point to lower. The air pressure decreases with altitude because of the ... of air. The lowered boiling point of water requires an increase in cooking times or temperature.

Description : In catalytic alkylation, higher iso-butane to olefin ratio gives (A) Low final boiling point product (B) Higher yield (C) Both (A) and (B) (D) Neither (A) nor (B

Last Answer : (A) Low final boiling point product

Description : Among Cis and Trans structure of Hex-2-ene which has higher boiling point and why?

Last Answer : Ans: The dipole moment of a molecule depends upon dipole-dipole interactions. Since cis-isomer has higher dipole moment, therefore it has higher boiling point.

Description : Name two isomers of butanol? Which has higher boiling point?

Last Answer : Ans. n-butanol and 2-methyl propan-2-ol.Butanol has the higher boiling point as the branching increases the surface area of the molecule decreases so the boiling point decreases.

Description : Glycerine is used as a coolant in cooling of some engines instead of water, because (A) Its higher boiling point (290°C) increases its heat carrying capacity (B) Comparatively less weight of coolant is required (C) Smaller radiator can be used (D) All a, b & c

Last Answer : (D) All a, b & c

Description : The distillation carried out in such a way that the liquid with the lowest boiling point is first evaporated and recondensed, then the liquid with the next higher boiling point is then evaporated and ... is called  A. cracking  B. carbonisation  C. fractional distillation  D. full distillation

Last Answer : Answer: C

Description : Safety aside, for which of the following reasons is alcohol used in preference to mercury in a minimum thermometer? w) Alcohol has a higher boiling point x) Alcohol has a lower freezing point y) Alcohol contracts more uniformly z) Alcohol can be dyed for visibility

Last Answer : ANSWER: X -- ALCOHOL HAS A LOWER FREEZING POINT

Description : Relative to the pure solvent, the boiling point of a solution is: w) higher x) lower y) at the same temperature

Last Answer : ANSWER: W -- HIGHER

Description : Compared to Chlorine, Bromine has: w) smaller atomic size x) higher density y) lower boiling point z) greater number of outer electrons

Last Answer : ANSWER: X -- HIGHER DENSITY

Description : The boiling point of water decreases at higher altitudes is due to (1) low temperature (2) low atmospheric pressure (3) high temprature (4) high atmospheric pressure

Last Answer : low atmospheric pressure

Description : Pressure Cooker cooks faster because (1) boiling point decreases with rise of pressure (2) it cooks the food at low pressure (3) higher temperature is attained for cooking (4) the material of the cooker is a good conductor

Last Answer : higher temperature is attained for cooking 

Description : Multiple Choice [1 point each] (1) The gases that contribute to the greenhouse effect on Earth are, in order of greatest to smallest in importance, (a) CO2, H20, CH4 (b) H20, CO2, CH4 (c) CH4, CO2, H20 (d) H20, CH4, CO2

Last Answer : (b) H20, CO2, CH4

Description : Which of the following refrigerants has lowest freezing point (a) Freon-12 (b) NH3 (c) CO2 (d) Freon-22

Last Answer : Ans: d

Description : Point group D3h belong to the molecule a. BF3 b. NH3 c. CHCl3 d. CH3

Last Answer : a. BF3

Description : Point group C2v belong to the molecule a. H2O b. BeH2 c. NH3 d. C2H2

Last Answer : a. H2O

Description : 31 Scalding with steam is more severe than scalding by boiling water because A. Steam can penetrate the skin B. Steam is at a higher temperature C. Steam contains more energy than boiling water D. Steam is at a higher pressure

Last Answer : ANSWER: C

Description : Scalding with steam is more severe than scalding by boiling water because (a) steam can penetrate the skin (b) steam is at a higher temperature (c) steam contains more energy than boiling water (d) steam is at a higher pressure

Last Answer : Ans:(c)

Description : Burns caused by steam are much severe than those caused by boiling water because – (1) Steam pierces through the pores of body quickly (2) Steam has latent heat (3) Steam is gas and engulfs the body quickly (4) Temperature of steam is higher

Last Answer : (2) Steam has latent heat Explanation: When water changes into steam, it absorbs latent heat, and when steam condenses to form water, it gives out an equal amount of latent heat. Bums caused ... boiling water, simply because steam contains more heat (in the form of latent heat) than boiling water.

Description : Pick out the wrong statement. (A) Lower boiling paraffins have higher octane number than higher paraffins (B) Dehydrogenation of naphthenes to aromatics is a desirable reaction in reforming ... is dearomatised kerosene (D) Catalyst used in catalytic reforming is platinum on silica-alumina base

Last Answer : (C) The most ideal feedstock for thermal reforming is dearomatised kerosene