First Law of Thermodynamics:
i) Closed System Cyclic Process :- It states that if a system executes a cycle, transferring work and heat through its boundary, the net heat transfer is equivalent to the network transfer and does not place any restriction on the direction of flow but the reversal of the process not violet the first law. According to this statement of first law the potential energy can be converted into kinetic energy and kinetic energy can be converted into potential energy but in natural practice this does not happen.
ii) Closed system Non cyclic process:- The principle of conservation of energy leads to first law of thermodynamics. This principle states that „energy can neither be created nor be destroyed though it can be transformed from one form to another form of energy. According to this law, when a system undergoes a change of state (thermodynamic process) both heat and work transfer takes place. The net energy transfer is stored within the system and is known as stored energy or total energy of system.
Q = ΔU + W