The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are:
(A) 1
(B) 2
(C) 3
(D) 0

1 Answer

Answer :

(B) 2

Related questions

Description : What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor? (A) 2 (B) 0 (C) 3 (D) 1

Last Answer : (A) 2

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

Description : For the liquid phase zero order irreversible reaction A → B, the conversion of A in a CSTR is found to be 0.3 at a space velocity of 0.1min -1 . What will be the conversion for a PFR with a space velocity of 0.2 min ... conditions are the same for CSTR and PFR. (A) 0.15 (B) 0.30 (C) 0.60 (D) 0.90

Last Answer : (C) 0.60

Description : What is the number of degree of freedom for a system of two miscible non-reacting species in vapor-liquid equilibrium forming an azeotrope? (A) 0 (B) 2 (C) 1 (D) 3

Last Answer : (C) 1

Description : What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope? (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (C) 2

Description : Can anyone help me with this? Chlorine and carbon monoxide gases are mixed in a 1.00L container and the following equilibrium is established: CO(g) + Cl2(g) COCl2(g).. Initially 1.5 mol of ... monoxide. At equilibrium, 0.8 mol of COCl2(g) was found. How do you calculate the percent reaction?

Last Answer : For a start, your equation isn't balanced; it should be Cl2 (Cl2, not 2Cl, because of HONClBrIF). Given this, if we assume the reaction goes to completion, 1.5 mol Cl2 will produce 1.5 mol ... .3% Incidentally, is that supposed to be CO or Co? It has no effect on the calculation, just curious.

Description : In case of absorption & stripping, the interface of the liquid & gas phases are present in equilibrium, when the diffusional resistance of __________ is zero. (A) Interface (B) Gas phase (C) Liquid phase (D) All 'a', 'b' & 'c'

Last Answer : (A) Interface

Description : At equilibrium the concentration of water in vapour phase (C* ) in kg/m3 of air space and the amount of water (m) adsorbed per kg of dry silica gel are related by, C* = 0.0667m. To maintain dry conditions in a room ... which the temperature is maintained constant) is (A) 0.0 (B) 0.2 (C) 0.4 (D) 1.0

Last Answer : (C) 0.4

Description : Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature. (A) Less than (B) More than (C) Equal to (D) Either (A) or (B); depends on the solid

Last Answer : (A) Less than

Description : Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is (A) 2 (B) 0 (C) 1 (D) 3

Last Answer : (A) 2

Description : Pure A in gas phase enters a reactor 50% of this A is converted to Bthrough the reaction, A → 3B. Mole fraction of A in the exit stream is (A) 1/2 (B) 1/3 (C) 1/4 (D) 1/5

Last Answer : (B) 1/3

Description : When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is (A) Same in both the phases (B) Zero in both the phases (C) More in vapour phase (D) More in liquid phase

Last Answer : (A) Same in both the phases

Description : When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is (A) More in vapour phase (B) More in liquid phase (C) Same in both the phases (D) Replaced by chemical potential which is more in vapour phase

Last Answer : (C) Same in both the phases

Description : If a two phase system is in physical equilibrium; then it means that, the (A) Escaping tendency of each component from the liquid phase to the vapor phase is exactly equal to that from vapor phase to liquid phase ... liquid phase is equal to that throughout the vapor phase (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Description : Pick out the wrong statement. (A) The controlling resistance in case of heating of air by condensing steam is in the air film (B) The log mean temperature difference (LMTD) for ... a pure fluid at a given pressure from liquid to vapor or vice-versa occurs at saturation temperature

Last Answer : (C) In case of a 1 - 2 shell and tube heat exchanger, the LMTD correction factor value increases sharply, when a temperature cross occurs

Description : Pick out the wrong statement. (A) Minimum number of degree of freedom of a system is zero (B) Degree of freedom of a system containing a gaseous mixture of helium, carbon ... ) Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation

Last Answer : (D) Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation

Description : Sodium reacts with water to form sodium hydroxide and hydrogen gas. The balanced equation which represents the above reaction is (a) Na(s) + 2H20(l) → 2NaOH(aq) + 2H2(g) (b) 2Na(s) + 2H2O(l) → 2NaOH(aq) +H2(g) (c) 2Na(s) + 2H20(l) → NaOH(aq) + 2H2(g) (d) 2Na(s) + H20(l) - 2NaOH(aq) + 2H2(g)

Last Answer : Answer: (b)

Description : The reaction A → B is conducted in an adiabatic plug flow reactor (PFR). Pure A at a concentration of 2 kmol/m3 is fed to the reactor at the rate of 0.01 m3 /s and at a temperature of 500 K. If the exit ... /kmole. K (may be assumed to be independent of temperature)) (A) 400 (B) 500 (C) 600 (D) 1000

Last Answer : (C) 600

Description : A 10m^3 vessel initially contains 5 m^3 of liquid water and 5 m^3 of saturated water vapor at 100 kPa. Calculate the internal energy of the system using the steam table.  A. 5 x10^5 kJ  B. 8x10^5 kJ  C. 1 ... 3 kJ/kg ug= 2506kJ/kg formula: Mvap = V vap/vg M liq = Vliq/ vƒ u =uƒM liq + ug M vap

Last Answer : 2 x10^6 kJ

Description : The fractional volume change between no conversion and complete conversion, for the isothermal gas phase reaction, 2A → R, is (A) 0.5 (B) -0.5 (C) 1 (D) 1.5

Last Answer : (B) -0.5

Description : The pressure of the vapor phase of a substance that is in equilibrium with the liquid or solid phase.  a. Phase Pressure  b. Equilibrium Vapor Pressure  c. Specific Pressure  d. Equilibrium Phase Pressure

Last Answer : Equilibrium Vapor Pressure

Description : A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume ... 2V (C) d(VCA )/dt = -FCA - kCA 2V (D) d(VCA )/dt = FCAF - kCA 2V

Last Answer : (D) d(VCA )/dt = FCAF - kCA 2V

Description : The conversion for a first order liquid phase reaction. A → B in a CSTRis 50%. If another CSTR of the same volume is connected in series, then the % conversion at the exit of the second reactor will be (A) 60 (B) 75 (C) 90 (D) 100

Last Answer : (B) 75

Description : Liquid "X" is at equilibrium with its vapor in a cylinder and piston apparatus. When the volume of the space above the liquid is 50 ml and the temperature 25!, the vapor pressure of "X" is 120 torr. What will the ... 25!C? Some liquid is always present. w) 30 torr x) 60 torr y) 120 torr z) 240 torr

Last Answer : ANSWER: Y -- 120 TORR

Description : A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is (A) 0.33 (B) 0.5 (C) 1 (D) Data insufficient, can't be predicted

Last Answer : (C) 1

Description : For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

Last Answer : (B) 0.338

Description : To maximise the formation of R in the simultaneous reaction A + B → R, rR = 2CA 0.5 .CB 2 A + B→ S, rS = 1.5 CA. CB We should have (A) Low CA , low CB (B) Low CA , high CB (C) High CA , low CB (D) High CA , high CB

Last Answer : (B) Low CA , high CB

Description : Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry

Last Answer : According to the formula ΔG° = -nFE° = – 2 × 96500 ×1.05 or ΔG° = -202650 J mol-1 = -202.65 KJ mol-1 Now ΔG° ⇒ -202650 J Mol-1 R = 8.314 J/Mol/K, T = 298 K

Description : At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm. ... (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f

Last Answer : (A) μ° + RT ln f

Description : Pick out the wrong statement (A) Co-current absorbers are usually used, when the gas to be dissolved in the liquid is a pure substance (B) In case of gas absorption, HETP is ... reaction (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process

Last Answer : (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process

Description : Identify the substances that are oxidised and the substances which are reduced in the following reactions. (i) 4Na(s) + O2(g) → 2Na2O(s) (ii) CuO (s) + H2(g) → Cu (s) + H2O(l) -Chemistry-10

Last Answer : (i) Substances oxidised is Na as it gains oxygen and oxygen is reduced. (ii) Substances reduced is Cu as hydrogen is oxidised as it gains oxygen.

Description : . The absorption factor is defined as (where, L = liquid flow rate, G = gas flow rate and, m = slope of the equilibrium line). (A) L/mG (B) G/mL (C) mL/G (D) LG/m

Last Answer : (A) L/mG

Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Description : The dimensions of rate constant for reaction 3A → B are (l/gm mole)/min. Therefore the reaction order is (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : (C) 2

Description : The correct sequence of phases of cell cycle is (a) G1 → S → G2 → M (b) M → G1 → G2 → S (c) G1 → G2 → S → M (d) S → G1 → G2 → M.

Last Answer : (a) G1 → S → G2 → M

Description : The necessary and sufficient condition for equilibrium between two phases is (A) The concentration of each component should be same in the two phases (B) The temperature of each phase should be same ( ... the two phases (D) The chemical potential of each component should be same in the two phases

Last Answer : (D) The chemical potential of each component should be same in the two phases

Description : The necessary condition for phase equilibrium in a multiphase system of N components is that the (A) Chemical potentials of a given component should be equal in all phases (B) Chemical potentials of all ... potentials of any given component in all the phases should be the same (D) None of these

Last Answer : (A) Chemical potentials of a given component should be equal in all phases

Description : Solid and liquid phases of a substance are in equilibrium at the (A) Critical temperature (B) Melting point (C) Freezing point (D) Both (B) and (C)

Last Answer : D) Both (B) and (C)

Description : A vessel with a volume of cubic meter contains liquid water and water vapor ion equilibrium at 600 kPa. The liquid water has mass of1kg. Using the steam table, calculate the mass of the water vapor.  A. 0.99kg  B. 1.57 kg  C ... / kg vg = 0.3157 m^3 / kg Vtot = mƒ vƒ + mg vg mg = (tot-mƒ vƒ) / vg

Last Answer : 3.16 kg

Description : The equilibrium liquid composition compared to the vapor composition in case of Azeotropic mixture is (A) More (B) Less (C) Same (D) Either more or less; depends on the system

Last Answer : (C) Same

Description : Clausius-Clapeyron equation is applicable to __________ equilibrium processes. (A) Solid-vapor (B) Solid-liquid (C) Liquid-vapor (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

Description : Molecularity of an elementary reaction, P + Q → R + S is (A) 1 (B) 2 (C) 3 (D) 4

Last Answer : (D) 4

Description : For the irreversible reaction, Ca+ 2C = Ca C2, Δ H°298 = - 60000 J . mole-1. If a system initially containing 2 moles of calcium, 3 moles of carbon and 1 mole of calcium carbide is allowed to react to completion, the heat evolved ... will be (A) 30,000 J (B) 60,000 J (C) 90,000 J (D) 2,40,000 J

Last Answer : (C) 90,000 J

Description : The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapour-liquid equilibrium, is (A) 3 (B) 1 (C) 2 (D) 0

Last Answer : B) 1

Description : What is the degree of freedom for a system comprising liquid water equilibrium with its vapour? (A) 0 (B) 1 (C) 2 (D) 3

Last Answer : B) 1

Description : The fractional volume change of the system for the isothermal gas phase reaction, A → 3B, between no conversion and complete conversion is (A) 0.5 (B) 1 (C) 2 (D) 3

Last Answer : (C) 2

Description : The composition of fresh feed to the high temperature, high pressure urea autoclave is (A) Excess liquid ammonia and liquefied CO2 (B) Excess liquid ammonia and compressed CO2 gas (C) Liquid ammonia and excess compressed CO2 (D) Compressed ammonia gas and excess compressed CO2

Last Answer : (B) Excess liquid ammonia and compressed CO2 gas