In which of the following reaction equilibrium, the value of equilibrium constant Kp will be more than is Kc? (A) 2HI ⇌ H2 + I2 (B) N2O4 ⇌ 2NO2 (C) 2SO2 + O2 ⇌ 2SO3 (D) None of these

In which of the following reaction equilibrium, the value of equilibrium constant Kp will be more than is Kc?
(A) 2HI ⇌ H2 + I2
(B) N2O4 ⇌ 2NO2
(C) 2SO2 + O2 ⇌ 2SO3
(D) None of these
by

1 Answer

Answer :

(B) N2O4 ⇌ 2NO2
by

Related questions

In which of the following gaseous phase reactions, the equilibrium of the reaction remains unaffected by pressure changes? (A) 2O3 ⇌ 3O2(B) N2 + O2 ⇌ 2NO (C) 2NO2 ⇌ N2O4 (D) 2SO2 + O2 ⇌ 2SO3

Description : In which of the following gaseous phase reactions, the equilibrium of the reaction remains unaffected by pressure changes? (A) 2O3 ⇌ 3O2 (B) N2 + O2 ⇌ 2NO (C) 2NO2 ⇌ N2O4 (D) 2SO2 + O2 ⇌ 2SO3

Last Answer : (B) N2 + O2 ⇌ 2NO

Which of the following chemical reactions will be favoured by low pressure? (A) 2HI ⇌ H2 + I2 (B) N2O2 ⇌ 2NO2 (C) N2 + O2 ⇌ 2NO (D) None of these

Description : Which of the following chemical reactions will be favoured by low pressure? (A) 2HI ⇌ H2 + I2 (B) N2O2 ⇌ 2NO2 (C) N2 + O2 ⇌ 2NO (D) None of these

Last Answer : (B) N2O2 ⇌ 2NO2

In multistage equilibrium conversion of SO2 to SO3 (2SO2 + O2 ⇌ 2SO3 ), the reverse reaction becomes appreciable at a temperature of 550° C. The percentage equilibrium conversion of SO2 to SO3 can be increased by (A) Increasing the oxygen concentration (B) Putting more quantity of V2O5 catalyst in the converter (C) Removing some quantity of SO3 during intermediate stage (D) Maintaining low temperature & pressure in the converter

Description : In multistage equilibrium conversion of SO2 to SO3 (2SO2 + O2 ⇌ 2SO3 ), the reverse reaction becomes appreciable at a temperature of 550° C. The percentage equilibrium conversion of SO2 to ... some quantity of SO3 during intermediate stage (D) Maintaining low temperature & pressure in the converter

Last Answer : (C) Removing some quantity of SO3 during intermediate stage

In the reaction, H2 +I2 ⇌ 2HI, addition of an inert gas will (A) Increase the partial pressure of H2 (B) Increase the partial pressure of I2 (C) Increase the total pressure and hence shift the equilibrium towards the right (D) Not affect the equilibrium conditions

Description : In the reaction, H2 +I2 ⇌ 2HI, addition of an inert gas will (A) Increase the partial pressure of H2 (B) Increase the partial pressure of I2 (C) Increase the total pressure and hence shift the equilibrium towards the right (D) Not affect the equilibrium conditions

Last Answer : (D) Not affect the equilibrium conditions Share

In case of the decomposition of hydroiodic acid (2HI ⇌ H2 + I2), addition of H2(at equilibrium condition) will (A) Increase the partial pressure of I2 (B) Decrease the partial pressure of HI (C) Diminish the degree of dissociation of HI (D) None of these

Description : In case of the decomposition of hydroiodic acid (2HI ⇌ H2 + I2), addition of H2(at equilibrium condition) will (A) Increase the partial pressure of I2 (B) Decrease the partial pressure of HI (C) Diminish the degree of dissociation of HI (D) None of these

Last Answer : (C) Diminish the degree of dissociation of HI

In the reaction, represented by, 2SO2 + O2 ⇌ 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by (A) Low temperature (B) High pressure (C) Both (A) and (B) (D) Neither (A) nor (B)

Description : In the reaction, represented by, 2SO2 + O2 ⇌ 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by (A) Low temperature (B) High pressure (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) and (B)

If in the gaseous phase reaction, N2O4 ⇌ 2NO2 , x is the part of N2O4 which dissociates, then the number of molecules at equilibrium will be (A) (1 + x) (B) (1 - x) (C) (1 + x) 2 (D) (1 - x)

Description : If in the gaseous phase reaction, N2O4 ⇌ 2NO2 , x is the part of N2O4 which dissociates, then the number of molecules at equilibrium will be (A) (1 + x) (B) (1 - x) (C) (1 + x) 2 (D) (1 - x)

Last Answer : (A) (1 + x)

The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is :

Description : The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is :

Last Answer : The relation between Kc and Kp for the reaction A(g) + B(g) ⇌ 2C(g) + D(g) is : a. Kc = Kp/RT b. Kp ... Kc = \(\frac{1}{\sqrt{Kp}}\) d. Kp/Kc = 1

In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Description : In the gaseous phase ammonia formation reaction (N2 + 3H2 ⇌ 2NH3 ), the value of the equilibrium constant depends on the (A) Total pressure of the system (B) Volume of the reactor (C) Temperature (D) Initial concentration of N2 and H2

Last Answer : (C) Temperature

In the reaction; N2 + O2 ⇌ 2NO, increasing the pressure will result in (A) Shifting the equilibrium towards right (B) Shifting the equilibrium towards left (C) No change in equilibrium condition (D) None of these

Description : In the reaction; N2 + O2 ⇌ 2NO, increasing the pressure will result in (A) Shifting the equilibrium towards right (B) Shifting the equilibrium towards left (C) No change in equilibrium condition (D) None of these

Last Answer : (C) No change in equilibrium condition

The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving force. and, Kp= M.T.C. for diffusion of a gas through a stagnant inert gas with pressure as driving force.) (A) Kc = Kp = Km (B) Kc = Kp /RT = Km . RT/P (C) Kc = Kp . RT = Km . RT/p (D) None of these

Description : The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving ... (C) Kc = Kp . RT = Km . RT/p (D) None of these

Last Answer : (C) Kc = Kp . RT = Km . RT/p

What is the relationship b/w kc, kp kc & kn?

Description : What is the relationship b/w kc, kp kc & kn?

Last Answer : These four parameters are related as. Kp = Kc (RT)n = Kx (P)n = Kn When mole of products are reactant are equal i.e. n = 0 their Kp = kc = dx = kn

What number of moles of O2 is required to react with 3.6 mol SO2 in the following reaction 2S02 plus O2 2SO3?

Description : What number of moles of O2 is required to react with 3.6 mol SO2 in the following reaction 2S02 plus O2 2SO3?

Last Answer : 1,8 of moles of O2 are required.

Consider the reaction, C + O2 ⇌ CO2; ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO2 → C + O2? (A) -94 kcal (B) +94 kcal (C) > 94 kcal (D) < -94 kcal

Description : Consider the reaction, C + O2 ⇌ CO2; ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO2 → C + O2? (A) -94 kcal (B) +94 kcal (C) > 94 kcal (D) < -94 kcal

Last Answer : (B) +94 kcal

Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry

Description : Determine the values of equilibrium constant (Kc) and ΔG° for the following reaction : Ni(s) + 2Ag+ (aq) → Ni2+ (aq) + 2Ag(s), E° = 1.05 V (1F = 96500 C mol-1 -Chemistry

Last Answer : According to the formula ΔG° = -nFE° = – 2 × 96500 ×1.05 or ΔG° = -202650 J mol-1 = -202.65 KJ mol-1 Now ΔG° ⇒ -202650 J Mol-1 R = 8.314 J/Mol/K, T = 298 K

Given, 3H2 + CO = CH4 + H2O, KP = 10 1.84 and, 4H2 + CO2 = CH4 + 2H2O, KP = 10 1.17 the KP for the reaction CO + H2O = CO2 + H2 is (A) 10 3.01 (B) 10 -0.67 (C) 10 -3.01 (D) 10 0.67

Description : Given, 3H2 + CO = CH4 + H2O, KP = 10 1.84 and, 4H2 + CO2 = CH4 + 2H2O, KP = 10 1.17 the KP for the reaction CO + H2O = CO2 + H2 is (A) 10 3.01 (B) 10 -0.67 (C) 10 -3.01 (D) 10 0.67

Last Answer : (D) 10 0.67

The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637

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With increase in temperature, the equilibrium constant at constant pressure (Kp) for oxidation of sulphur dioxide (A) Increases(B) Increases linearly(C) Decreases(D) Decreases linearly

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Last Answer : (C) Decreases

Which of the following is not a unit of the equilibrium constant Kp? (where, Δx = number of moles of products number of moles of reactants) (A) (atm)Δx, when Δx is negative (B) (atm)Δx, when Δx is positive (C) Dimensionless, when Δx = 0 (D) (atm)Δx2, when Δx > 0

Description : Which of the following is not a unit of the equilibrium constant Kp? (where, Δx = number of moles of products number of moles of reactants) (A) (atm)Δx, when Δx is negative (B) (atm)Δx, when Δx is positive (C) Dimensionless, when Δx = 0 (D) (atm)Δx2, when Δx > 0

Last Answer : (D) (atm)Δx2, when Δx > 0

Forward reaction will be favoured for the exothermic reaction, represented by CO + H2O ⇌ CO2 + H2, by (A) Low temperature and high pressure (B) Low temperature and low pressure (C) High temperature and high pressure (D) High temperature and low pressure

Description : Forward reaction will be favoured for the exothermic reaction, represented by CO + H2O ⇌ CO2 + H2, by (A) Low temperature and high pressure (B) Low temperature and low pressure (C) High temperature and high pressure (D) High temperature and low pressure

Last Answer : (A) Low temperature and high pressure

The effect of increasing pressure on the gaseous equilibrium of the reaction2X + 3Y ⇌ 3X + 2Y indicates that(A) Pressure has no effect(B) Backward reaction is favoured(C) Forward reaction is favoured(D) None of the

Description : The effect of increasing pressure on the gaseous equilibrium of the reaction2X + 3Y ⇌ 3X + 2Y indicates that (A) Pressure has no effect (B) Backward reaction is favoured (C) Forward reaction is favoured (D) None of the

Last Answer : (A) Pressure has no effect

For the reversible exothermic reaction, N2 + 3H2 ⇌ 2NH3, increase of pressure would (A) Shift the equilibrium towards right (B) Give higher yield of NH3 (C) Both (B) and (C) (D) Neither (A) nor (B)

Description : For the reversible exothermic reaction, N2 + 3H2 ⇌ 2NH3, increase of pressure would (A) Shift the equilibrium towards right (B) Give higher yield of NH3 (C) Both (B) and (C) (D) Neither (A) nor (B)

Last Answer : (C) Both (B) and (C)

When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will :

Description : When volume of the equilibrium reaction C(s) + H2O(g) ⇌ CO(g) + H2(g) is increased at constant temperature the equilibrium will :

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On application of pressure to the equilibrium system, ice ⇌ water; which of the following phenomenon will occur? (A) Water will evaporate (B) Equilibrium will not be attained (C) More ice will be formed (D) More water will be formed

Description : On application of pressure to the equilibrium system, ice ⇌ water; which of the following phenomenon will occur? (A) Water will evaporate (B) Equilibrium will not be attained (C) More ice will be formed (D) More water will be formed

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If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 (as per Le Chatelier's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

Description : If helium is introduced in a reactor containing O2 , SO2 and SO3 at equilibrium, so that total pressure increases while volume and temperature remains constant. In this case the dissociation of SO3 ( ... 's principle). (A) Decreases (B) Increases (C) Remains unaltered (D) Changes unpredictably

Last Answer : (A) Decreases

(a) What are fuel cells? Explain the electrode reactions involved in the working of H2 – O2 fuel cell. (b) Represent the galvanic cell in which the reaction Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s) takes place. -Chemistry

Description : (a) What are fuel cells? Explain the electrode reactions involved in the working of H2 – O2 fuel cell. (b) Represent the galvanic cell in which the reaction Zn (s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s) takes place. -Chemistry

Last Answer : (a) Fuel cells : These cells are the devices which convert the energy produced during combustion of fuels like H2, CH4, etc. directly into electrical energy. The electrode reaction for H2 – O2 fuel cell : (b) The galvanic cell may be represented as Zn (s) | Zn2+ (1M) || Cu2+ (1M) | Cu (s)

What of the following reactions demonstrates a synthesis reaction A) Mg plus H2SO4 and gt MgSO4 plus H2 B) 2NaCl and gt 2Na plus Cl2 C) C plus O2 and gt CO2 D) Zn plus 2HCl and gt ZnCl2 plus H2?

Description : What of the following reactions demonstrates a synthesis reaction A) Mg plus H2SO4 and gt MgSO4 plus H2 B) 2NaCl and gt 2Na plus Cl2 C) C plus O2 and gt CO2 D) Zn plus 2HCl and gt ZnCl2 plus H2?

Last Answer : C+O2 →CO2

How value of Kc can help to predict the extent to which a chemical reaction can take place?

Description : How value of Kc can help to predict the extent to which a chemical reaction can take place?

Last Answer : The extent of reaction depends upon the magnitude of Kc. i.e. (i) Very small value of Kc: when Kc is very small the forward reaction will not occur to an appreciable extent ... neither very large nor very small, the equilibrium mixture contains appreciable amounts of both reactant and products.

For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium is disturbed by ………..

Description : For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium is disturbed by ………..

Last Answer : For the equilibrium Cl2(g) + 2NO(g) ⇌ 2NOCl(g) the concentration of NOCl will increase if the equilibrium ... NO c. adding NOCl d. removal of Cl2

The equilibrium, H2O(l) ⇌ H^+(aq) + OH^-(aq) is :

Description : The equilibrium, H2O(l) ⇌ H^+(aq) + OH^-(aq) is :

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In the equation P = PS/[1 + loge -1 (nt)] of a logistic curve of population growth, the constant m is (A) Ps × P (B) PS /P (C) (PS - Po)/Po (D) KP

Description : In the equation P = PS/[1 + loge -1 (nt)] of a logistic curve of population growth, the constant m is (A) Ps × P (B) PS /P (C) (PS - Po)/Po (D) KP

Last Answer : (C) (PS - Po)/Po

Main constituents of purified Lurgi gas are (A) H2 , CmHn & CO2 (B) CO, H2 & CH4 (C) CO2 , O2 & CO (D) N2 , H2 & CO2

Description : Main constituents of purified Lurgi gas are (A) H2 , CmHn & CO2 (B) CO, H2 & CH4 (C) CO2 , O2 & CO (D) N2 , H2 & CO2

Last Answer : (B) CO, H2 & CH4

L.D. converter gas (produced in steel plant) comprises mainly of (A) CO (upto 65%) & CO2 (B) CO2 & H2 (C) CO & O2 (D) CO2 & O2

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Last Answer : (A) CO (upto 65%) & CO2

Naphtha in a fertiliser plant is used as a source of (A) Fuel (B) H2 (C) N2 (D) O2

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Last Answer : (B) H2

The essential ingredient of all the synthesis gas is (A) H2 (B) O2 (C) CO2 (D) N2

Description : The essential ingredient of all the synthesis gas is (A) H2 (B) O2 (C) CO2 (D) N2

Last Answer : (A) H

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Last Answer : (D) Cl2 , H2 & NaOH solution

Which of the following behaves most closely like an ideal gas? (A) He (B) N2 (C) O2 (D) H2

Description : Which of the following behaves most closely like an ideal gas? (A) He (B) N2 (C) O2 (D) H2

Last Answer : (A) He

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Last Answer : Option B

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Description : The lightest non-inflammable gas is (A) H2 (B) He (C) Ar (D) O2

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Description : For a heterogeneous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is (A) Surface Kc /(1 + TS ) ... A and absorbed B (C) Surface reaction between A in the gas phase and absorbed B (D) Desorption of C

Last Answer : (D) Desorption of C

According to Manning's formula, the discharge through an open channel is (where M = Manning's constant) (A) A × M × m 1/2 × i2/3 (B) A × M × m 2/3 × i1/2 (C) A 1/2 × M 2/3 × m × i (D) A 2/3 × M 1/3 × m ×

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Last Answer : Answer: Option B

Considering the endothermic dissociation of CaCO3 in a closed vessel (CaCO3 ⇌ CaO + CO2 ), the pressure of CO2 increases, if (A) A catalyst is added (B) The temperature is increased (C) An inert gas is pumped keeping the temperature constant (D) None of these

Description : Considering the endothermic dissociation of CaCO3 in a closed vessel (CaCO3 ⇌ CaO + CO2 ), the pressure of CO2 increases, if (A) A catalyst is added (B) The temperature is increased (C) An inert gas is pumped keeping the temperature constant (D) None of these

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Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of an inert gas at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

Description : Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will (A) Decrease on addition of Cl2 (B) Increase on addition of ... at constant pressure (C) Decrease on increasing the pressure of the system (D) None of these

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Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Description : Aniline is prepared by (a) the reaction of benzene with ammonia (b) the reduction of nitrobenzene with Sn/HCl (c) the dehydrogenation of nitrobenzene (d) the reaction of nitrobenzene with I2/NaOH

Last Answer : the reduction of nitrobenzene with Sn/HCl

The critical radius of insulation for cylindrical pipe is (where, hi = heat transfer coefficient at inside of the pipe) (A) K/h0 (B) 2K/h0 (C) hi /K (D) 2hi /K

Description : The critical radius of insulation for cylindrical pipe is (where, hi = heat transfer coefficient at inside of the pipe) (A) K/h0 (B) 2K/h0 (C) hi /K (D) 2hi /K

Last Answer : (A) K/h0

Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the reaction is practically irreversible in nature (C) The intercept of the Arrhenius plot is called the 'activation energy' (D) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Description : Pick out the wrong statement. (A) A particular chemical reaction is more temperature sensitive at low temperatures (B) A very high value of equilibrium constant, K (K >> 1) indicates that the ... ) Non-ideal flow takes place in reactors due to recycling, channeling or by creation of stagnant regions

Last Answer : (C) The intercept of the Arrhenius plot is called the 'activation energy

If heat contents of CH4, C2H4 and C3H8 are -17.9, 12.5 and -24.8 kcal/mole respectively, than ΔH for the reaction CH4(g) + C2H4(g) ⇌ C3H8(g) will be __________ Kcal. (A) -19.4 (B) -30.2 (C) 55.2 (D) -55.2

Description : If heat contents of CH4, C2H4 and C3H8 are -17.9, 12.5 and -24.8 kcal/mole respectively, than ΔH for the reaction CH4(g) + C2H4(g) ⇌ C3H8(g) will be __________ Kcal. (A) -19.4 (B) -30.2 (C) 55.2 (D) -55.2

Last Answer : (A) -19.4

Identify the substances that are oxidised and the substances which are reduced in the following reactions. (i) 4Na(s) + O2(g) → 2Na2O(s) (ii) CuO (s) + H2(g) → Cu (s) + H2O(l) -Chemistry-10

Description : Identify the substances that are oxidised and the substances which are reduced in the following reactions. (i) 4Na(s) + O2(g) → 2Na2O(s) (ii) CuO (s) + H2(g) → Cu (s) + H2O(l) -Chemistry-10

Last Answer : (i) Substances oxidised is Na as it gains oxygen and oxygen is reduced. (ii) Substances reduced is Cu as hydrogen is oxidised as it gains oxygen.

Which of the following molecules contains a polar covalent bond A.H2 B.N2 C.CO D.O2?

Description : Which of the following molecules contains a polar covalent bond A.H2 B.N2 C.CO D.O2?

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