Description : For spontaneous changes in an isolated system (S = entropy) (A) ds = 0 (B) ds 0 (D) ds = Constant
Last Answer : (C) ds > 0
Description : For the reversible reaction A ⇌ 2B, if the equilibrium constant K is 0.05 mole/litre; starting from initially 2 moles of A and zero moles of B, how many moles will be formed at equilibrium? (A) 0.253 (B) 0.338 (C) 0.152 (D) 0.637
Last Answer : (B) 0.338
Description : In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants) (A) Addition of inert gas favours the forward reaction, when Δx is positive (B) Pressure has no effect on equilibrium, when Δn = ... any value of Δx (+ ve, - ve) or zero) (D) All 'a', 'b' & 'c'
Last Answer : D) All 'a', 'b' & 'c'
Description : Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased ... condition is the change in Helmholtz free energy (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : The equilibrium constant for the reversible reaction as shown in the bellow figure, is affected by the (A) Temperature of the system (B) Presence or absence of inerts (C) Pressure of the system (D) Kinetics of the reaction
Last Answer : (C) Pressure of the system
Description : A control volume refers to what? a. A fixed region in space b. A reversible process c. an isolated system d. a specified mass
Last Answer : A fixed region in space
Description : What is referred to by control volume? a. An isolated system b. Closed system c. Fixed region in space d. Reversible process only
Last Answer : Fixed region in space
Description : In a reversible chemical reaction having two reactants in equilibrium, if the concentration of the reactants are doubled, then the equilibrium constant will (A) Remain the same (B) Be halved (C) Also be doubled (D) Become one fourth
Last Answer : (A) Remain the same
Description : The irreversible reaction is a special case of reversible reaction, if the(A) Equilibrium constant is 1 (B) Conversion of the reactant at equilibrium condition is zero (C) Reactant concentration at equilibrium condition is zero (D) All (A), (B) and (C)
Last Answer : (C) Reactant concentration at equilibrium condition is zero
Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric coefficients of the reaction
Last Answer : (B) Increases with pressure
Description : The irreversible reaction, X → Y, is the special case of the reversible reaction, X ⇌ Y, in which the (A) Equilibrium constant is infinite (B) Fractional conversion of 'A' at equilibrium is unity (C) Concentration of 'A' at equilibrium is zero (D) All (A), (B) and (C)
Description : Catalyst is a substance, which __________ chemical reaction. (A) Increases the speed of a (B) Decreases the speed of a (C) Can either increase or decrease the speed of a (D) Alters the value of equilibrium constant in a reversible
Last Answer : (C) Can either increase or decrease the speed of a
Description : Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be (A) Same (B) Doubled (C) Halved (D) One fourth of its original value
Last Answer : (A) Same
Description : Identify the INCORRECT statement below regarding chemical equilibrium. A All chemical reactions are, in principle, reversible. B Equilibrium is achieved when the forward reaction rate equals the ... equilibrium constant. E Equilibrium is achieved when reactant and product concentrations are equal.
Last Answer : E Equilibrium is achieved when reactant and product concentrations are equal.
Description : In case of a reversible process (following pvn = constant), work obtained for trebling the volume (v1 = 1 m3 and v23 m3) is maximum, when the value of 'n' is (A) 0 (B) 1 (C) y = 1.44 (D) 1.66
Last Answer : (A) 0
Description : In the equation, PVn = Constant, if the value of n = 0, then it represents a reversible __________ process. (A) Isobaric (B) Isothermal (C) Isentropic (D) Isometric
Last Answer : (A) Isobaric
Description : For a constant pressure reversible process, the enthalpy change (ΔH) of the system is (A) Cv.dT (B) Cp.dT (C) ∫ Cp.dT (D) ∫ Cv.dT
Last Answer : (C) ∫ Cp.dT
Description : Pick out the wrong statement. (A) The net change in entropy in any reversible cycle is always zero (B) The entropy of the system as a whole in an irreversible process increases (C) The ... to a maximum (D) The entropy of a substance does not remain constant during a reversible adiabatic change
Last Answer : (D) The entropy of a substance does not remain constant during a reversible adiabatic change
Description : In the equation, PVn = constant, if the value of n is in between 1 and y (i.e. Cp/Cv), then it represents a reversible __________ process. (A) Isometric (B) Polytropic (C) Isentropic (D) Isobaric
Last Answer : (B) Polytropic
Description : With decrease in temperature, the equilibrium conversion of a reversible endothermic reaction (A) Decreases (B) Increases (C) Remain unaffected (D) Increases linearly with temperature
Last Answer : (A) Decreases
Description : Pick out the wrong statement. (A) Use of different catalysts in a reversible catalytic chemical reaction does not change the equilibrium composition (B) Alumina is added as a promoter to ... Arrhenius plot (D) Presence of inerts affects the equilibrium conversion of reactants in a chemical reaction
Last Answer : (C) Activation energy for a reaction is obtained from the intercept of the Arrhenius plot
Description : Promoter (A) Initiates a chemical reaction and is a catalyst by itself (B) Alters the position of equilibrium in a reversible reaction (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals (D) All (A), (B) and (C)
Last Answer : (C) Increases the number of active centres by increasing the unevenness of catalyst surface and by creating discontinuities in the crystals
Description : Pick out the wrong statement. (A) A catalyst does not alter the final position of equilibrium in a reversible reaction (B) A catalyst initiates a reaction (C) A catalyst is specific in reaction (D) A catalyst remains unchanged in chemical composition at the end the reaction
Last Answer : (B) A catalyst initiates a reaction
Description : For the reversible exothermic reaction, N2 + 3H2 ⇌ 2NH3, increase of pressure would (A) Shift the equilibrium towards right (B) Give higher yield of NH3 (C) Both (B) and (C) (D) Neither (A) nor (B)
Last Answer : (C) Both (B) and (C)
Description : Change in internal energy in a closed system is equal to heat transferred if the reversible process takes place at constant (a) pressure (b) temperature (c) volume (d) internal energy (e) entropy.
Last Answer : Answer : c
Description : Change in enthalpy in a closed system is equal to heat transferred if the reversible process takes place at constant (a) pressure (b) temperature (c) volume (d) internal energy (e) entropy.
Last Answer : Answer : a
Description : A system in which there is a flow of mass is known as _____. A. Equilibrium system B. Isolated system C. Open system D. Closed system
Last Answer : Open system
Description : An isentropic process is the one, in which (A) pv = constant (B) pv r= constant (C) pv r = constant, and process is reversible (D) None of these
Last Answer : (C) pv r = constant, and process is reversible
Description : Which of the following is not correct for a reversible adiabatic process? (A) TV γ-1 = constant (B) p 1-γ .T Y = constant (C) PV γ = constant (D) None of these
Last Answer : (D) None of these
Description : In polytropic process (PV n = constant), if n = 1; it means a/an __________ process. (A) Adiabatic (B) Reversible (C) Isothermal (D) None of these
Last Answer : (C) Isothermal
Description : What happens in a reversible adiabatic expansion process? (A) Heating takes place (B) Cooling takes place (C) Pressure is constant (D) Temperature is constant
Last Answer : (B) Cooling takes place
Description : PVy = constant, holds good for an isentropic process, which is (A) Reversible and isothermal (B) Isothermal and irreversible (C) Reversible and adiabatic (D) Adiabatic and irreversible
Last Answer : C) Reversible and adiabatic
Description : In the equation, PVn = constant, if the value of n = ± ∞, then it represents a reversible __________ process. (A) Adiabatic (B) Isometric (C) Isentropic (D) Isothermal
Last Answer : (B) Isometric
Description : Pick out the wrong statement: (A) The expansion of a gas in vacuum is an irreversible process (B) An isometric process is a constant pressure process (C) Entropy change for a reversible adiabatic process is zero (D) Free energy change for a spontaneous process is negative
Last Answer : (B) An isometric process is a constant pressure process
Description : Throttling process is a/an __________ process. (A) Reversible and isothermal (B) Irreversible and constant enthalpy (C) Reversible and constant entropy (D) Reversible and constant enthalpy
Last Answer : (B) Irreversible and constant enthalpy
Description : In the equation PVn = constant, if the value of n = y = Cp/Cv, then it represents a reversible __________ process. (A) Isothermal (B) Adiabatic (C) Isentropic (D) Polytropic
Last Answer : (C) Isentropic
Description : In the equation, PVn = constant, if the value of n = 1, then it represents a reversible __________ process. (A) Isothermal (B) Isobaric (C) Polytropic (D) Adiabatic
Last Answer : (A) Isothermal
Description : Which of the following is not a reversible process? (A) Expansion of an ideal gas against constant pressure (B) Atmospheric pressure vaporisation of water at 100°C (C) Solution of NaCl in water at 50°C (D) None of these
Last Answer : C) Solution of NaCl in water at 50°C
Description : Is chemical equilibrium reversible?
Last Answer : Need answer
Description : Adiabatic process is (A) Essentially an isentropic process is___________ (B) Non-heat transfer process (C) Reversible process (D) Constant temperature process
Last Answer : (B) Non-heat transfer process
Description : Which of the following occurs in a reversible polytrophic process? a. Enthalpy remains constant b. Internal energy does not change c. Some heat transfer occurs d. Entropy remains constant
Last Answer : Some heat transfer occurs
Description : Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance ... temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these
Last Answer : (B) 1
Description : A piston filled with `0.04` mole of an ideal gas expands reversible from `50.0mL` at a constant temperature of `37.0^(@)C` . As it does so, it absorbs
Last Answer : A piston filled with `0.04` mole of an ideal gas expands reversible from `50.0mL` at a constant temperature of `37. ... J` D. `q= +208 J, w=+208 J`
Description : If the forward rate constant of reversible reaction is 0.16 and backward rate constant is `4xx10^(4)` , then the equilibrum constant will be .
Last Answer : If the forward rate constant of reversible reaction is 0.16 and backward rate constant is `4xx10^(4)` , then the ... C. `4xx10^(-6)` D. `4xx10^(-5)`
Description : The expression, ∆G = nRT. ln(P2/P1), gives the free energy change (A) With pressure changes at constant temperature (B) Under reversible isothermal volume change (C) During heating of an ideal gas (D) During cooling of an ideal gas
Last Answer : (A) With pressure changes at constant temperature
Description : Entropy of a substance remains constant during a/an __________ change. (A) Reversible isothermal (B) Irreversible isothermal (C) Reversible adiabatic (D) None of these
Last Answer : (C) Reversible adiabatic
Description : What happens in a reversible adiabatic compression? (A) Heating occurs (B) Cooling occurs (C) Pressure is constant (D) Temperature is constant
Last Answer : A) Heating occurs
Description : In a reversible process (A) Tds = dE + dW (B) dE - dW = Tds (C) dW - dE = Tds (D) Tds - dW + dE >0
Last Answer : (A) Tds = dE + dW
Description : For a reversible process involving only pressure-volume work (A) (dF)T, p < 0 (B) (dF)T, p > 0 (C) (dF)T, p = 0 (D) (dA)T, v < 0
Last Answer : (C) (dF)T, p = 0
Description : Assertion :- Entropy is always constant for a closed system. Reason :- Closed system is always reversible.
Last Answer : Assertion :- Entropy is always constant for a closed system. Reason :- Closed system is always ... D. If both Assertion & Reason are false.