Although thermodynamically feasible, in practice, Magnesium metal is not used for the reduction of Alumina in the metallurgy of aluminium.Why?

1 Answer

Answer :

Ans. : Below the temperature(1623 K) correspoinding to the point of intersection of Al 2O3 and MgO curves in Ellingham diagram, Magnesium can reduce Alumina because the ΔfG o value of Al2O3 at temperatures below 1623 K, is less negative than that of MgO. Therefore below 1623 K Mg can reduce Al2O3 to Al. But Magnesium is much costier metal than Aluminium and hence the process will be uneconomical.

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