answer:It says something different for boiled just because of rounding, and math errors. The way they calculate how many kCal and how much fat (or salt, sugar, etc) is in something isn’t perfect. Often the total number of kCal in a portion won’t add up to the breakdown below. The difference isn’t all that great, so don’t stress about it. The water probably contains some of the calories and some of the fat, but not very much at all. Mostly carbs, probably… Unfortunately it’ll be impossible to figure out exactly how much, but probably little enough that it doesn’t really matter. Also, just for curiosity’s sake… why on earth would you cook a bunch of barley and then toss it and drink the water it was boiled in?? That makes no sense at all to me!