In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these

In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure
(B) Partial pressure
(C) Chemical potential
(D) None of these
by

1 Answer

Answer :

(B) Partial pressure
by

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Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature __________ as its mole fraction increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Description : Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and ... increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Last Answer : (C) Increases

Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of a component is equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

Description : Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of ... equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

Last Answer : (D) The fugacity co-efficient is zero for an ideal gas

Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

Description : Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

Last Answer : (A) Chemical potential

In an ideal solution, the activity of a component equals its (A) Mole fraction (B) Fugacity at the same temperature and pressure (C) Partial pressure (D) None of these

Description : In an ideal solution, the activity of a component equals its (A) Mole fraction (B) Fugacity at the same temperature and pressure (C) Partial pressure (D) None of these

Last Answer : (A) Mole fraction

Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is important in problems involving gas absorption without chemical reaction (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion (D) Total reflux in case of distillation operation requires infinite number of plates for a binary system separation

Description : Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is ... reflux in case of distillation operation requires infinite number of plates for a binary system separation

Last Answer : (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion

At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) (A) μ° + RT ln f (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f

Description : At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm. ... (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f

Last Answer : (A) μ° + RT ln f

“The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these

Description : “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these

Last Answer : (B) Called Lewis-Randall rule

Fugacity and pressure are numerically equal, when the gas is (A) In standard state (B) At high pressure (C) At low temperature (D) In ideal state

Description : Fugacity and pressure are numerically equal, when the gas is (A) In standard state (B) At high pressure (C) At low temperature (D) In ideal state

Last Answer : (D) In ideal state

At a fixed pressure, the humidity depends upon the partial pressure of vapor in the mixture. Humidity of a vapour free gas is __________ percent. (A) 100 (B) 0 (C) 50 (D) Between 0 and 100

Description : At a fixed pressure, the humidity depends upon the partial pressure of vapor in the mixture. Humidity of a vapour free gas is __________ percent. (A) 100 (B) 0 (C) 50 (D) Between 0 and 100

Last Answer : (B) 0

According to Avogadro’s law  A. the product of the gas constant and the molecular mass of an ideal gas is constant  B. the sum of partial pressure of the mixture of two gases is sum of the two  C. equal volumes of all gases, at the same temperature and pressure, contain equal number of molecules  D. all of the above

Description : According to Avogadro's law  A. the product of the gas constant and the molecular mass of an ideal gas is constant  B. the sum of partial pressure of the mixture of two gases is sum of the ... all gases, at the same temperature and pressure, contain equal number of molecules  D. all of the above

Last Answer : Answer: C

Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Description : Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Last Answer : (A) Escaping tendencies of the same substance in different phases of a system

Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state

Description : Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state

Last Answer : (C) Both (A) and (B)

A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)

Description : For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) and (B)

The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Last Answer : (B) T and P

Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Last Answer : (D) All (A), (B), and (C)

A 0.064 kg of octane vapor (MW = 114) is mixed with0.91 kg of air (MW = 29.0) in the manifold of an Engine. The total pressure in the manifold is 86.1 kPa, and a temperature is 290 K. assume octane behaves ideally. What is the partial pressure of the air in the mixture in KPa?  a. 46.8  b. 48.6  c. 84.6  d. 64.8

Description : A 0.064 kg of octane vapor (MW = 114) is mixed with0.91 kg of air (MW = 29.0) in the manifold of an Engine. The total pressure in the manifold is 86.1 kPa, and a temperature is 290 K. assume octane behaves ideally. What is ... of the air in the mixture in KPa?  a. 46.8  b. 48.6  c. 84.6  d. 64.8

Last Answer : 84.6

According to Avogadro’s Hypothesis  (a) the molecular weights of all the perfect gases occupy the same volume under same conditions of pressure and temperature  (b) the sum of partial pressure of mixture of two gases is sum of the two  (c) product of the gas constant and the molecular weight of an ideal gas is constant  (d) gases have two values of specific heat  (e) all systems can be regarded as closed systems.

Description : According to Avogadro's Hypothesis  (a) the molecular weights of all the perfect gases occupy the same volume under same conditions of pressure and temperature  (b) the sum of partial pressure of ... gases have two values of specific heat  (e) all systems can be regarded as closed systems.

Last Answer : Answer : a

Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when (A) Only vapor phase follows Raoult's law (B) Only liquid phase obeys Dalton's law (C) Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Description : Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of ... law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Last Answer : (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these

Description : Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance ... temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these

Last Answer : (B) 1

Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Description : Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial ... at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

Last Answer : (C) Azeotropes obey Raoult's law at all temperature

The partial pressure of each constituent present in an alloy is __________ the total vapor pressure exerted by the alloy. (A) Less than (B) Equal to (C) More than (D) Either (B) or (C); depends on the type of alloy

Description : The partial pressure of each constituent present in an alloy is __________ the total vapor pressure exerted by the alloy. (A) Less than (B) Equal to (C) More than (D) Either (B) or (C); depends on the type of alloy

Last Answer : (A) Less than

gas which is collected over water becomes moistened due to water vapor, exerts its own partial pressure at the gas temperature, which is termed as its (A) Aqueous tension (B) Saturated humidity (C) Vapor pressure

Description : gas which is collected over water becomes moistened due to water vapor, exerts its own partial pressure at the gas temperature, which is termed as its (A) Aqueous tension (B) Saturated humidity (C) Vapor pressure

Last Answer : Option A

For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant(A) Is independent of pressure(B) Increases with pressure(C) Decreases with pressure(D) Increases /decreases with pressure depending on the stoichiometric co￾efficients of the reaction

Description : For an ideal gas mixture undergoing a reversible gaseous phase chemical reaction, the equilibrium constant (A) Is independent of pressure (B) Increases with pressure (C) Decreases with pressure (D) Increases /decreases with pressure depending on the stoichiometric co￾efficients of the reaction

Last Answer : (B) Increases with pressure

In case of an unsaturated mixture of gas and vapor, the percentage saturation is __________ its relative saturation. (A) Lower than (B) Higher than (C) Equal to (D) Either (A) or (B), depends on the mixture composition

Description : In case of an unsaturated mixture of gas and vapor, the percentage saturation is __________ its relative saturation. (A) Lower than (B) Higher than (C) Equal to (D) Either (A) or (B), depends on the mixture composition

Last Answer : (A) Lower than

The chemical potential for a pure substance is __________ its partial molal free energy. (A) More than (B) Less than (C) Equal to (D) Not related to

Description : The chemical potential for a pure substance is __________ its partial molal free energy. (A) More than (B) Less than (C) Equal to (D) Not related to

Last Answer : (C) Equal to

For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

Description : For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

Last Answer : (C) Activity co-efficient

Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium solubility curve in case of a single component stripper (C) The operating pressure in solvent extraction system should be below vapor pressures of all components (D) The solubility of a particular gas in ideal solution in any solvent is always the same

Description : Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium ... (D) The solubility of a particular gas in ideal solution in any solvent is always the same

Last Answer : (C) The operating pressure in solvent extraction system should be below vapor pressures of all components

__________ is the temperature at which a gas-vapor mixture becomes saturated, when cooled at constant total pressure out of contact with a liquid. (A) Dew point (B) Bubble point (C) Dry bulb temperature (D) Wet bulb temperature

Description : __________ is the temperature at which a gas-vapor mixture becomes saturated, when cooled at constant total pressure out of contact with a liquid. (A) Dew point (B) Bubble point (C) Dry bulb temperature (D) Wet bulb temperature

Last Answer : (A) Dew point

The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture. (A) Composition (B) Temperature (C) Total pressure (D) All (A), (B) and (C)

Description : The dew point of an unsaturated gas-vapor mixture does not depend upon the __________ of the mixture. (A) Composition (B) Temperature (C) Total pressure (D) All (A), (B) and (C)

Last Answer : (B) Temperature

During dehumidification of unsaturated air wet bulb temperature & partial pressure of vapor are not constant. However, during evaporative cooling process with recirculated water supply, the __________ remains constant. (A) Wet bulb temperature (B) Partial pressure of water vapor (C) Relative humidity (D) None of these

Description : During dehumidification of unsaturated air wet bulb temperature & partial pressure of vapor are not constant. However, during evaporative cooling process with recirculated water supply, the __________ remains ... pressure of water vapor (C) Relative humidity (D) None of these

Last Answer : (A) Wet bulb temperature

If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature increases (B) Solubility increases as temperature decreases (C) Solubility is independent of temperature (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution

Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution

Last Answer : (B) Solubility increases as temperature decreases

The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) & (B)

The partial pressure distribution of an ideal gas diffusing through another stagnant ideal gas at steady state follows a/an __________ law. (A) Exponential (B) Parabolic (C) Linear (D) Cubic

Description : The partial pressure distribution of an ideal gas diffusing through another stagnant ideal gas at steady state follows a/an __________ law. (A) Exponential (B) Parabolic (C) Linear (D) Cubic

Last Answer : (A) Exponential

Condensation of a vapour-gas mixture just begins, when (where, p = partial pressure of the vapour P = vapour pressure of the liquid). (A) p = P (B) p >>P (C) p < P (D) p << P

Description : Condensation of a vapour-gas mixture just begins, when (where, p = partial pressure of the vapour P = vapour pressure of the liquid). (A) p = P (B) p >>P (C) p < P (D) p

Last Answer : (A) p = P

Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

Description : Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

Last Answer : (B) Increases

With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly

Description : With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly

Last Answer : (A) Increases

Vapour lock is a. complete or partial stoppage of fuel supply due to vaporization of the fuel b. locking of carburetor due to high vapor pressure c. excess fuel supply to the engine d. supply of liquid fuel to the engine

Description : Vapour lock is a. complete or partial stoppage of fuel supply due to vaporization of the fuel b. locking of carburetor due to high vapor pressure c. excess fuel supply to the engine d. supply of liquid fuel to the engine

Last Answer : ANSWER a. complete or partial stoppage of fuel supply due to vaporization of the fuel

On a day when the partial pressure of water vapor remains constant, what happens as the temperature rises?  a. the relative humidity increases  b. the relative humidity decreases  c. the relative humidity remains constant  d. the air would eventually become saturated

Description : On a day when the partial pressure of water vapor remains constant, what happens as the temperature rises?  a. the relative humidity increases  b. the relative humidity decreases  c. the relative humidity remains constant  d. the air would eventually become saturated

Last Answer : the relative humidity decreases

_________is the partial pressure of water vapor at the existing temperature divided by the equilibrium vapor pressure of water at the existing temperature.  a. vacuum pressure  b. relative humidity  c. absolute pressure  d. vapor pressure

Description : _________is the partial pressure of water vapor at the existing temperature divided by the equilibrium vapor pressure of water at the existing temperature.  a. vacuum pressure  b. relative humidity  c. absolute pressure  d. vapor pressure

Last Answer : relative humidity

According to Dalton’s law, the total pres sure of the mixture of gases is equal to  (a) greater of the partial pressures of all  (b) average of the partial pressures of all  (c) sum of the partial pressures of all  (d) sum of the partial pressures of all divided by average molecular weight  (e) atmospheric pressure.

Description : According to Dalton's law, the total pres sure of the mixture of gases is equal to  (a) greater of the partial pressures of all  (b) average of the partial pressures of all  (c) sum ... all  (d) sum of the partial pressures of all divided by average molecular weight  (e) atmospheric pressure.

Last Answer : Answer : c

Mercury is an ideal barometric fluid mainly due to its(A) High density (B) Low compressibility (C) Low capillary action (D) Very low vapor pressure

Description : Mercury is an ideal barometric fluid mainly due to its (A) High density (B) Low compressibility (C) Low capillary action (D) Very low vapor pressure

Last Answer : (D) Very low vapor pressure

What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation

Description : What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation

Last Answer : ANSWER: X -- IDEAL GAS EQUATION

If a mixture of two gases has a total pressure of 5.7 ATM. If one gas has a partial pressure of 4.1 ATM what is the partial pressure of the other gas?

Description : If a mixture of two gases has a total pressure of 5.7 ATM. If one gas has a partial pressure of 4.1 ATM what is the partial pressure of the other gas?

Last Answer : 1.6 ATM

In case of an ideal solution, the total vapor pressure varies __________ with the composition expressed as mole fraction, (A) Inversely (B) Linearly (C) Exponentially (D) None of these

Description : In case of an ideal solution, the total vapor pressure varies __________ with the composition expressed as mole fraction, (A) Inversely (B) Linearly (C) Exponentially (D) None of these

Last Answer : (B) Linearly

Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor? (A) d ln p/dt = Hvap/RT2 (B) d ln p/dt = RT2/Hvap (C) dp/dt = RT2/Hvap (D) dp/dt = Hvap/RT2

Description : Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor? (A) d ln p/dt = Hvap/RT2 (B) d ln p/dt = RT2/Hvap (C) dp/dt = RT2/Hvap (D) dp/dt = Hvap/RT2

Last Answer : (A) d ln p/dt = Hvap/RT2

The chemical potential of any constituent of an ideal solution depends on the __________ of the solution. (A) Temperature (B) Pressure (C) Composition (D) All (A), (B) and (C)

Description : The chemical potential of any constituent of an ideal solution depends on the __________ of the solution. (A) Temperature (B) Pressure (C) Composition (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

For an ideal gas, the chemical potential is given by (A) RT d ln P (B) R d ln P (C) R d ln f (D) None of these

Description : For an ideal gas, the chemical potential is given by (A) RT d ln P (B) R d ln P (C) R d ln f (D) None of these

Last Answer : (A) RT d ln P

With increase in absolute humidity, the dew point of an unsaturated mixture of air and water vapor (at constant pressure and temperature). (A) Increases (B) Remains unchanged (C) Decreases (D) Decreases linearly

Description : With increase in absolute humidity, the dew point of an unsaturated mixture of air and water vapor (at constant pressure and temperature). (A) Increases (B) Remains unchanged (C) Decreases (D) Decreases linearly

Last Answer : (A) Increases

Dew point of an air-water vapor mixture (A) Decreases with decrease in pressure (B) At constant humidity & total pressure is fixed (C) Corresponding to any point on the humidity chart is obtained by projecting a line through this point parallel to the temperature axis and to the saturation curve (D) All 'a', 'b' & 'c'

Description : Dew point of an air-water vapor mixture (A) Decreases with decrease in pressure (B) At constant humidity & total pressure is fixed (C) Corresponding to any point on the humidity chart is obtained by projecting a ... to the temperature axis and to the saturation curve (D) All 'a', 'b' & 'c'

Last Answer : (D) All 'a', 'b' & 'c'