In an ideal solution, the activity of a component equals its (A) Mole fraction (B) Fugacity at the same temperature and pressure (C) Partial pressure (D) None of these

In an ideal solution, the activity of a component equals its (A) Mole fraction
(B) Fugacity at the same temperature and pressure
(C) Partial pressure
(D) None of these
by

1 Answer

Answer :

(A) Mole fraction
by

Related questions

Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature __________ as its mole fraction increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Description : Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and ... increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant

Last Answer : (C) Increases

Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of a component is equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

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Last Answer : (D) The fugacity co-efficient is zero for an ideal gas

For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases. (A) Decreases (B) Increases (C) Remain same (D) Decreases linearly

Description : For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases. (A) Decreases (B) Increases (C) Remain same (D) Decreases linearly

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Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

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Henry's law states that the (A) Partial pressure of a component over a solution is proportional to its mole fraction in the liquid (B) Partial pressure of a component over a solution is proportional to the mole fraction in the vapour (C) Vapour pressure is equal to the product of the mole fraction and total pressure (D) Partial pressure is equal to the product of the mole fraction and total pressure

Description : Henry's law states that the (A) Partial pressure of a component over a solution is proportional to its mole fraction in the liquid (B) Partial pressure of a component over a solution ... pressure (D) Partial pressure is equal to the product of the mole fraction and total pressure

Last Answer : (A) Partial pressure of a component over a solution is proportional to its mole fraction in the liquid

Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient

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For a solution of volatile liquids, the partial vapour pressure of each component in solution is directly proportional to its (a) Molarity (b) Mole fraction (c) Molality (d) Normality

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Last Answer : Ans:(b)

Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)

Last Answer : (D) All (A), (B), and (C)

In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these

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Last Answer : (B) Partial pressure

“The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these

Description : “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these

Last Answer : (B) Called Lewis-Randall rule

For a single component absorber, the operating line is straight only when plotted in term of __________ units. (A) Partial pressure (B) Mole ratio (C) Mole fraction (D) None of these

Description : For a single component absorber, the operating line is straight only when plotted in term of __________ units. (A) Partial pressure (B) Mole ratio (C) Mole fraction (D) None of these

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A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co-efficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of (A) Temperature only (B) Temperature and pressure only (C) Temperature, pressure and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi

Last Answer : (C) Temperature, pressure and liquid composition xi only

For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

Description : For an ideal liquid solution, which of the following is unity? (A) Activity (B) Fugacity (C) Activity co-efficient (D) Fugacity co-efficient

Last Answer : (C) Activity co-efficient

In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)

Description : For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) and (B)

In case of an ideal solution, the total vapor pressure varies __________ with the composition expressed as mole fraction, (A) Inversely (B) Linearly (C) Exponentially (D) None of these

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Last Answer : (B) Linearly

The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

Last Answer : (B) T and P

Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state

Description : Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state

Last Answer : (C) Both (A) and (B)

Fugacity and pressure are numerically equal, when the gas is (A) In standard state (B) At high pressure (C) At low temperature (D) In ideal state

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For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be (A) 6738.9 (B) 6753.5 (C) 7058.3 (D) 9000

Description : For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be (A) 6738.9 (B) 6753.5 (C) 7058.3 (D) 9000

Last Answer : (B) 6753.5

Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature. (A) Decreases (B) Increases (C) Remains constant

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Last Answer : (B) Increases

If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature increases (B) Solubility increases as temperature decreases (C) Solubility is independent of temperature (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution

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Last Answer : (B) Solubility increases as temperature decreases

The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving force. and, Kp= M.T.C. for diffusion of a gas through a stagnant inert gas with pressure as driving force.) (A) Kc = Kp = Km (B) Kc = Kp /RT = Km . RT/P (C) Kc = Kp . RT = Km . RT/p (D) None of these

Description : The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving ... (C) Kc = Kp . RT = Km . RT/p (D) None of these

Last Answer : (C) Kc = Kp . RT = Km . RT/p

Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Description : Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these

Last Answer : (A) Escaping tendencies of the same substance in different phases of a system

The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)

Description : The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)

Last Answer : (C) Both (A) & (B)

Which of the following is not affected by temperature changes? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) None of these

Description : Which of the following is not affected by temperature changes? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) None of these

Last Answer : (D) None of these

For a given substance at a specified temperature, activity is __________ to fugacity. (A) Directly proportional (B) Inversely proportional (C) Equal (D) None of these

Description : For a given substance at a specified temperature, activity is __________ to fugacity. (A) Directly proportional (B) Inversely proportional (C) Equal (D) None of these

Last Answer : (A) Directly proportional

Which of the following is affected by the temperature? (A) Fugacity (B) Activity co-efficient (C) Free energy (D) All (A), (B) & (C)

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Last Answer : (D) All (A), (B) & (C)

Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium solubility curve in case of a single component stripper (C) The operating pressure in solvent extraction system should be below vapor pressures of all components (D) The solubility of a particular gas in ideal solution in any solvent is always the same

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Last Answer : (C) The operating pressure in solvent extraction system should be below vapor pressures of all components

The unit of fugacity is the same as that of the (A) Pressure (B) Temperature (C) Volume (D) Molar concentration

Description : The unit of fugacity is the same as that of the (A) Pressure (B) Temperature (C) Volume (D) Molar concentration

Last Answer : (A) Pressure

With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly

Description : With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly

Last Answer : (A) Increases

At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Description : At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole ... respectively. Activity co-efficient of methanol is (A) 1.572 (B) 1.9398 (C) 3.389

Last Answer : (A) 1.572

In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Description : In a homogeneous solution, the activity co-efficient of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)

Last Answer : (D) All (A), (B) and (C)

In saturated gas, the (A) Vapour is in equilibrium with the liquid at the gas temperature (B) Vapour is in equilibrium with the liquid at the room temperature (C) Partial pressure of vapour equals the vapour pressure of the liquid at room temperature (D) None of these

Description : In saturated gas, the (A) Vapour is in equilibrium with the liquid at the gas temperature (B) Vapour is in equilibrium with the liquid at the room temperature (C) Partial pressure of vapour equals the vapour pressure of the liquid at room temperature (D) None of these

Last Answer : (A) Vapour is in equilibrium with the liquid at the gas temperature

1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be (A) 35 K (B) 174 K (C) 274 K (D) 154 K

Description : 1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be (A) 35 K (B) 174 K (C) 274 K (D) 154 K

Last Answer : (C) 274 K

According to Avogadro’s law  A. the product of the gas constant and the molecular mass of an ideal gas is constant  B. the sum of partial pressure of the mixture of two gases is sum of the two  C. equal volumes of all gases, at the same temperature and pressure, contain equal number of molecules  D. all of the above

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Last Answer : Answer: C

According to Avogadro’s Hypothesis  (a) the molecular weights of all the perfect gases occupy the same volume under same conditions of pressure and temperature  (b) the sum of partial pressure of mixture of two gases is sum of the two  (c) product of the gas constant and the molecular weight of an ideal gas is constant  (d) gases have two values of specific heat  (e) all systems can be regarded as closed systems.

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Last Answer : Answer : a

The operating line for an absorber is curved, when plotted in terms of (A) Mole fractions (B) Mole ratios (C) Partial pressure (D) Mass fractions

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Last Answer : (C) Partial pressure

Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of component 'B', when (A) Only vapor phase follows Raoult's law (B) Only liquid phase obeys Dalton's law (C) Liquid phase obeys Dalton's law and vapor phase obeys Raoult's law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Description : Relative volatility varies with the concentration of component for an ideal solution. The relative volatility of a binary mixture may be defined as the ratio of vapor pressure of component 'A' to that of ... law (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Last Answer : (D) Vapor phase obeys Dalton's law and liquid phase obeys Raoult's law

Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

Description : Activity co-efficient is a measure of the (A) Departure from ideal solution behaviour (B) Departure of gas phase from ideal gas law (C) Vapour pressure of liquid (D) None of these

Last Answer : (A) Departure from ideal solution behaviour

Consider an ideal solution of components A and B. The entropy of mixing per mole of an alloy containing 50% B is (A) R ln 2 (B) -R ln 2 (C) 3 R ln 2 (D) -3R ln 2

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Last Answer : (A) R ln 2

The partial pressure distribution of an ideal gas diffusing through another stagnant ideal gas at steady state follows a/an __________ law. (A) Exponential (B) Parabolic (C) Linear (D) Cubic

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Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is important in problems involving gas absorption without chemical reaction (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion (D) Total reflux in case of distillation operation requires infinite number of plates for a binary system separation

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When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of component B (B) Vapour pressure of component A to the total pressure (C) Vapour pressure of component A to the partial pressure of A (D) Partial pressure of component A to the total pressure

Description : When the liquid phase and vapour phase of a binary system obeys Raoult's and Dalton's law respectively, the relative volatility is the ratio of (A) Vapour pressure of component A to that of ... to the partial pressure of A (D) Partial pressure of component A to the total pressure

Last Answer : (A) Vapour pressure of component A to that of component B

Pick out the wrong statement. (A) An ideal liquid or solid solution is defined as one in which each component obeys Raoult's law (B) If Raoult's law is applied to one component of a binary mixture; Henry's law or Raoult's law is applied to the other component also (C) Henry's law is rigorously correct in the limit of infinite dilution (D) None of these

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Which of the following is not a unit of mass transfer co-efficient? (A) Moles transferred/ [(time) (area) (mole fraction)] (B) Moles transferred/ [(time) (area) (mass A/mass B)] (C) Moles transferred/ [(time) (area) (pressure)] (D) None of these

Description : Which of the following is not a unit of mass transfer co-efficient? (A) Moles transferred/ [(time) (area) (mole fraction)] (B) Moles transferred/ [(time) (area) (mass A/mass B)] (C) Moles transferred/ [(time) (area) (pressure)] (D) None of these

Last Answer : (D) None of these

A piston filled with `0.04` mole of an ideal gas expands reversible from `50.0mL` at a constant temperature of `37.0^(@)C` . As it does so, it absorbs

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Last Answer : A piston filled with `0.04` mole of an ideal gas expands reversible from `50.0mL` at a constant temperature of `37. ... J` D. `q= +208 J, w=+208 J`

For an ideal solution, the value of activity co-efficient is (A) 0 (B) 1 (C) < 1 (D) > 1

Description : For an ideal solution, the value of activity co-efficient is (A) 0 (B) 1 (C) < 1 (D) > 1

Last Answer : (B) 1

What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation

Description : What is the name given to the equation PV=nRT? w) law of partial pressure x) ideal gas equation y) quadratic equation z) Raoult's equation

Last Answer : ANSWER: X -- IDEAL GAS EQUATION

Boiling point elevation of an ideal solution (A) Increases rapidly with temperature rise (B) Decreases rapidly with temperature rise (C) In independent of pressure (D) Both (B) and (C)

Description : Boiling point elevation of an ideal solution (A) Increases rapidly with temperature rise (B) Decreases rapidly with temperature rise (C) In independent of pressure (D) Both (B) and (C)

Last Answer : (A) Increases rapidly with temperature rise