Description : If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem
Last Answer : B) Clausius-Clapeyron Equation
Description : Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor? (A) d ln p/dt = Hvap/RT2 (B) d ln p/dt = RT2/Hvap (C) dp/dt = RT2/Hvap (D) dp/dt = Hvap/RT2
Last Answer : (A) d ln p/dt = Hvap/RT2
Description : Pick out the wrong statement. (A) Enthalpies of all elements in their standard states are assumed to be zero (B) Combustion reactions are never endothermic in nature (C) Heat of reaction ... to the change in internal energy (D) Clausius-Clapeyron equation is not applicable to melting process
Last Answer : (D) Clausius-Clapeyron equation is not applicable to melting process
Description : Clausius-Clapeyron Equation gives accurate result, when the (A) Vapour pressure is relatively low and the temperature does not vary over wide limits (B) Vapour obeys the ideal gas law and the latent heat of ... is negligible compared with that in the vapour state (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (∆HV/R) (1/T1- 1/T2) from the exact Clapeyron equation, it is assumed that the (A) Volume of the liquid phase is negligible compared to ... gas (C) Heat of vaporisation is independent of temperature (D) All (A), (B) & (C)
Last Answer : (D) All (A), (B) & (C)
Description : Which of the following is not an equation of state? (A) Bertholet equation (B) Clausius-Clapeyron equation (C) Beattie-Bridgeman equation (D) None of these
Last Answer : (B) Clausius-Clapeyron equation
Description : Pick out the Clausius-Clapeyron equation from the following: (A) dP/dT = ∆H/T∆V (B) ln P = - (∆H/RT) + constant (C) ∆F = ∆H + T [∂(∆F)/∂T]P (D) None of these
Last Answer : B) ln P = - (∆H/RT) + constant
Description : Clapeyron equation is applicable for registration at (a) saturation point of vapour (b) saturation point of liquid (c) sublimation temperature (d) triple point.
Last Answer : Ans: a
Description : Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation. (A) Gibbs-Duhem (B) Maxwell's (C) Clapeyron (D) None of these
Last Answer : (C) Clapeyron
Description : Bound moisture is that liquid which exerts an equilibrium vapor pressure __________ that of the pure liquid at the given temperature. (A) Less than (B) More than (C) Equal to (D) Either (A) or (B); depends on the solid
Last Answer : (A) Less than
Description : The pressure of the vapor phase of a substance that is in equilibrium with the liquid or solid phase. a. Phase Pressure b. Equilibrium Vapor Pressure c. Specific Pressure d. Equilibrium Phase Pressure
Last Answer : Equilibrium Vapor Pressure
Description : The critical temperature is the temperature: w) above which a substance cannot be vaporized x) at which the density is a minimum y) at which solid, liquid, and vapor are in equilibrium z) above which the substance cannot be liquified.
Last Answer : ANSWER: Z -- ABOVE WHICH THE SUBSTANCE CANNOT BE LIQUIFIED.
Description : Clapeyron Equation deals with the (A) Rate of change of vapour pressure with temperature (B) Effect of an inert gas on vapour pressure (C) Calculation of ΔF for spontaneous phase change (D) Temperature dependence of heat of phase transition
Last Answer : (A) Rate of change of vapour pressure with temperature
Description : If a two phase system is in physical equilibrium; then it means that, the (A) Escaping tendency of each component from the liquid phase to the vapor phase is exactly equal to that from vapor phase to liquid phase ... liquid phase is equal to that throughout the vapor phase (D) All (A), (B) and (C)
Description : The equilibrium liquid composition compared to the vapor composition in case of Azeotropic mixture is (A) More (B) Less (C) Same (D) Either more or less; depends on the system
Last Answer : (C) Same
Description : What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor? (A) 2 (B) 0 (C) 3 (D) 1
Last Answer : (A) 2
Description : What is the number of degree of freedom for a system of two miscible non-reacting species in vapor-liquid equilibrium forming an azeotrope? (A) 0 (B) 2 (C) 1 (D) 3
Last Answer : (C) 1
Description : What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope? (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (C) 2
Description : The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are: (A) 1 (B) 2 (C) 3 (D) 0
Last Answer : (B) 2
Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi
Last Answer : (C) Temperature, pressure and liquid composition xi only
Description : Moisture in a solid exerting an equilibrium vapour pressure equal to that of the pure liquid at the same temperature is called the __________ moisture. (A) Unbound (B) Critical (C) Free (D) Bound
Last Answer : (A) Unbound
Description : Clapeyron equation is a relation between (a) temperature, pressure and enthalpy (b) specific volume and enthalpy (c) temperature and enthalpy (d) temperature, pressure, specific vapour and enthalpy.
Last Answer : Ans: D
Description : __________________ represents the highest pressure and highest temperature at which liquid and vapor can coexist in equilibrium. a) Critical Point b) Boiling Point c) Quality Point d) None of the above
Last Answer : Critical Point
Description : A vessel with a volume of cubic meter contains liquid water and water vapor ion equilibrium at 600 kPa. The liquid water has mass of1kg. Using the steam table, calculate the mass of the water vapor. A. 0.99kg B. 1.57 kg C ... / kg vg = 0.3157 m^3 / kg Vtot = mƒ vƒ + mg vg mg = (tot-mƒ vƒ) / vg
Last Answer : 3.16 kg
Description : Liquid "X" is at equilibrium with its vapor in a cylinder and piston apparatus. When the volume of the space above the liquid is 50 ml and the temperature 25!, the vapor pressure of "X" is 120 torr. What will the ... 25!C? Some liquid is always present. w) 30 torr x) 60 torr y) 120 torr z) 240 torr
Last Answer : ANSWER: Y -- 120 TORR
Description : If the solubilities of different components (in a liquid-liquid extraction system) increase with rise in temperature, then the temperature above which they dissolve completely is known as the critical solution ... On heating, a vapor phase will appear; while on cooling, a solid phase will appear
Last Answer : (D) On heating, a vapor phase will appear; while on cooling, a solid phase will appear
Description : Smog is (A) Nothing but black smoke (B) A combination of smoke and fog (C) A liquid particle resulting from vapor condensation (D) A solid particle e.g. fly-ash
Last Answer : (B) A combination of smoke and fog
Description : What is a physical process by which vapor becomes liquid or solid the opposite of evaporation?
Last Answer : condensation
Description : Condensate is the liquid formed when steam passes from the ________ to the ______ state. a. Vapor, solid b. Solid, liquid c. Vapor, liquid d. None
Last Answer : c. Vapor, liquid
Description : The changing of solid directly to vapor without passing through liquid state is called a. Evaporation b. Vaporization c. Sublimation d. Condensation
Last Answer : Sublimation
Description : What is defined as the direct conversion of a substance from the solid to the vapor state or vice versa without passing the liquid state? A. Condensation B. Vaporization C. Sublimation D. Cryogenation
Description : Fanning equation is given by (∆P/ρ) = 4f (L/D) (v 2 /2gc ). It is applicable to __________ region flow. (A) Transition (B) Laminar (C) Turbulent (D) Both (B) and (C)
Last Answer : (D) Both (B) and (C)
Description : Which of the following psychrometric processes is followed by water vapour laden unsaturated air, when it is passed through solid or liquid adsorbent? (A) Cooling and dehumidification ... (C) Dehumidification with dry bulb temperature remaining constant (D) None of these
Last Answer : (B) Heating and dehumidification at almost constant wet bulb temperature
Description : A trickle bed reactor is the one, which (A) Has altogether three streams either entering or leaving (B) Processes three reactants at different flow rates (C) Processes three reactants with same flow rate (D) Employs all the three phases (i.e. solid, liquid and gas)
Last Answer : (D) Employs all the three phases (i.e. solid, liquid and gas)
Description : Solid and liquid phases of a substance are in equilibrium at the (A) Critical temperature (B) Melting point (C) Freezing point (D) Both (B) and (C)
Last Answer : D) Both (B) and (C)
Description : __________ is the temperature at which a gas-vapor mixture becomes saturated, when cooled at constant total pressure out of contact with a liquid. (A) Dew point (B) Bubble point (C) Dry bulb temperature (D) Wet bulb temperature
Last Answer : (A) Dew point
Description : Flooding in a vapor-liquid contacting equipment occurs in a tray, when the pressure drop through a tray is __________ the liquid head available in the downcomer. (A) Less than (B) More than (C) Same as (D) Very much less
Last Answer : (B) More than
Description : The separation of liquid droplets from the vapor is done by a/an __________, in the evaporators. (A) Steam ejector (B) Entrainment separator (C) Compressor (D) Vacuum pump
Last Answer : (B) Entrainment separator
Description : A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor. (A) Isolated (B) Closed (C) Open (D) None of these
Last Answer : (C) Open
Description : Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium ... (D) The solubility of a particular gas in ideal solution in any solvent is always the same
Last Answer : (C) The operating pressure in solvent extraction system should be below vapor pressures of all components
Description : A stable interface between solid _________ liquid ____________ and gaseous ___________ promotes high rate of electrode processes. a) Fuel, electrolyte, electrode b) Electrode, fuel, electrolyte c) Electrode, electrolyte, fuel d) Fuel, electrode, electrolyte
Last Answer : c) Electrode, electrolyte, fuel
Description : What is the unique state at which solid, liquid and gaseous phase can go co-exist in equilibrium? a. Triple point b. Critical point c. Boiling point d. Pour point
Last Answer : Triple point
Description : In centrifugal pump operation, the cavitation can be eliminated by maintaining suction pressure __________ the vapor pressure of the liquid at the suction temperature. (A) Lower than (B) Higher than (C) Equal to (D) None of these
Last Answer : (B) Higher than
Description : Rayleigh equation applies to __________ distillation. (A) Differential (B) Flash (C) Equilibrium (D) Molecular
Last Answer : (A) Differential
Description : Which of the following unit operations makes use of Thiele-Geddes equation? (A) Liquid-liquid extraction (B) Solid-liquid extraction (C) Multi-component absorption with chemical reaction (D) Multi-component distillation
Last Answer : (D) Multi-component distillation
Description : Which of the following expression is not applicable on the hydrolysis equilibrium : `CN^(-)H_(2)OrArrHCN+OH^(-)`
Last Answer : Which of the following expression is not applicable on the hydrolysis equilibrium : `CN^(-)H_(2)OrArrHCN+OH^(-)` A. ... H+] =sqrt((K_(w).K_(a))/(C))`
Description : What is the temperature when water and vapor are in equilibrium with the atmospheric pressure? a. Ice point b. Steam point c. Critical point d. Freezing point
Last Answer : Steam point
Description : At steam point, the temperature of water and its vapor at standard pressure are: a. Extremes or maximum b. unity c. in equilibrium d. undefined
Last Answer : in equilibrium
Description : What is the temperature when water and vapor are in the equilibrium with the atmospheric pressure? a. Ice point b. Steam point c. Critical point d. Freezing point
Description : _________is the partial pressure of water vapor at the existing temperature divided by the equilibrium vapor pressure of water at the existing temperature. a. vacuum pressure b. relative humidity c. absolute pressure d. vapor pressure
Last Answer : relative humidity