Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is important in problems involving gas absorption without chemical reaction (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion (D) Total reflux in case of distillation operation requires infinite number of plates for a binary system separation

Pick out the correct statement.

(A) Higher hold up of the solid in the rotary dryer results in better exposure

of the solids to the gas

(B) The 'Hatta number' is important in problems involving gas absorption

without chemical reaction

(C) For a non-reacting binary mixture of ideal gases, the partial pressure

distribution of both components is linear in the case of steady state equimolal

counter-diffusion

(D) Total reflux in case of distillation operation requires infinite number of

plates for a binary system separation


by

1 Answer

Answer :

(C) For a non-reacting binary mixture of ideal gases, the partial pressure

distribution of both components is linear in the case of steady state equimolal

counter-diffusion

by

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Pick out the wrong statement. (A) The mole fraction of solute is directly proportional to the molality of a 'dilute' solution (B) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is nonlinear in the case of steady state unimolal unidirectional diffusion (C) Azeotropes obey Raoult's law at all temperature (D) The relative volatility of a binary mixture at the Azeotropic composition is 1

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Steady state equimolal counter diffusion is encountered in (A) Separation of a binary mixture by distillation (B) Absorption of NH3 from air by water (C) All liquid-liquid diffusion systems (D) All liquid-solid diffusion systems

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Steady state equimolal counter diffusion occurs in case of (A) Leaching (B) Absorption (C) Binary phase distillation (D) Liquid-liquid extraction

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The Hatta number is important in (A) Multi-component distillation (B) Binary distillation (C) Gas absorption without chemical reaction (D) Gas absorption with chemical reaction

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Pick out the wrong statement (A) Co-current absorbers are usually used, when the gas to be dissolved in the liquid is a pure substance (B) In case of gas absorption, HETP is equal to HTU, when both the operating line & the equilibrium lines are parallel (C) Hatta number is important in case of gas absorption with chemical reaction (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process

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The value of NA/(NA + NB), for steady state equimolal counter diffusion of two gases 'A' and 'B' is (A) 1 (B) ∞ (C) 0.5

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A distillation column with N plates is being operated under normal conditions. At some point of time, the operation is shifted to total reflux condition (i.e., no product and residue are being withdrawn and feed to the column is stopped). At the new steady state, (A) Composition of vapors and that of liquid do not vary throughout the column (B) Reboiler load and condenser load are minimum (C) The top and bottom compositions are unchanged with and without total reflux (D) The top and bottom compositions correspond to the maximum enrichment available

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Pick out the correct statement. (A) The slope of the stripping line is always less than unity (B) For a given separation in a binary distillation column, with increase in reflux ratio (above the minimum reflux ratio), the fixed cost of the distillation column first increases and then decreases (C) In Ponchon-Savarit method of no. of theoretical plate determination, the stripping and rectifying operating lines are vertical at total reflux (D) Kremser-Brown-Souder's equation is used to calculate the efficiency of a plate tower

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Pick out the correct statement. (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of non￾ideal binary system by distillation (B) A sharp decrease in pressure drop is an indication of flooding in a distillation coloumn (C) Solvent used in extractive distillation should be of high volatility (D) Flash distillation is suitable for separating components which have very close boiling temperature

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Pick out the wrong statement. (A) In solvent extraction, the distribution co-efficient should be as large as possible for solvent economy (B) With increase in pressure, the solubility of gases in solvent increases at a fixed temperature (C) Decrease in Murphree plate efficiency is an indication of entrainment in distillation column (D) The capacity of a distillation column is maximum at total reflux

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Pick out the wrong statement. (A) An ideal liquid or solid solution is defined as one in which each component obeys Raoult's law (B) If Raoult's law is applied to one component of a binary mixture; Henry's law or Raoult's law is applied to the other component also (C) Henry's law is rigorously correct in the limit of infinite dilution (D) None of these

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Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of a component is equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas

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Total reflux in a distillation operation requires minimum (A) Reboiler load (B) Number of plates (C) Condenser load (D) All (A), (B) and (C)

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Pick out the wrong statement: (A) Reboiler is not used in open steam distillation (B) The separation of solutes of different molecular sizes in a liquid solution by use of a suitable membrane is called dialysis (C) Freeze drying is used for the drying of fish (D) Fenske-Underwood equation is used for calculating theoretical number of plates in a distillation column at normal operating reflux condition

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The partial pressure distribution of an ideal gas diffusing through another stagnant ideal gas at steady state follows a/an __________ law. (A) Exponential (B) Parabolic (C) Linear (D) Cubic

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Pick out the wrong statement. (A) The Reynolds analogy for mass transfer is given by Lewis relation and is applicable, when Schmidt number is one (B) Sherwood number for flow in pipes can be expressed as the ratio of the concentration gradient at wall to the overall concentration difference (C) According to film theory for equimolar counter diffusion, the mass transfer coefficient is given by DAB(B)P - 3, Q - 2 (D) The z-component of the total mass flux of a component A in binary mixture of A and B is given by - Dab'.dCA/dz

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“The total volume of a mixture of non-reacting gases is equal to the sum of the partial volumes.” This statement is known as ______.  A. Law of Dulong and Petit  B. Maxwell-Boltzmann law  C. Amagat’s law  D. Avogadro’s law

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The-relative volatility for separation of a non-ideal binary mixture by distillation should be (A) 0 (B) 1 (C) > 1 (D) < 1

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Pick out the wrong statement. (A) With decrease in feed temperature, the number of plates required for binary distillation decreases for a given ‘L/V’ ratio (B) The extraction per unit of total height for a short packed column is more effective than for a tall column, in case of liquid-liquid extraction(C) Natural draft cooling towers are made of ferroconcrete and its cross￾section is wider at the bottom(D) Vander wall adsorption is also called chemisorption

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The minimum number of theoretical plates is required for achieving a given separation in distillation column with (A) No reflux (B) Total reflux (C) Zero reflux ratio (D) Minimum reflux ratio

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. For the same feed, feed quality and separation (in a distillation column), with the increase of total pressure, the number of ideal plates will (A) Increase (B) Decrease (C) Remain same (D) Data insufficient, can't be predicted

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Pick out the wrong statement. (A) Different solids have different equilibrium moisture curves (B) Total condenser or reboiler is considered equivalent to one theoretical plate in McCabe-Thiele method of theoretical plate calculation for distillation column (C) Heat removal load on cooler remains constant, even with increase of the reflux ratio in a distillation column (D) Even a forced draft cooling tower cannot cool water below the wet bulb temperature

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According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a bottom fraction containing 98 mol% B ? Assume that relative volatility (αAB = 2) does not change appreciably in the column. (A) 5 (B) 9 (C) 12 (D) 28

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Can the efficiency of a plate in the distillation tower be greater than 100%? (A) Yes (B) Normally not; but is possible if infinite number of plates are put(C) Never(D) Yes; if the reflux ratio is maximum

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Flights in a rotary dryer are provided to (A) Lift and shower the solids thus exposing it thoroughly to the drying action of the gas (B) Reduce the residence time of solid (C) Increase the residence time of the solid (D) None of these

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Pick out the wrong statement. (A) The binary diffusivity in liquids is of the order of 10 -5 cm2 /sec (B) Molecular diffusion in solid is much faster than that in liquids (C) Particles movement from higher concentration to lower concentration takes place in diffusion process (D) According to Poiseuille's law, the permeability decreases with increase in temperature for flow of a gas through a given capillary

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Binary distillation involves the mass transfer by __________ at the gas￾liquid interface. (A) Unidirectional diffusion from liquid to gas phase (B) Unidirectional diffusion from gas to liquid phase (C) Either 'a' or 'b' (D) A counter diffusion at an almost equal molar rate

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Fenske equation determines the (A) Maximum number of ideal plates (B) Height of the distillation column (C) Minimum number of theoretical plates (D) Optimum reflux ratio

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The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving force. and, Kp= M.T.C. for diffusion of a gas through a stagnant inert gas with pressure as driving force.) (A) Kc = Kp = Km (B) Kc = Kp /RT = Km . RT/P (C) Kc = Kp . RT = Km . RT/p (D) None of these

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The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z

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Pick out the wrong statement. (A) Critical moisture content is not a property of the material itself (B) A sharp increase in pressure drop gives an indication of the flooding in a distillation column (C) Separation of components is not possible in liquid extraction, if selectivity is unity (D) Dehydration of ethyl alcohol is most economically done by molecular distillation at very high vacuum

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Pick out the wrong statement. (A) For a first order consecutive reaction, a tubular flow reactor as compared to a stirred tank reactor provides higher overall selectivity(B) For an ideal mixed reactor at steady state, the exit stream has the samecomposition as fluid within the reactor and the space time is equivalent toholding time for constant density system(C) Plug flow reactor (PFR) is always smaller than mixed reactor for allpositive reaction orders for a particular duty(D) Reaction rate does not decrease appreciably as the reaction proceeds incase of an autocatalytic reaction

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Steam distillation is used to (A) Reduce the number of plates (B) Avoid thermal decomposition of a component (C) Increase the efficiency of separation (D) Increase the total pressure of distillation

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Last Answer : (B) Avoid thermal decomposition of a component

Pick out the wrong statement. (A) Constant pressure distillation cannot separate an Azeotropic mixture (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature (C) The relative volatility of a binary mixture at Azeotropic composition is unity (D) Flash distillation is practised on wide spread scale in petroleum refinery

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Last Answer : (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature

As the reflux ratio in a distillation column is increased from the minimum, the (A) Slope of the operating line in stripping section decreases (B) Number of plates decreases very slowly first and then more and more rapidly (C) Total cost first decreases and then increases (D) Liquid flow increases while the vapor flow decreases for a system

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Last Answer : (C) Total cost first decreases and then increases

According to Avogadro’s law  A. the product of the gas constant and the molecular mass of an ideal gas is constant  B. the sum of partial pressure of the mixture of two gases is sum of the two  C. equal volumes of all gases, at the same temperature and pressure, contain equal number of molecules  D. all of the above

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According to Avogadro’s Hypothesis  (a) the molecular weights of all the perfect gases occupy the same volume under same conditions of pressure and temperature  (b) the sum of partial pressure of mixture of two gases is sum of the two  (c) product of the gas constant and the molecular weight of an ideal gas is constant  (d) gases have two values of specific heat  (e) all systems can be regarded as closed systems.

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Last Answer : Answer : a

Fenske-Underwood equation used for calculating the minimum number of theoretical plates in distillation column is valid for (A) Constant molal overflow (B) Total reflux (C) Constant relative volatility (D) All (A), (B) and (C)

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At __________ reflux, theoretical number of plates in a distillation coloumn is calculated using Fenske-Underwood equation. (A) Operating (B) Total (C) Minimum (D) Maximum permissible

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In case of binary distillation, increasing the reflux ratio above optimum does not result in the increase of (A) Area between operating line and 45° diagonal x-y diagram (B) Condenser and reboiler surfaces (C) Tower cross-section (D) None of these

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Pick out the wrong statement. (A) In drying a solid containing moisture above the critical moisture content the number of degrees of freedom is 2 (B) Sherwood number in mass transfer corresponds to Nusselt number in heat transfer and Schmidt number to Prandtl number (C) Forced convection is relatively more effective in increasing the rate of mass transfer, if Schmidt number is larger (D) Hot gases at moderate pressure are usually in the shell side of shell and tube heat exchangers. At higher pressure, however, it is customary to put gas in the tube side

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Pick out the wrong statement (A) A horizontal line on the humidity chart indicates the temperature changes at constant molal humidity (B) When water is cooled from 80 to 70°C by exposure to the air with a wet bulb temperature of 60°C, then both the approach & the range would be 10°C (C) For unsaturated air-water vapor mixture at atmospheric conditions, the wet bulb temperature & adiabatic cooling lines are the same (D) Relative saturation of unsaturated mixture of water vapor & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

Description : Pick out the wrong statement (A) A horizontal line on the humidity chart indicates the temperature changes at constant molal humidity (B) When water is cooled from 80 to 70°C by exposure ... & air cannot be increased by either reducing the mixture temperature or by increasing the total pressure

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Pick out the wrong statement. (A) The operating line always lies above the equilibrium solubility curve in case of a single component absorber (B) The operating line always lies below the equilibrium solubility curve in case of a single component stripper (C) The operating pressure in solvent extraction system should be below vapor pressures of all components (D) The solubility of a particular gas in ideal solution in any solvent is always the same

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In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these

Description : In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these

Last Answer : (B) Partial pressure

Pick out the wrong statement. (A) 'Hold back' is defined as the fraction of material that stays longer than the mean residence time (B) Study of non-ideal flow reactor is done experimentally by stimulus￾response technique (C) For studying a chemical reaction, it is desirable to monitor the reactants during initial stages and the products during the final stages of reaction (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

Description : Pick out the wrong statement. (A) 'Hold back' is defined as the fraction of material that stays longer than the mean residence time (B) Study of non-ideal flow reactor is done experimentally ... final stages of reaction (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

Last Answer : (D) A batch reactor cannot be used to study the kinetics of catalytic reaction

Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by light (D) A chemical reaction occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Description : Pick out the correct statement. (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state (C) A photochemical reaction is catalysed by ... occurs when the energy of the reacting molecule is less than the activation energy of the reaction

Last Answer : (A) Reactions with high activation energies are very temperature sensitive (B) Chemical equilibrium is a static state

In McCabe-Thiele method, at infinite reflux ratio (A) Number of plates is maximum (B) Overhead product is maximum (C) Both the operating lines coincide with the diagram (D) None of these

Description : In McCabe-Thiele method, at infinite reflux ratio (A) Number of plates is maximum (B) Overhead product is maximum (C) Both the operating lines coincide with the diagram (D) None of these

Last Answer : (C) Both the operating lines coincide with the diagram