The Hatta number is important in
(A) Multi-component distillation
(B) Binary distillation
(C) Gas absorption without chemical reaction
(D) Gas absorption with chemical reaction
Description : Pick out the correct statement. (A) Higher hold up of the solid in the rotary dryer results in better exposure of the solids to the gas (B) The 'Hatta number' is ... reflux in case of distillation operation requires infinite number of plates for a binary system separation
Last Answer : (C) For a non-reacting binary mixture of ideal gases, the partial pressure distribution of both components is linear in the case of steady state equimolal counter-diffusion
Description : Pick out the wrong statement (A) Co-current absorbers are usually used, when the gas to be dissolved in the liquid is a pure substance (B) In case of gas absorption, HETP is ... reaction (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process
Last Answer : (D) In actual practice, absorption is an endothermic process, while stripping is an exothermic process
Description : Which of the following unit operations makes use of Thiele-Geddes equation? (A) Liquid-liquid extraction (B) Solid-liquid extraction (C) Multi-component absorption with chemical reaction (D) Multi-component distillation
Last Answer : (D) Multi-component distillation
Description : Flash distillation is (A) Same as differential distillation (B) Used for multi-component systems like crude refining (C) Same as simple distillation (D) Most useful for handling binary systems
Last Answer : (B) Used for multi-component systems like crude refining
Description : Langmuir equation is associated with (A) Leaching (B) Adsorption (C) Steam distillation (D) Multi-component absorption
Last Answer : (B) Adsorption
Description : For which of the following unit operations, Lewis number is ofsignificance? (A) Adsorption (B) Binary distillation (C) Gas absorption (D) Humidification
Last Answer : (D) Humidification
Description : Fenske equation for determining the minimum number of theoretical stages in distillation column holds good, when the (A) Relative volatility is reasonably constant (B) Mixture (to be separated) ... (to be separated) shows positive deviation from ideality (D) Multi-component distillation is involved
Last Answer : (A) Relative volatility is reasonably constant
Description : Steady state equimolal counter diffusion occurs in case of (A) Leaching (B) Absorption (C) Binary phase distillation (D) Liquid-liquid extraction
Last Answer : (C) Binary phase distillation
Description : Steady state equimolal counter diffusion is encountered in (A) Separation of a binary mixture by distillation (B) Absorption of NH3 from air by water (C) All liquid-liquid diffusion systems (D) All liquid-solid diffusion systems
Last Answer : (A) Separation of a binary mixture by distillation
Description : Use of packed towers for distillation is generally limited to the (A) Small sizes (B) Multi-component distillation (C) High pressure operation (D) Vacuum distillation
Last Answer : (A) Small sizes
Description : Binary distillation involves the mass transfer by __________ at the gasliquid interface. (A) Unidirectional diffusion from liquid to gas phase (B) Unidirectional diffusion from gas to liquid phase (C) Either 'a' or 'b' (D) A counter diffusion at an almost equal molar rate
Last Answer : (D) A counter diffusion at an almost equal molar rate
Description : Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these
Last Answer : (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Description : In which of the following unit operations, the selectivity is an important parameter? (A) Distillation (B) Solvent extraction (C) Absorption (D) None of these
Last Answer : (B) Solvent extraction
Description : When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is (A) Same in both the phases (B) Zero in both the phases (C) More in vapour phase (D) More in liquid phase
Last Answer : (A) Same in both the phases
Description : For a multi-component system, the term chemical potential is equivalent to the (A) Molal concentration difference (B) Molar free energy (C) Partial molar free energy (D) Molar free energy change
Last Answer : (C) Partial molar free energy
Description : For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases. (A) Chemical potential (B) Fugacity (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : The main use of heavy gas oil produced by the vacuum distillation unit is as a (A) Blending component for kerosene (B) Blending component for petrol (C) Feedstock for fluid catalytic cracking unit (D) None of these
Last Answer : (C) Feedstock for fluid catalytic cracking unit
Description : An alkaline solution is used to reduce the concentration of carbon dioxide in a stream from 10% to 0.1% by absorption with irreversible chemical reaction. The overall number of transfer units based on gas phase is: (A) 9.21 (B) 4.605 (C) 100 (D) 0.001
Last Answer : (B) 4.605
Description : The Graetz number is concerned with the (A) Mass transfer between a gas and a liquid (B) Absorption with chemical reaction (C) Heat transfer in turbulent flow (D) Heat transfer in laminar flow
Last Answer : (D) Heat transfer in laminar flow
Description : Pick out the wrong statement. (A) In the McCabe-Thiele diagram for binary distillation, vertical feed line represents saturated liquid feed and horizontal feed line represents saturated vapour feed (B) In ... layers over a flat plate are of equal thickness, if Schmidt number is equal to unity
Last Answer : (C) For Laminar flow over a plate of length L, the local mass transfer coefficient at a distance L from the leading edge is 1.5 × 10 -2m/s. Then the average mass transfer co-efficient for the plate is 2 × 10 -2m/s
Description : Pick out the wrong statement. (A) With decrease in feed temperature, the number of plates required for binary distillation decreases for a given L/V' ratio (B) The extraction per unit ... and its crosssection is wider at the bottom (D) Vander wall adsorption is also called chemisorption
Last Answer : (D) Vander wall adsorption is also called chemisorption
Description : Pick out the correct statement. (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of ... Flash distillation is suitable for separating components which have very close boiling temperature
Last Answer : (A) Ponchan-Savarit method is more accurate than McCabe-Thiele method to determine the number of theoretical stages required for the separation of nonideal binary system by distillation
Description : For a binary mixture distillation process, the degree of freedom is 2. However, if the pressure is fixed in this process, the number of independent variables in this process will be (A) 1 (B) 0 (C) 2 (D) 3
Last Answer : (A) 1
Description : According to the Fenske equation, what will be the minimum number of plates required in a distillation column to separate an equimolar binary mixture of components A and B into an overhead fraction containing 99 mol% A and a ... in the column. (A) 5 (B) 9 (C) 12 (D) 28
Last Answer : (C) 12
Description : Black liquor is converted into white liquor by (A) Evaporation and burning the concentrate followed by causticisation of products (B) Multi-effect evaporation only (C) Selective liquid extraction (D) Extractive distillation
Last Answer : (A) Evaporation and burning the concentrate followed by causticisation of products
Description : Absorption with chemical reaction' is involved in the removal of (A) Carbon dioxide from gaseous stream using alkaline solution (B) Benzol from coke oven gas using solar oil/wash oil (C) Ammonia ... gas using refrigerated water (D) Tar from coke oven gas in primary gas coolers using chilled water
Last Answer : (A) Carbon dioxide from gaseous stream using alkaline solution
Description : Absorption accompanied with chemical reaction is exemplified by the absorption of (A) Ammonia in water (B) Benzol present in coke oven gas by wash oil (C) SO2 in alkaline solution (D) All (A), (B) and (C)
Last Answer : (C) SO2 in alkaline solution
Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z
Last Answer : (B) T and P
Description : The-relative volatility for separation of a non-ideal binary mixture by distillation should be (A) 0 (B) 1 (C) > 1 (D) < 1
Last Answer : (C) > 1
Description : McCabe-Thiele method of binary distillation does not assume that the (A) Sensible heat changes are negligible compared with latent heat changes (B) Molar latent heats of all components are equal (C) Heat of mixing is negligible (D) None of these
Last Answer : (D) None of these
Description : Components, having widely different boiling point in a binary mixture, can be separated using __________ distillation. (A) Molecular (B) Extractive (C) Steam (D) Simple
Last Answer : (D) Simple
Description : In case of binary distillation, increasing the reflux ratio above optimum does not result in the increase of (A) Area between operating line and 45° diagonal x-y diagram (B) Condenser and reboiler surfaces (C) Tower cross-section (D) None of these
Last Answer : (A) Area between operating line and 45° diagonal x-y diagram
Description : Pick out the correct statement. (A) The slope of the stripping line is always less than unity (B) For a given separation in a binary distillation column, with increase in reflux ratio ( ... (D) Kremser-Brown-Souder's equation is used to calculate the efficiency of a plate tower
Last Answer : C) In Ponchon-Savarit method of no. of theoretical plate determination, the stripping and rectifying operating lines are vertical at total reflux
Description : Flash distillation is suitable for separating the constituents of a binary system, which (A) Form minimum boiling azeotrope (B) Have very wide boiling points (C) Have very close boiling points (D) Form constant boiling azeotrope
Last Answer : (B) Have very wide boiling points
Description : Pick out the wrong statement. (A) Constant pressure distillation cannot separate an Azeotropic mixture (B) Relative volatility of a binary mixture changes appreciably with the minor change in ... unity (D) Flash distillation is practised on wide spread scale in petroleum refinery
Last Answer : (B) Relative volatility of a binary mixture changes appreciably with the minor change in temperature
Description : A binary mixture of benzene and cyclohexane is separated by (A) Flash vaporisation (B) Extractive distillation (C) Solvent extraction (D) Ordinary distillation
Last Answer : (B) Extractive distillation
Description : In a binary distillation column, if the feed contains 40 mole % vapour, the q line will have a slope of (A) 1.5 (B) -0.6 (C) -1.5 (D) 0.6
Last Answer : (C) -1.5
Description : For a binary mixture with low relative volatility, (A) Use steam distillation (B) Use molecular distillation (C) Use high pressure distillation (D) An azeotrope may be formed during distillation
Last Answer : (D) An azeotrope may be formed during distillation
Description : Heat sensitive materials with very high latent heat of vaporisation may be economically separated using (A) Liquid extraction (B) Distillation (C) Evaporation (D) Absorption
Last Answer : (A) Liquid extraction
Description : The recovery of penicillin from the acidified fermentation broth is done by (A) Distillation (B) Evaporation (C) Absorption (D) Liquid extraction
Last Answer : (D) Liquid extraction
Description : ADDUCTS' and 'CLATHRATES' are used in case of (A) Extractive distillation (B) Crystallisation (C) Absorption (D) None of these
Last Answer : (B) Crystallisation
Description : Acetic acid will be most economically separated from a dilute solution of acetic acid in water by (A) Solvent extraction (B) Continuous distillation (C) Evaporation (D) Absorption
Last Answer : (A) Solvent extraction
Description : When acetone is added in a two layer mixture of methyl isobutyl ketone and water at 30°C, the acetone distributes between the two layers and the composition of the layer follows two solubility curves. For this system ... at the concentration of the plait point (D) All (A), (B) and (C
Last Answer : (D) All (A), (B) and (C
Description : A 'unit process' is exemplified by the (A) Distillation (B) Hydrogenation of oils (C) Absorption (D) Humidification
Last Answer : (B) Hydrogenation of oils
Description : In distillation, overhead product contains (A) Only one component (B) Two components (C) Any number of components (D) Only saturated liquid
Last Answer : (C) Any number of components
Description : Steam distillation is used to (A) Reduce the number of plates (B) Avoid thermal decomposition of a component (C) Increase the efficiency of separation (D) Increase the total pressure of distillation
Last Answer : (B) Avoid thermal decomposition of a component
Description : With lapse of time, the overhead composition of light component in case of batch distillation with constant reflux (A) Increases (B) Decreases (C) Remain same (D) May increase or decrease; depends on system
Last Answer : (B) Decreases
Description : Design calculation for multiple component distillation is done by (A) Ponchon-Savarit method (B) McCabe-Thiele method (C) Enthalpy concentration method (D) Tray to tray calculations
Last Answer : (D) Tray to tray calculations
Description : steam distillation, the (A) Temperature is 100°C(B) Temperature is more than 100° C (C) Product must be immiscible with water (D) Temperature is higher than the boiling point of either component
Last Answer : (C) Product must be immiscible with water
Description : Light oil whose major component is Benzol, is obtained by the distillation of crude tar in the temperature range of __________ °C. (A) 80-170 (B) 200-300 (C) 250-270
Last Answer : (A) 80-170