Description : For a real gas, the chemical potential is given by (A) RT d ln P (B) RT d ln f (C) R d ln f (D) None of these
Last Answer : (B) RT d ln f
Description : At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm. ... (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f
Last Answer : (A) μ° + RT ln f
Description : The free energy change for a chemical reaction is given by (where, K = equilibrium constant) (A) RT ln K (B) -RT ln K (C) -R ln K (D) T ln K
Last Answer : (B) -RT ln K
Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12
Last Answer : (A) A . x22
Description : Helium ( R= 0.4698 BTU/lbm-˚R ) is compressed isothermally from 14.7 psia and 68 ˚F. The compression ratio is 1:4. Calculate the work done by the gas. A. –1454 BTU/lbm B. -364 BTU/lbm C.-187BTU/lbm D.46.7 BTU/lbm Formula: W = RT ln (V2/V1)
Last Answer : -364 BTU/lbm
Description : Pick out the Clausius-Clapeyron equation from the following: (A) dP/dT = ∆H/T∆V (B) ln P = - (∆H/RT) + constant (C) ∆F = ∆H + T [∂(∆F)/∂T]P (D) None of these
Last Answer : B) ln P = - (∆H/RT) + constant
Description : If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.) A.9.8 ft^3/lbm B.11.2 ft^3/lbm C.13.33 ft^3/lbm D.14.2 ft^3/lbm Formula: pv = RT v = RT / p
Last Answer : 13.33 ft^3/lbm
Description : The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving ... (C) Kc = Kp . RT = Km . RT/p (D) None of these
Last Answer : (C) Kc = Kp . RT = Km . RT/p
Description : To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (∆HV/R) (1/T1- 1/T2) from the exact Clapeyron equation, it is assumed that the (A) Volume of the liquid phase is negligible compared to ... gas (C) Heat of vaporisation is independent of temperature (D) All (A), (B) & (C)
Last Answer : (D) All (A), (B) & (C)
Description : Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor? (A) d ln p/dt = Hvap/RT2 (B) d ln p/dt = RT2/Hvap (C) dp/dt = RT2/Hvap (D) dp/dt = Hvap/RT2
Last Answer : (A) d ln p/dt = Hvap/RT2
Description : The compressibility factor, x, is used for predicting the behavior of nonideal gases. How is the compressibility ty factor defined relative to an ideal gas? (subscript c refers to critical value) A. ... compressibility factor, x, is an dimensionless constant given by pV=zRT. Therefore z = pV / RT
Last Answer : z = pV/ RT
Description : The theoretical minimum work required to separate one mole of a liquid mixture at 1 atm, containing 50 mole % each of n- heptane and n octane into pure compounds each at 1 atm is (A) -2 RT ln 0.5 (B) -RT ln 0.5 (C) 0.5 RT (D) 2 RT
Last Answer : (B) -RT ln 0.5
Description : The expression for entropy change given by, ΔS = - nR ln (P2/P1), holds good for (A) Expansion of a real gas (B) Reversible isothermal volume change (C) Heating of an ideal gas (D) Cooling of a real gas
Last Answer : (B) Reversible isothermal volume change
Description : The expression for entropy change given by, ΔS = nR ln (V2/V1) + nCvln (T2/T1) is valid for (A) Reversible isothermal volume change (B) Heating of a substance (C) Cooling of a substance (D) Simultaneous heating and expansion of an ideal gas
Last Answer : (D) Simultaneous heating and expansion of an ideal gas
Description : In the equation Pv = RT, the constant of proportionality R is known as ______. A. Universal gas constant B. Gas constant C. Ideal gas factor D. Gas index
Last Answer : Gas constant
Description : What is the equation for the work done by a constant temperature system? A. W = mRTln(V2-V1) B. W = mR( T2-T1 ) ln( V2/V1) C. W = mRTln (V2/V1) D. W = RT ln (V2/V1) Formula : W=∫ pdV lim1,2 ∫ = mRT / V
Last Answer : W = mRTln (V2/V1)
Description : Consider an ideal solution of components A and B. The entropy of mixing per mole of an alloy containing 50% B is (A) R ln 2 (B) -R ln 2 (C) 3 R ln 2 (D) -3R ln 2
Last Answer : (A) R ln 2
Description : The expression, ∆G = nRT. ln(P2/P1), gives the free energy change (A) With pressure changes at constant temperature (B) Under reversible isothermal volume change (C) During heating of an ideal gas (D) During cooling of an ideal gas
Last Answer : (A) With pressure changes at constant temperature
Description : The expression, nRT ln(P1/P2), is for the __________of an ideal gas. (A) Compressibility (B) Work done under adiabatic condition (C) Work done under isothermal condition (D) Co-efficient of thermal expansion
Last Answer : C) Work done under isothermal condition
Description : In an ideal P.F.R. at steady state conditions (A) The composition of reactants remains constant along a flow path (B) The conversion of the reactant varies from point to point along a flow path (C) There is no lateral mixing of fluid (D) There may be diffusion along the flow path
Last Answer : (B) The conversion of the reactant varies from point to point along a flow path
Description : What mass of nitrogen is contained in a10 ft3 vessel at a pressure of 840atm and 820°R? Make a computation by using ideal gas equation. a. 194lb b. 214lb c. 394 lb d. 413lb formula: m=pV /RT
Last Answer : 394 lb
Description : What is the value of ln y (where y = activity co-efficient) for ideal gases? (A) Zero (B) Unity (C) Infinity (D) Negative
Last Answer : (A) Zero
Description : The potential of a uniformly charged line with density λ is given by, λ/(2πε) ln(b/a). State True/False. a) True b) False
Last Answer : a) True
Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)
Last Answer : (C) Temperature
Description : Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only
Last Answer : (A) Pressure & temperature
Description : In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these
Last Answer : (B) Partial pressure
Description : Pick out the wrong statement: (A) Chemical reactions with high activation energy are very temperature sensitive (B) A flat velocity profile exists in a plug flow reactor (C) The residence ... D) Half life of a reaction increases with increased initial concentration for reaction orders more than one
Last Answer : (C) The residence time for all the elements of fluid in case of a P.F.R. need not be same
Description : Pick out the correct statement. (A) Plastic chips are called non-cohesive solids (B) Kick's crushing law is, P/m = K . ln (D̅sa /Ds̅b ) (C) Communition is a generic term for size enlargement ... per ton of product, such that 80% of it passes through a 200 mesh screen, is called 'Work index'
Last Answer : (B) Kick's crushing law is, P/m = K . ln (D̅sa /Ds̅b )
Description : . Which of the following equations is Rittinger's crushing law? (Where P = power required by the machine, m = feed rate, k = a constant, Ds̅a & D̅sb = volume surface mean diameter of feed & product respectively.) (A) P/m = K/ ... K . ln D̅sa /D̅sb (C) P/m = K . (1/ D̅sb - 1/Ds̅a ) (D) None of these
Last Answer : (C) P/m = K . (1/ D̅sb - 1/Ds̅a )
Description : The value of Steric factor 'P' in the equation k = PZe E/RT usually ranges from (A) 1.0 to 10 -8 (B) 1.1 to 10 2 (C) 0.1 to 0.9 (D) None of these
Last Answer : (A) 1.0 to 10 -8
Description : The chemical potential of any constituent of an ideal solution depends on the __________ of the solution. (A) Temperature (B) Pressure (C) Composition (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)
Description : Chemical potential of ith component of a system is given by (A) µi = (∂F/∂ni)T, P, ni (B) µi = (∂A/∂ni)T, P, ni (C) µi = (∂F/∂ni)T, P (D) µi = (∂A/∂ni)T, P
Last Answer : A) µi = (∂F/∂ni)T, P, ni
Description : Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by (A) k. t = ln a/(a - x) (B) k. t = x/a (a - x) (C) k. t = ln (a - x)/a (D) k. t = ln a (a - x)/x
Last Answer : (A) k. t = ln a/(a - x)
Description : The thickness of oxide film is y at time t. If K1, K2 and K3 are the temperature dependent constants, the parabolic law of oxidation is given by (A) y2 = 2k1t + k2 (B) y = k1 ln (k2t + k3) (C) y = k1 t + k2 (D) y = k1t3 + k2
Last Answer : Option A
Description : The formula for computing impedance in a series circuit containing resistance, capacitance, and inductance is _____________. [ NOTE: the symbol * stands for 'multiplied by' ] A. Z = RT + XL + XC B. Z = R + XL - XC C. Z * Z = R * R + (XL - XC) * (XL - XC) D. Z = R * R + (XL * XC) - (XL * XC)
Last Answer : Answer: C
Description : If the potential is given by, V = 10sin θ cosφ/r, find the density at the point P(2, π/2, 0) (in 10 -12 units) a) 13.25 b) 22.13 c) 26.31 d) 31.52
Last Answer : b) 22.13
Description : he gas law (PV = RT) is true for an __________ change. (A) Isothermal (B) Adiabatic (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) & (B)
Description : In the given figure, YZ is parallel to MN, XY is parallel is LM and XZ is parallel to LN. Then MY is -Maths 9th
Last Answer : answer:
Description : The inductance of a coaxial cable with inner radius a and outer radius b, from a distance d, is given by a) L = μd ln(b/a)/2π b) L = 2π μd ln(b/a) c) L = πd/ln(b/a) d) L = 0
Last Answer : a) L = μd ln(b/a)/2π
Description : Given an open address hash table with load factor a < 1, the expected number of probes in a successful search is (A) Atmost 1/α ln (1-α/α) (B) Atmost 1/α ln (1/1-α) (C) Atleast 1/α ln (1/1-α) (D) Atleast 1/α ln (α/1-α)
Last Answer : (B) Atmost 1/α ln (1/1-α)
Description : 3.0 lbm of air are contained at 25 psia and 100 ˚F. Given that Rair = 53.35 ft-lbf/lbm- ˚F, what is the volume of the container? A.10.7 ft^3 B.14.7 ft^3 C.15 ft^3 D.24.9 ft^3 Formula: use the ideal gas law pV = mRT T = (100 +460) ˚R V = mRT/p
Last Answer : 24.9 ft^3
Description : The ratio of volume of mixed reactor to the volume of P.F.R. (for identical flow rate, feed composition and conversion) for zero order reaction is: (A) ∞ (B) 0 (C) 1 (D) > 1
Last Answer : (C) 1
Description : In case of a P.F.R., there (A) May be lateral mixing of fluid (B) Should not be any mixing along the flow path (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : The performance equations for constant density systems are identical for (A) P.F.R. and backmix reactor (B) P.F.R. and batch reactor (C) P.F.R, batch reactor and backmix reactor (D) Batch reactor and backmix reactor
Last Answer : (B) P.F.R. and batch reactor
Description : . The entropy change in a reversible isothermal process, when an ideal gas expands to four times its initial volume is (A) R loge 4 (B) R log10 4 (C) Cv log10 4 (D) Cv loge 4
Last Answer : (A) R loge 4
Description : y = specific heat ratio of an ideal gas is equal to (A) Cp/Cv (B) Cp/(CP-R) (C) 1 + (R/CV) (D) All (A), (B) and (C)
Last Answer : D) All (A), (B) and (C)
Description : The equation, Cp- Cv = R, is true for __________ gas. (A) No (B) Any real (C) Only ideal (D) Both (B) and (C)
Last Answer : (C) Only ideal
Description : For an ideal gas, Cp- Cvis (A) R (B) -R (C) 0 (D) (3/2) R
Last Answer : (A) R