Description : When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is (A) Same in both the phases (B) Zero in both the phases (C) More in vapour phase (D) More in liquid phase
Last Answer : (A) Same in both the phases
Description : At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm. ... (B) μ°+ R ln f (C) μ° + T ln f (D) μ° + R/T ln f
Last Answer : (A) μ° + RT ln f
Description : The necessary and sufficient condition for equilibrium between two phases is (A) The concentration of each component should be same in the two phases (B) The temperature of each phase should be same ( ... the two phases (D) The chemical potential of each component should be same in the two phases
Last Answer : (D) The chemical potential of each component should be same in the two phases
Description : When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is (A) More in vapour phase (B) More in liquid phase (C) Same in both the phases (D) Replaced by chemical potential which is more in vapour phase
Last Answer : (C) Same in both the phases
Description : For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases. (A) Decreases (B) Increases (C) Remain same (D) Decreases linearly
Last Answer : (B) Increases
Description : A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yiis the liquid activity co- ... and liquid composition xi only (D) Temperature, pressure, liquid composition xi and vapour composition yi
Last Answer : (C) Temperature, pressure and liquid composition xi only
Description : Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and ... increases. (A) Decreases (B) Decreases exponentially (C) Increases (D) Remain constant
Last Answer : (C) Increases
Description : The standard state of a gas (at a given temperature) is the state in which fugacity is equal to (A) Unity (B) Activity (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) & (B)
Description : The necessary condition for phase equilibrium in a multiphase system of N components is that the (A) Chemical potentials of a given component should be equal in all phases (B) Chemical potentials of all ... potentials of any given component in all the phases should be the same (D) None of these
Last Answer : (A) Chemical potentials of a given component should be equal in all phases
Description : In an ideal solution, the activity of a component equals its (A) Mole fraction (B) Fugacity at the same temperature and pressure (C) Partial pressure (D) None of these
Last Answer : (A) Mole fraction
Description : What happens when a chemical bond is formed? (1) energy is always absorbed (2) energy in always released (3) more energy is released than is absorbed (4) energy is neither released nor ... as potential energy. Upon the breaking of these bonds the energy is released thereby creating usable energy.
Last Answer : Silver nitrate solution is kept in brown bottles in laboratory because - (1) it reacts with ordinary white bottles (2) brown bottles stops the passage of light through it (3) brown bottles do not react with it (4) brown bottles react with it
Description : With increase in temperature, the equilibrium __________ rises in case of endothermic reaction. (A) Constant (B) Conversion (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (B) Conversion
Description : In an ideal gas mixture, fugacity of a species is equal to its (A) Vapor pressure (B) Partial pressure (C) Chemical potential (D) None of these
Last Answer : (B) Partial pressure
Description : In a homogeneous solution, the fugacity of a component depends upon the (A) Pressure (B) Composition (C) Temperature (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Fugacity is a measure of the (A) Escaping tendencies of the same substance in different phases of a system (B) Relative volatility of a mixture of two miscible liquids (C) Behaviour of ideal gases (D) None of these
Last Answer : (A) Escaping tendencies of the same substance in different phases of a system
Description : Partial molar free energy of an element A in solution is same as its (A) Chemical potential (B) Activity (C) Fugacity (D) Activity co-efficient
Last Answer : (A) Chemical potential
Description : Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation. (A) Gibbs-Duhem (B) Maxwell's (C) Clapeyron (D) None of these
Last Answer : (C) Clapeyron
Description : In a packed absorption tower, if the equilibrium and operating lines are both straight lines, then the ratio, HETP/HTUOG __________ the absorption factor. (A) Increases with increase in (B) Is one at unity value of (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : For the reversible exothermic reaction, N2 + 3H2 ⇌ 2NH3, increase of pressure would (A) Shift the equilibrium towards right (B) Give higher yield of NH3 (C) Both (B) and (C) (D) Neither (A) nor (B)
Last Answer : (C) Both (B) and (C)
Description : Slurry reactors are characterised by the (A) Lack of intraparticle diffusion resistance (B) Presence of two mobile phases (C) Both (A) and (B) (D) Neither (A) nor (B)
Description : For a multi-component system, the term chemical potential is equivalent to the (A) Molal concentration difference (B) Molar free energy (C) Partial molar free energy (D) Molar free energy change
Last Answer : (C) Partial molar free energy
Description : Pick out the wrong statement. (A) Activity co-efficient is dimensionless. (B) In case of an ideal gas, the fugacity is equal to its pressure. (C) In a mixture of ideal gases, the fugacity of ... equal to the partial pressure of the component. (D) The fugacity co-efficient is zero for an ideal gas
Last Answer : (D) The fugacity co-efficient is zero for an ideal gas
Description : In an interphase heat transfer process, the equilibrium state corresponds to equality of temperature in the two phases, while the condition for equilibrium in an interphase mass transfer process is ... B) Chemical potentials (C) Activity co-efficients (D) Mass transfer co-efficients
Last Answer : (A) Concentrations
Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)
Last Answer : (D) All (A), (B), and (C)
Description : For __________ drying, the effects of velocity, temperature and humidity of the gas and the thickness of the solid are the same. (A) Unsaturated surface (B) Constant rate (C) Both (A) and (B) (D) Neither (A) nor (B)
Description : Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance ... temperature and pressure is (A) 0 (B) 1 (C) ∞ (D) None of these
Last Answer : (B) 1
Description : If a system involves two phases, it is in ______ equilibrium when the mass of each phase reaches an equilibrium level and stays there. A. Chemical B. Thermal C. Mechanical D. Phase
Last Answer : Phase
Description : In a packed tower, the value of HETP equals HTUOG, when the equilibrium and the operating lines are (where, HETP = height equivalent to a theoretical plate HTUOG = overall gas phase height of a transfer unit). (A) Straight (B) Parallel (C) Both (A) & (B) (D) Neither (A) nor (B
Description : If the overall efficiency and Murphree plate efficiency are equal, then both the equilibrium and operating lines are: (A) Straight (B) Parallel (C) Both (A) & (B) (D) Neither (A) nor (B)
Description : The unit of fugacity is the same as that of the (A) Pressure (B) Temperature (C) Volume (D) Molar concentration
Last Answer : (A) Pressure
Description : With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure (A) Increases (B) Decreases (C) Remain same (D) Decreases linearly
Last Answer : (A) Increases
Description : Corrosion involves exchange of electrons in __________ corrosion. (A) Chemical (B) Electrochemical (C) Both (A) & (B) (D) Neither (A) nor (B)
Description : Design of heterogamous catalytic reactor involves consideration of __________ steps. (A) Only chemical (B) Only physical (C) Both (A) & (B) (D) Neither (A) nor (B)
Description : For a solid catalysed chemical reaction, the effectiveness of solid catalyst depends upon the __________ adsorption. (A) Physical (B) Chemical (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (B) Chemical
Description : Chemical kinetics can predict the __________ of a chemical reaction. (A) Rate (B) Feasibility (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (A) Rate
Description : Fugacity and pressure are numerically not equal for the gases (A) At low temperature and high pressure (B) At standard state (C) Both (A) and (B) (D) In ideal state
Description : If a two phase system is in physical equilibrium; then it means that, the (A) Escaping tendency of each component from the liquid phase to the vapor phase is exactly equal to that from vapor phase to liquid phase ... liquid phase is equal to that throughout the vapor phase (D) All (A), (B) and (C)
Description : The variation of atmospheric potential is caused due to: (A) Difference in temperature over the surface of the earth (B) Change in the density of air (C) Both (a) and (b) (D) Neither (a) nor (b)
Last Answer : (C) Both (a) and (b)
Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)
Description : Solid and liquid phases of a substance are in equilibrium at the (A) Critical temperature (B) Melting point (C) Freezing point (D) Both (B) and (C)
Last Answer : D) Both (B) and (C)
Description : In a liquid-liquid extraction, 10 kg of a solution containing 2 kg of solute C and 8 kg of solvent A is brought into contact with 10 kg of solvent B. Solvent A and B are completely immiscible in each other whereas ... (C) Less than 1 kg of C is transferred to B (D) No amount of C is transferred to B
Last Answer : (A) The entire amount of C is transferred to solvent B
Description : The 'shanks system' of leaching (i.e., counter-current multiple contact leaching) is used for (A) Recovery of tannis from the tree barks and woods (B) Leaching sodium nitrate from Chilean nitrate bearing rock (C) Both (A) and (B) (D) Neither (A) nor (B)
Description : Economy of a multiple effect evaporator depends upon the (A) Heat balance consideration (B) Rate of heat transfer (C) Both (A) and (B) (D) Neither (A) nor (B
Last Answer : (A) Heat balance consideration
Description : For multiple reactions, the flow pattern within the vessel affects the (A) Size requirement (B) Distribution of reaction products (C) Both (A) and (B) (D) Neither (A) nor (B)
Description : For a given substance at a specified temperature, activity is __________ to fugacity. (A) Directly proportional (B) Inversely proportional (C) Equal (D) None of these
Last Answer : (A) Directly proportional
Description : The cake resistance increases steadily with the time of filtration in a plate and frame filter employing constant __________ filtration. (A) Rate (B) Pressure (C) Both (A) & (B) (D) Neither (A) nor (B
Description : . A Rotameter works on the principle of __________ pressure drop. (A) Constant (B) Variable (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (A) Constant
Description : Velocity head on sudden enlargement in a horizontal pipe is converted into __________ head. (A) Elevation (B) Pressure (C) Both (A) & (B) (D) Neither (A) nor (B)
Last Answer : (B) Pressure
Description : __________ increases with increase in pressure. (A) The melting point of wax (B) The boiling point of a liquid (C) Both (A) and (B) (D) Neither (A) nor (B)
Description : Dry bulb temperature of unsaturated air is more than its __________ temperature. (A) Dew point (B) Wet bulb (C) Both 'a' & 'b' (D) Neither 'a' nor 'b
Last Answer : (C) Both 'a' & 'b