Description : Gibbs phase rule finds application, when heat transfer occurs by (A) Conduction (B) Convection (C) Radiation (D) Condensation
Last Answer : (D) Condensation
Description : The four properties of a system viz. P, V, T, S are related by __________ equation. (A) Gibbs-Duhem (B) Gibbs-Helmholtz (C) Maxwell's (D) None of these
Last Answer : (C) Maxwell's
Description : “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these
Last Answer : (B) Called Lewis-Randall rule
Description : The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation. (A) Gibbs-Duhem (B) Van Laar (C) Gibbs-Helmholtz (D) Margules
Last Answer : (A) Gibbs-Duhem
Description : Pick out the wrong statement. (A) Minimum number of degree of freedom of a system is zero (B) Degree of freedom of a system containing a gaseous mixture of helium, carbon ... ) Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
Last Answer : (D) Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
Description : Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is (A) 2 (B) 0 (C) 1 (D) 3
Last Answer : (A) 2
Description : If a reaction has an enthalpy of -54.32 kJ/mol and an entropy of -354.2 J/(K*mol), what is the Gibbs free Energy at 54.3(degrees c)?
Last Answer : DeltaG = DeltaH - TDeltaS dG = -54.32 kJ/mol - (54'32+273)K(-354.2J/molK) NB Thevtemperature is quoted in Kelvin(K) and the Entropy must be converted to kJ by dividing by '1000'/ Hence dG = ... 115.94 kJ/mol dG = (+)61.61 kJ/mol Since dG is positive, the reaction is NOT thermodynamically feasible.
Description : The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are: (A) 1 (B) 2 (C) 3 (D) 0
Last Answer : (B) 2
Description : When a gas is expanded from high pressure region to low pressure region; temperature change occurs". This phenomenon is related to the (A) Gibbs-Duhem equation (B) Gibbs-Helmholtz equation (C) Third law of thermodynamics (D) Joule-Thomson effect
Last Answer : (D) Joule-Thomson effect
Description : Specific __________ does not change during phase change at constant temperature and pressure. (A) Entropy (B) Gibbs energy (C) Internal energy (D) Enthalpy
Last Answer : (B) Gibbs energy
Description : Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.). (A) Entropy (B) Internal energy (C) Enthalpy (D) Gibbs free energy
Last Answer : (D) Gibbs free energy
Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)
Last Answer : (D) All (A), (B), and (C)
Description : _________ does not change during phase transformation processes like sublimation, melting & vaporisation. (A) Entropy (B) Gibbs free energy (C) Internal energy (D) All (A), (B) & (C)
Last Answer : (B) Gibbs free energy
Description : (∂H/∂T)P is the mathematical expression for (A) CV (B) Entropy change (C) Gibbs free energy (D) None of these
Last Answer : (D) None of these
Description : Gibbs-Helmholtz equation is (A) ∆F = ∆H + T [∂(∆F)/∂T]P (B) ΔF = ΔH - TΔT (C) d(E - TS) T, V < 0 (D) dP/dT = ∆Hvap/T.∆Vvap
Last Answer : (A) ∆F = ∆H + T [∂(∆F)/∂T]P
Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12
Last Answer : (A) A . x22
Description : During free vibration, different degrees of freedom oscillate with different phase angles.
Last Answer : False
Description : Pick out the wrong statement. (A) In drying a solid containing moisture above the critical moisture content the number of degrees of freedom is 2 (B) Sherwood number in mass transfer corresponds to ... tube heat exchangers. At higher pressure, however, it is customary to put gas in the tube side
Last Answer : (C) Forced convection is relatively more effective in increasing the rate of mass transfer, if Schmidt number is larger
Description : he number of degrees of freedom at the triple point of water is (A) 0 (B) 1 (C) 2 (D) 3
Last Answer : (A) 0
Description : What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor? (A) 2 (B) 0 (C) 3 (D) 1
Description : The number of degrees of freedom for a mixture of ice and water (liquid) are (A) 3 (B) 2 (C) 1 (D) 0
Last Answer : (C) 1
Description : For any system, what is the minimum number of degrees of freedom? (A) 0 (B) 1 (C) 2 (D) 3
Description : Degrees of freedom at triple point will be (A) 0 (B) 1 (C) 2 (D) 3
Description : __________ is concerned with the adsorption equilibria. (A) Fick's law (B) Gibb's equation (C) Freundlich equation (D) None of these
Last Answer : (C) Freundlich equation
Description : Equation which relates pressure, volume and temperature of a gas is called the (A) Equation of state (B) Gibbs Duhem equation (C) Ideal gas equation (D) None of these
Last Answer : (A) Equation of state
Description : Boiling of liquid is accompanied with increase in the (A) Vapor pressure (B) Specific Gibbs free energy (C) Specific entropy (D) All (A), (B) and (C)
Last Answer : (A) Vapor pressure
Description : Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these
Last Answer : (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Description : Specific/molar Gibbs free energy for a pure substance does not change during (A) Sublimation (B) Vaporisation (C) Melting (D) Either (A), (B) or (C)
Last Answer : (D) Either (A), (B) or (C)
Description : The change in Gibbs free energy for vaporisation of a pure substance is (A) Positive (B) Negative (C) Zero (D) May be positive or negative
Last Answer : (C) Zero
Description : Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature. (A) Infinity (B) Minus infinity (C) Zero (D) None of these
Last Answer : (B) Minus infinity
Description : Gibbs free energy at constant pressure and temperature under equilibrium conditions is (A) ∞ (B) 0 (C) Maximum (D) Minimum
Last Answer : (D) Minimum
Description : If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as (A) Solubility increases as temperature ... (D) Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
Last Answer : (B) Solubility increases as temperature decreases
Description : In any spontaneous process, the __________ free energy decreases. (A) Helmholtz (B) Gibbs (C) Both ‘a’ & ‘b’ (D) Neither 'a' nor 'b'
Last Answer : (C) Both ‘a’ & ‘b’
Description : Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation. (A) Gibbs-Duhem (B) Maxwell's (C) Clapeyron (D) None of these
Last Answer : (C) Clapeyron
Description : Gibbs free energy per mole for a pure substance is equal to the (A) Latent heat of vaporisation (B) Chemical potential (C) Molal boiling point (D) Heat capacity
Last Answer : (B) Chemical potential
Description : Gibbs free energy of mixing at constant pressure and temperature is always (A) 0 (B) ∞ (C) + ve (D) - ve
Last Answer : (D) - ve
Description : The standard Gibbs free energy change of a reaction depends on the equilibrium (A) Pressure (B) Temperature (C) Composition (D) All (A), (B) and (C)
Last Answer : (B) Temperature
Description : The change in __________ is equal to the reversible work for compression in steady state flow process under isothermal condition. (A) Internal energy (B) Enthalpy (C) Gibbs free energy (D) Helmholtz free energy
Last Answer : (C) Gibbs free energy
Description : Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs Helmholtz equation? (A) [∂(G/T)/∂T] = - (H/T2) (B) [∂(A/T)/∂T]V = - E/T2 (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : Number of displacement polynomials used for an element depends on . a.nature of element b.type of an element c.degrees of freedom d.nodes
Last Answer : c.degrees of freedom
Description : The number of moveable joints in the base, the arm, and the end effectors of the robot determines_________ a) degrees of freedom b) payload capacity c) operational limits d) flexibility
Last Answer : a) degrees of freedom
Description : The number of moveable joints in the base, the arm, and the end effectors of the robot determines A : degrees of freedom B : payload capacity C : operational limits D : flexibility
Last Answer : A : degrees of freedom
Description : The number of degrees of freedom in simple spring mass system is A. Zero B. One C. Two D. Three
Last Answer : B. One
Description : The number of degrees of freedom of a vibrating system depends on a. number of masses b. number of masses and degrees of freedom of each mass c. number of coordinates used to describe the position of each mass d. None of the above
Last Answer : b. number of masses and degrees of freedom of each mass
Description : The number of degrees of freedom of a simple pendulum is: (a) 0 (b) 1 (c) 2
Last Answer : (b) 1
Description : 5-Match the following Robot part Function a. Manipulator arm 1. For holding a piece or tool b. Controllers 2. Move the manipulator arm and end effector c. Drives 3. Number of degrees of freedom of movement d. Gripper 4. Delivers commands to the ... -1 (C) a-3, b-2, c-4, d-1 (D) a-4, b-3, c-2, d-1
Last Answer : B
Description : Maximum number of degrees of freedom for two component system is a) One b) Two c) Three d) Zero
Last Answer : c) Three
Description : A balanced three-phase, 50 Hz voltage is applied to a 3 phase, 4 pole, induction motor. When the motor is delivering rated output, the slip is found to be 0.05. The speed of the rotor m.m.f. relative to the rotor structure is (A) 1500 r.p.m. (B) 1425 r.p.m. (C) 25 r.p.m. (D) 75 r.p.m.
Last Answer : (D) 75 r.p.m.
Description : State the application of phase sequence indicator; clip on ammeter, frequency meter & P.F. meter.
Last Answer : Phase Sequence Indicator: 1. For finding correct phase sequence of supply 2. For obtaining exact instant of parallel operation of alternators. 3. For obtaining reversal of rotation ... 4. In electroplating industries 5. In various processes industries for measuring power factor
Description : A 500 MW, 3-phase, Y-connected synchronous generator has a rated voltage of 21.5 kV at 0.85 p.f. The line current when operating at full load rated conditions will be (A) 13.43 kA (B) 15.79 kA (C) 23.25 kA (D) 27.36 kA
Last Answer : A 500 MW, 3-phase, Y-connected synchronous generator has a rated voltage of 21.5 kV at 0.85 p.f. The line current when operating at full load rated conditions will be 15.79 kA