Description : When a gas is expanded from high pressure region to low pressure region; temperature change occurs". This phenomenon is related to the (A) Gibbs-Duhem equation (B) Gibbs-Helmholtz equation (C) Third law of thermodynamics (D) Joule-Thomson effect
Last Answer : (D) Joule-Thomson effect
Description : The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation. (A) Gibbs-Duhem (B) Van Laar (C) Gibbs-Helmholtz (D) Margules
Last Answer : (A) Gibbs-Duhem
Description : Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation. (A) Gibbs-Duhem (B) Maxwell's (C) Clapeyron (D) None of these
Last Answer : (C) Clapeyron
Description : Gibbs-Helmholtz equation is (A) ∆F = ∆H + T [∂(∆F)/∂T]P (B) ΔF = ΔH - TΔT (C) d(E - TS) T, V < 0 (D) dP/dT = ∆Hvap/T.∆Vvap
Last Answer : (A) ∆F = ∆H + T [∂(∆F)/∂T]P
Description : Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs Helmholtz equation? (A) [∂(G/T)/∂T] = - (H/T2) (B) [∂(A/T)/∂T]V = - E/T2 (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure. (A) Fugacity (B) Partial pressure (C) Activity co-efficient (D) All (A), (B), and (C)
Last Answer : (D) All (A), (B), and (C)
Description : Gibbs-Duhem equation (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure (B) Applies only to binary systems (C) Finds no application in gas-liquid equilibria involved in distillation (D) None of these
Last Answer : (A) States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Description : Equation which relates pressure, volume and temperature of a gas is called the (A) Equation of state (B) Gibbs Duhem equation (C) Ideal gas equation (D) None of these
Last Answer : (A) Equation of state
Description : The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H - P. This equation is called the (A) Maxwell's equation (B) Thermodynamic equation of state (C) Equation of state (D) Redlich-Kwong equation of state
Last Answer : (B) Thermodynamic equation of state
Description : In any spontaneous process, the __________ free energy decreases. (A) Helmholtz (B) Gibbs (C) Both ‘a’ & ‘b’ (D) Neither 'a' nor 'b'
Last Answer : (C) Both ‘a’ & ‘b’
Description : The change in __________ is equal to the reversible work for compression in steady state flow process under isothermal condition. (A) Internal energy (B) Enthalpy (C) Gibbs free energy (D) Helmholtz free energy
Last Answer : (C) Gibbs free energy
Description : The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is (A) (∂T/∂V)S = - (∂P/∂S)V (B) (∂S/∂P)T = - (∂V/∂T)P (C) (∂V/∂S)P = (∂T/∂P)S (D) (∂S/∂V)T = (∂P/∂T)V
Last Answer : (D) (∂S/∂V)T = (∂P/∂T)V
Description : Maxwell's relation corresponding to the identity, dH = dS = Vdp + ∑μi dni is (A) (∂T/∂V)S, ni = -(∂P/∂S)V, ni (B) (∂S/∂P)T, ni = (∂V/∂T)P, ni (C) (∂S/∂V)T, ni = (∂P/∂T)V, ni (D) (∂T/∂P)S, ni = (∂V/∂S)P, ni
Last Answer : (D) (∂T/∂P)S, ni = (∂V/∂S)P, ni
Description : “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture". This is (A) The statement as per Gibbs-Helmholtz (B) Called Lewis-Randall rule (C) Henry's law (D) None of these
Last Answer : (B) Called Lewis-Randall rule
Description : The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1is the activity co-efficient of component 1, is (A) A . x22 (B) Ax1 (C) Ax2 (D) Ax12
Last Answer : (A) A . x22
Description : Number of components (C), phase (P) and degrees of freedom (F) are related by Gibbs phase rule as (A) P + F - C = 2 (B) C = P - F + 2 (C) F = C - P - 2 (D) P = F - C - 2
Last Answer : A) P + F - C = 2
Description : __________ is concerned with the adsorption equilibria. (A) Fick's law (B) Gibb's equation (C) Freundlich equation (D) None of these
Last Answer : (C) Freundlich equation
Description : If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the (A) Maxwell's equation (B) Clausius-Clapeyron Equation (C) Van Laar equation (D) Nernst Heat Theorem
Last Answer : B) Clausius-Clapeyron Equation
Description : For reactions in parallel viz A → P (desired product) and A → Q (unwanted product), if the order of the desired reaction is higher than that of the undesired reaction, a (A) Batch reactor is preferred over a ... a single CSTR for high yield (C) Both (A) and (B) (D) Single CSTR is the most suitable
Description : The type of liquor circulation system to be ' employed in evaporators (viz. natural or forced circulation) is determined mainly by the __________ of the liquid. (A) Viscosity (B) Density (C) Thermal conductivity (D) Corrosive nature
Last Answer : (A) Viscosity
Description : On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line ... Y (C) (∂P/∂V)S = y(∂P/∂V)T (D) (∂P/∂V)S = 1/y(∂P/∂V)T
Last Answer : (C) (∂P/∂V)S = y(∂P/∂V)T
Description : In which of the following forms can Maxwell’s equation not be represented? a) Static b) Differential c) Integral d) Harmonic
Last Answer : a) Static
Description : For structural analysis of forces, the method refers to (A) Moment-area-theorem (B) Three-moment equation (C) Maxwell's reciprocal theorem (D) None of these
Last Answer : (A) Moment-area-theorem
Description : Those fertilizers having all the three major nutrients viz., N, P and K.
Last Answer : Ans. Complete fertilizers
Description : The Monetary Authority in India, viz Reserve Bank of India is bound to maintain a reserve against the notes issued, Whatever may be the mount. This system is called as __________ A. Minimum Reserve ... Reserve System C. Maximum Fiduciary Issue system D. Simple deposit system E. None of the Above
Last Answer : A. Minimum Reserve System Explanation: The RBI follows a minimum reserve system in the note issue. Initially, it used to keep 40 per cent of gold reserves in its total assets.
Description : The four underlying equations in electromagnetic theory are called: w) Einstein's Equations x) Maxwell's Equations y) Newton's Equations z) Faraday's Law
Last Answer : ANSWER: X -- MAXWELL'S EQUATIONS
Description : (∂H/∂T)P is the mathematical expression for (A) CV (B) Entropy change (C) Gibbs free energy (D) None of these
Last Answer : (D) None of these
Description : Which of the following is the Ideal gas law (equation)? A. V/T = K B. V= k*(1/P) C. P1/T1 = P2/T2 D. PV = nRT
Last Answer : PV = nRT
Description : Write A Short Note On Gibbs Free Energy And Derive The Equation For The Same.?
Last Answer : This thermodynamic quantity states that the decrease in value during a process is equal to the useful work done by the system. It is denoted by G and the mathematical equation is: G = H - TS Where ... of the system Thus the above equation becomes: ΔG = ΔH - TΔS is known as Gibbs-Helmoholtz equation.
Description : Pick out the correct statement. (A) The available energy in an isolated system for all irreversible (real) processes decreases (B) The efficiency of a Carnot engine increases, if the sink temperature is decreased ... condition is the change in Helmholtz free energy (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : Gibbs free energy of a pure fluid approaches __________ as the pressure tends to zero at constant temperature. (A) Infinity (B) Minus infinity (C) Zero (D) None of these
Last Answer : (B) Minus infinity
Description : Specific __________ does not change during phase change at constant temperature and pressure. (A) Entropy (B) Gibbs energy (C) Internal energy (D) Enthalpy
Last Answer : (B) Gibbs energy
Description : Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.). (A) Entropy (B) Internal energy (C) Enthalpy (D) Gibbs free energy
Last Answer : (D) Gibbs free energy
Description : Heat transfer rate to the charge/stock in a furnace does not depend upon the (A) Type of fuels viz. solid, liquid or gaseous (B) Flue gas temperature (C) Emissivity of refractory walls (D) Initial temperature of the charged stock
Last Answer : (A) Type of fuels viz. solid, liquid or gaseous
Description : An appropriate combination of farm enterprises viz., cropping system, livestock, poultry, fisheries and the means available to the farmer to raise them for increasing profitability is called as
Last Answer : Ans.Farming system
Description : There are two systems under which village postmen’s beats can be arranged, viz., a) The fixed beat, & unfixed beat system b) Normal beat & emergency beat c) Single beat & double beat d) None of these
Last Answer : a) The fixed beat, & unfixed beat system
Description : Helmholtz free energy (A) is defined as (A) A = H - TS (B) A = E - TS (C) A = H + TS (D) None of these
Last Answer : (B) A = E - TS
Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)
Description : Which of the following identities can be most easily used to verify steam table data for superheated steam? (A) (∂T/∂V)S = (∂p/∂S)V (B) (∂T/∂P)S = (∂V/∂S)P (C) (∂P/∂T)V = (∂S/∂V)T (D) (∂V/∂T)P = -(∂S/∂P)T
Last Answer : D) (∂V/∂T)P = -(∂S/∂P)T
Description : "At the absolute zero temperature, the entropy of every perfectly crystalline substance becomes zero". This follows from the (A) Third law of thermodynamics (B) Second law of thermodynamics (C) Nernst heat theorem (D) Maxwell's relations
Last Answer : (A) Third law of thermodynamics
Description : Describe with a neat diagram the working of a simple vapour compression refrigeration system. Represent the cycle on P–V and T–S diagram.
Last Answer : Vapour compression refrigeration cycle: The vapor-compression uses a circulating liquid refrigerant as the medium which absorbs and removes heat from the space to be cooled and subsequently rejects that heat elsewhere. Figure shows ... the compressor. P-V Diagram T-S diagram:
Description : From the L ineweaver-Burk p lot of Michaelis-Menten equation, Km and Vmax can be determined when V is the reaction velocity at substrate concentration S, the X-axis experimental data are expressed as (A) 1/V (B) V (C) 1/S (D) S
Last Answer : Answer : C
Description : For calculating the evaporation rate over a reservoir surface E = 0.771 (1.465 - 0.00732B) (0.44 - 0.007375 V) (pe - pa), the equation is given by (A) Roohwer's, formula in M.K.S. (B) Roohwer's formula in F.P.S. (C) Dalton's formula in F.P.S. (D) Dalton's formula in M.K.S
Last Answer : Answer: Option A
Description : Let’s look at words at the end of the second and fourth lines, viz., ‘snows’ and ‘clothes’, ‘true’ and ‘you’, ‘below’ and ‘know’. -English 9th
Last Answer : Earth-hearth, done-one, lay-away, another-over, flat-that, faint-saint, form- worm, food-wood, same-flame.
Description : An aeroplane is starting a non-precision approach with an MDH of 250ft and minimum visibility of 800 meters. ATC gives threshold, mid-runway and final third RVRs. When may the approach be started? ... than 800m. RVR is for precision approaches only. d. When threshold RVR is greater than 800m
Last Answer : d. When threshold RVR is greater than 800m
Description : Write various advantages of using high mast tower lighting viz a vIz Sodium lamps in circulating areas?
Last Answer : Ans. (i) Better illumination (ii) Vide area illumination (iii)where mass public movement (iv) Where loading & unloading of materials (v) At goods coaches & passenger coaches formation, checking and maintenance.
Description : Nandita scores 60% marks in five subjects together, viz., Hindi, Science, Mathematics, English and Sanskrit, where in the maximum marks of each subject were 105. How many marks did Nandita score in Science, if she scored 69 ... and 51 marks in English? a) 66 b) 68 c) 55 d) 65 e) None of these
Last Answer : Answer: D Total of maximum marks of all subjects=105×5=525 75% of 525=525 ×60/100= 315 Obtained marks of foru subjects (Hindi, Sanskrit, mathematics and English) =69+62+68+51=250 So, the obtained marks in Science=315-250=65
Description : Which of the following represents the Virial equation of state? (A) T = [RT/(V- b)] - [a/√T. V(V + b)] (B) PV/RT = 1 + (B/V) + (C/V2) + …… (C) n1u2 + μ2μ1 = 0 (D) None of these
Last Answer : (B) PV/RT = 1 + (B/V) + (C/V2) + ……
Description : General crushing equation is given by d(P/m) = -K (dD̅S /D̅ n S ). Bond's crushing law is obtained by solving this equation for n = __________ and feed of infinite size. (A) 1 (B) 1.5 (C) 2 (D) 2.5
Last Answer : (B) 1.5
Description : The two-dimensional rotation equation in the matrix form is a.P’=T+P b.P’=S*P c.P’=R*P d.P’=dx+dy
Last Answer : c.P’=R*P