Description : Maxwell's relation corresponding to the identity, dH = dS = Vdp + ∑μi dni is (A) (∂T/∂V)S, ni = -(∂P/∂S)V, ni (B) (∂S/∂P)T, ni = (∂V/∂T)P, ni (C) (∂S/∂V)T, ni = (∂P/∂T)V, ni (D) (∂T/∂P)S, ni = (∂V/∂S)P, ni
Last Answer : (D) (∂T/∂P)S, ni = (∂V/∂S)P, ni
Description : The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is (A) (∂T/∂V)S = - (∂P/∂S)V (B) (∂S/∂P)T = - (∂V/∂T)P (C) (∂V/∂S)P = (∂T/∂P)S (D) (∂S/∂V)T = (∂P/∂T)V
Last Answer : (D) (∂S/∂V)T = (∂P/∂T)V
Description : Which of the following identities can be most easily used to verify steam table data for superheated steam? (A) (∂T/∂V)S = (∂p/∂S)V (B) (∂T/∂P)S = (∂V/∂S)P (C) (∂P/∂T)V = (∂S/∂V)T (D) (∂V/∂T)P = -(∂S/∂P)T
Last Answer : D) (∂V/∂T)P = -(∂S/∂P)T
Description : Cvis given by (A) (∂E/∂T)V (B) (∂E/∂V)T (C) (∂E/∂P)V (D) (∂V/∂T)P
Last Answer : (A) (∂E/∂T)V
Description : The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H - P. This equation is called the (A) Maxwell's equation (B) Thermodynamic equation of state (C) Equation of state (D) Redlich-Kwong equation of state
Last Answer : (B) Thermodynamic equation of state
Description : On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line ... Y (C) (∂P/∂V)S = y(∂P/∂V)T (D) (∂P/∂V)S = 1/y(∂P/∂V)T
Last Answer : (C) (∂P/∂V)S = y(∂P/∂V)T
Description : (1/V) (∂V/∂T)Pis the mathematical expression (A) Joule-Thomson co-efficient (B) Specific heat at constant pressure (Cp) (C) co-efficient of thermal expansion (D) Specific heat at constant volume (CV)
Last Answer : (C) co-efficient of thermal expansion
Description : (∂T/∂P)H is the mathematical expression for (A) Specific heat at constant pressure (Cp) (B) Specific heat at constant volume (Cv) (C) Joule-Thompson co-efficient (D) None of these
Last Answer : (C) Joule-Thompson co-efficient
Description : Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is (A) 0 (B) ∞ (C) +ve (D) -ve
Last Answer : (A) 0
Description : The Joule-Thomson co-efficient is defined as (∂T/∂P)H. Its value at the inversion point is (A) ∞ (B) 1 (C) 0 (D) -ve
Last Answer : (C) 0
Description : Joule-Thomson co-efficient is defined as (A) µ = (∂P/∂T)H (B) µ = (∂T/∂P)H (C) µ = (∂E/∂T)H (D) µ = (∂E/∂P)H
Last Answer : (B) µ = (∂T/∂P)H
Description : Gibbs-Helmholtz equation is (A) ∆F = ∆H + T [∂(∆F)/∂T]P (B) ΔF = ΔH - TΔT (C) d(E - TS) T, V < 0 (D) dP/dT = ∆Hvap/T.∆Vvap
Last Answer : (A) ∆F = ∆H + T [∂(∆F)/∂T]P
Description : An ideal gas is heated at constant volume and then expanded isothermally. Show processes on P-V & T-S diagrams.
Last Answer : Process 1-2 : Constant volume process Process 2-3 : Constant temperature process (Isothermal process)
Description : Pick out the Clausius-Clapeyron equation from the following: (A) dP/dT = ∆H/T∆V (B) ln P = - (∆H/RT) + constant (C) ∆F = ∆H + T [∂(∆F)/∂T]P (D) None of these
Last Answer : B) ln P = - (∆H/RT) + constant
Description : Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs Helmholtz equation? (A) [∂(G/T)/∂T] = - (H/T2) (B) [∂(A/T)/∂T]V = - E/T2 (C) Both (A) and (B) (D) Neither (A) nor (B)
Last Answer : (C) Both (A) and (B)
Description : 3.0 lbm of air are contained at 25 psia and 100 ˚F. Given that Rair = 53.35 ft-lbf/lbm- ˚F, what is the volume of the container? A.10.7 ft^3 B.14.7 ft^3 C.15 ft^3 D.24.9 ft^3 Formula: use the ideal gas law pV = mRT T = (100 +460) ˚R V = mRT/p
Last Answer : 24.9 ft^3
Description : If air is at pressure, p, of 3200 lbf/ft2 , and at a temperature, T, of 800 ˚R, what is the specific volume, v? (R=5303 ft-lbf/lbm-˚R, and air can be modeled as an ideal gas.) A.9.8 ft^3/lbm B.11.2 ft^3/lbm C.13.33 ft^3/lbm D.14.2 ft^3/lbm Formula: pv = RT v = RT / p
Last Answer : 13.33 ft^3/lbm
Description : Which of the following is the Ideal gas law (equation)? A. V/T = K B. V= k*(1/P) C. P1/T1 = P2/T2 D. PV = nRT
Last Answer : PV = nRT
Description : What ideal gas is stored in a container at constant volume. If the temperature (T) were increased to 3T what would be the change in pressure (P)?
Last Answer : Feel Free to Answer
Description : The compressibility factor, x, is used for predicting the behavior of nonideal gases. How is the compressibility ty factor defined relative to an ideal gas? (subscript c refers to critical value) A. ... compressibility factor, x, is an dimensionless constant given by pV=zRT. Therefore z = pV / RT
Last Answer : z = pV/ RT
Description : The relation among various mass transfer co-efficients (M.T.C) for ideal gases is given by (where, Kc & Km are M.T.C. for equimolar counter diffusion with concentration & mole fraction respectively as the driving ... (C) Kc = Kp . RT = Km . RT/p (D) None of these
Last Answer : (C) Kc = Kp . RT = Km . RT/p
Description : (∂E/∂T)V is the mathematical expression for (A) CV (B) Enthalpy change (C) Free energy change (D) None of these
Last Answer : (D) None of these
Description : Uniform fluid flow occurs, when the derivative of the flow variables satisfy the following condition. (A) ∂/∂t = 0 (B) ∂/∂t = constant (C) ∂/∂s = 0 (D) ∂/∂s = constant
Last Answer : (C) ∂/∂s = 0
Description : Steady fluid flow occurs, when the derivative of flow variables satisfy the following condition. (A) ∂/∂s = 0 (B) ∂/∂t = 0 (C) ∂/∂s = constant (D) ∂/∂t = constant
Last Answer : (B) ∂/∂t = 0
Description : (∂H/∂T)P is the mathematical expression for (A) CV (B) Entropy change (C) Gibbs free energy (D) None of these
Description : For a perfect gas, according to Boyle’s law (where p = Absolute pressure, v = Volume, and T = Absolute temperature) A. p v = constant, if T is kept constant B. v/T = constant, if p is kept constant C. p/T = constant, if v is kept constant D. T/p = constant, if v is kept constant
Last Answer : Answer: A
Description : According to Gay-Lussac law for a perfect gas, p/T = constant, if v is kept constant. A. True B. False
Description : The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv ), depends upon its (A) Pressure (B) Volume (C) Temperature (D) All (A), (B) & (C)
Last Answer : (C) Temperature
Description : Boyle's law for gases states that (A) P ∝ 1/V, when temperature is constant (B) P ∝ 1/V, when temperature & mass of the gas remain constant (C) P ∝ V, at constant temperature & mass of the gas (D) P/V = constant, for any gas
Last Answer : (B) P ∝ 1/V, when temperature & mass of the gas remain constant
Description : In a P-V diagram (for an ideal gas), an isothermal curve will coincide within adiabatic curve (through a point), when (A) Cp < Cv (B) Cp = Cv (C) Cp > Cv (D) C ≥ Cv
Last Answer : (B) Cp = Cv
Description : An ideal gas is taken around the cycle ABCA as shown in P-V diagram below: The work done by the gas during the cycle is equal to (A) 12 P1V1 (B) 6 P1 V1 (C) 3 P1V1 (D) P1 V1
Last Answer : (C) 3 P1V1
Description : Charles' law for gases states that (A) V/T = Constant (B) V ∝ 1/T (C) V ∝ 1/P (D) PV/T = Constant
Last Answer : (A) V/T = Constant
Description : The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and ... , nj (C) (∂H/∂ni)S, P, nj (D) All (A), (B) and (C)
Last Answer : (D) All (A), (B) and (C)
Description : The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of (A) T (B) T and P (C) T, P and Z (D) T and Z
Last Answer : (B) T and P
Description : Ideal gas law is applicable at (A) Low T, low P (B) High T, high P (C) Low T, high P (D) High T, low P
Last Answer : (D) High T, low P
Description : An ideal gas at 45psig and 80ºF is heated in the close container to 130ºF. What is the final pressure? a. 65.10 psi b. 65.11 psi c. 65.23 psi d. 61.16 psi P1V1/T1= P2V2/T2;V = Constant
Last Answer : 65.23 psi
Description : For one dimensional flow of an incompressible fluid in unsteady state in x-direction, the continuity equation is given by (A) ∂u/∂x = 0 (B) ∂(ρu)/∂x = 0 (C) (∂u/∂x) = - (∂ρ/∂t) (D) ∂ρ/∂t = 0
Last Answer : (A) ∂u/∂x = 0
Description : As the temperature is lowered towards the absolute zero, the value of ∂(∆F)/∂T, then approaches (A) Unity (B) Zero (C) That of the heat of reaction (D) Infinity
Last Answer : B) Zero
Description : As the temperature is lowered towards the absolute zero, the value of the quantity (∂∆F/∂T) approaches (A) Zero (B) Unity (C) Infinity (D) None of these
Last Answer : (A) Zero
Description : In an ideal P.F.R. at steady state conditions (A) The composition of reactants remains constant along a flow path (B) The conversion of the reactant varies from point to point along a flow path (C) There is no lateral mixing of fluid (D) There may be diffusion along the flow path
Last Answer : (B) The conversion of the reactant varies from point to point along a flow path
Description : The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as the pressure (P) applied to it. The gas occupies a vol
Last Answer : The volume (V) of a mass of gas varies directly as its absulute temperature (T) and iversely as ... and pressure are 250 ml and 320 Pa respectively?
Description : The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as the pressure (P) applied to it. The gas occupies a vo
Last Answer : The volume (V) of a mass of gas varies directly as its absolute temperature (T) and inversely as ... and pressure are 200 ml and 250 Pa respectively?
Description : Boyle's law states that A. pressure of a gas is inversely proportional to its volume i.e. P V = constant B. pressure of a gas is directly proportional to its volume i.e. P⁄V = constant C. ... of a gas is directly proportional to the square of its volume i.e. P ⁄ V² = constant
Last Answer : pressure of a gas is inversely proportional to its volume i.e. P × V = constant
Description : Van der Waals derived an expression for the pressure defect', if the observed pressure is denoted as p' and volume is denoted as V', the gas pressure in the bulk of the gas is equal to: A. p + ... a: constant for the particular gas D. p + (a V²); where a: constant for the particular gas
Last Answer : p + a/(V²); where a: constant for the particular gas
Description : Internal energy of a gas obeying Van-Der-Waals equation of state, [p + (a/v2)] (V - b) = RT, depends upon its (A) Pressure & temperature (B) Pressure & specific volume (C) Temperature & specific volume (D) Temperature only
Last Answer : (A) Pressure & temperature
Description : The four properties of a system viz. P, V, T, S are related by __________ equation. (A) Gibbs-Duhem (B) Gibbs-Helmholtz (C) Maxwell's (D) None of these
Last Answer : (C) Maxwell's
Description : For an irreversible process involving only pressure-volume work (A) (dF)T, p 0 (D) (dA)T, v >0
Last Answer : (A) (dF)T, p
Description : For a reversible process involving only pressure-volume work (A) (dF)T, p < 0 (B) (dF)T, p > 0 (C) (dF)T, p = 0 (D) (dA)T, v < 0
Last Answer : (C) (dF)T, p = 0
Description : In case of isentropic flow, the speed of sound in an ideal gas is proportional to (where, T = absolute temperature). (A) 1/√T (B) 1/T (C) √T (D) T
Last Answer : (C) √T
Description : Translational kinetic energy of molecules of an ideal gas is proportional to (where, T = absolute temperature of the gas) (A) T (B) √T (C) T2 (D) 1/√T
Last Answer : (A) T